Coexisting melt (MI), fluid-melt (FMI) and fluid (FI) inclusions in quartz from the Oktaybrskaya pegmatite, central Transbaikalia, have been studied and the thermodynamic modeling of PVTX-properties of aqueous orthoboric-acid fluids has been carried out to define the conditions of pocket formation. At room temperature, FMI in early pocket quartz and in quartz from the coarse-grained quartz–oligoclase host pegmatite contain crystalline aggregates and an orthoboric-acid fluid. The portion of FMI in inclusion assemblages decreases and the volume of fluid in inclusions increases from the early to the late growth zones in the pocket quartz. No FMI have been found in the late growth zones. Significant variations of solid/fluid ratios in the neighboring FMI result from heterogeneous entrapment of coexisting melts and fluids by a host mineral. Raman spectroscopy, SEM EDS and EMPA indicate that the crystalline aggregates in FMI are dominated by mica minerals of the boron-rich muscovite–nanpingite CsAl2[AlSi3O10](OH,F)2 series as well as lepidolite. Topaz, quartz, potassium feldspar and several unidentified minerals occur in much lower amounts. Fluid isolations in FMI and FI have similar total salinity (4–8 wt.% NaCl eq.) and H3BO3 contents (12–16 wt.%). The melt inclusions in host-pegmatite quartz homogenize at 570–600 °C. The silicate crystalline aggregates in large inclusions in pocket quartz completely melt at 615 °C. However, even after those inclusions were significantly overheated at 650±10 °C and 2.5 kbar during 24 h they remained non-homogeneous and displayed two types: (i) glass+unmelted crystals and (ii) fluid+glass. The FMI glasses contain 1.94–2.73 wt.% F, 2.51 wt.% B2O3, 3.64–5.20 wt.% Cs2O, 0.54 wt.% Li2O, 0.57 wt.% Ta2O5, 0.10 wt.% Nb2O5, 0.12 wt.% BeO. The H2O content of the glass could exceed 12 wt.%. Such compositions suggest that the residual melts of the latest magmatic stage were strongly enriched in H2O, B, F, Cs and contained elevated concentrations of Li, Be, Ta, and Nb. FMI microthermometry showed that those melts could have crystallized at 615–550 °C.
Crystallization of quartz–feldspar pegmatite matrix leads to the formation of H2O-, B- and F-enriched residual melts and associated fluids (prototypes of pockets). Fluids of different compositions and residual melts of different liquidus–solidus P–T-conditions would form pockets with various internal fluid pressures. During crystallization, those melts release more aqueous fluids resulting in a further increase of the fluid pressure in pockets. A significant overpressure and a possible pressure gradient between the neighboring pockets would induce fracturing of pockets and “fluid explosions”. The fracturing commonly results in the crushing of pocket walls, formation of new fractures connecting adjacent pockets, heterogenization and mixing of pocket fluids. Such newly formed fluids would interact with a primary pegmatite matrix along the fractures and cause autometasomatic alteration, recrystallization, leaching and formation of “primary–secondary” pockets. 相似文献
The Xugou garnet peridotite body of the southern Sulu ultrahigh‐pressure (UHP) terrane is enclosed in felsic gneiss, bounded by faults, and consists of harzburgite and lenses of garnet clinopyroxenite and eclogite. The peridotite is composed of variable amounts of olivine (Fo91), enstatite (En92?93), garnet (Alm20?23Prp53?58Knr6?9Grs12?18), diopside and rare chromite. The ultramafic protolith has a depleted residual mantle composition, indicated by a high‐Mg number, very low CaO, Al2O3 and total REE contents compared to primary mantle and other Sulu peridotites. Most garnet (Prp44?58) clinopyroxenites are foliated. Except for rare kyanite‐bearing eclogitic bands, most eclogites contain a simple assemblage of garnet (Alm29?34Prp32?50Grs15?39) + omphacite (Jd24?36) + minor rutile. Clinopyroxenite and eclogite exhibit LREE‐depleted and LREE‐enriched patterns, respectively, but both have flat HREE patterns. Normalized La, Sm and Yb contents indicate that both eclogite and garnet clinopyroxenite formed by high‐pressure crystal accumulation (+ variable trapped melt) from melts resulting from two‐stage partial melting of a mantle source. Recrystallized textures and P–T estimates of 780–870 °C, 5–7 GPa and a metamorphic age of 231 ± 11 Ma indicate that both mafic and ultramafic protoliths experienced Triassic UHP metamorphism in the P–T forbidden zone with an extremely low thermal gradient (< 5 °C km?1), and multistage retrograde recrystallization during exhumation. Develop of prehnite veins in clinopyroxenite, eclogite, felsic blocks and country rock gneiss, and replacements of eclogitic minerals by prehnite, albite, white mica, and K‐feldspar indicate low‐temperature metasomatism. 相似文献
Soil samples from 0 to 100 cm depth were collected in four sampling sites (Sites A, B, C and D) along a 250-m length of sampling zone from the Yellow River channel to a tidal creek in a seasonal flooding wetland of the Yellow River Delta of China in fall of 2007 and spring of 2008 to investigate spatial and seasonal distribution patterns of total phosphorous (TP) and available phosphorus (AP) and their influencing factors. Our results showed that TP contents in spring and AP contents in both seasons in surface soils increased with increasing distances away from the Yellow River channel. TP contents in surface soils (0–10 cm) followed the order Site A (698.6 mg/kg) > Site B (688.0 mg/kg) > Site C (638.8 mg/kg) > Site D (599.2 mg/kg) in fall, while Site C (699.6 mg/kg) > Site D (651.7 mg/kg) > Site B (593.6 mg/kg) > Site A (577.5 mg/kg) in spring. Generally, lower TP content (630.6 mg/kg) and higher AP level (6.2 mg/kg) in surface soils were observed in spring compared to fall (656.2 mg/kg for TP and 5.2 mg/kg for AP). Both TP and AP exhibited similar profile distribution patterns and decreased with depth along soil profiles with one or two accumulation peaks at the depth of 40–80 cm. Although the mean TP content in soil profiles was slightly higher in spring (635.7 mg/kg) than that in fall (628.0 mg/kg), the mean TP stock was obviously lower in spring (959.9 g/m2) with an obvious accumulation at the 60–80 cm soil depth compared to fall (1124.6 g/m2). Topsoil concentration factors also indicated that TP and AP had shallower distribution in soil profiles. Correlation analysis showed that AP had significant and positive correlation with these soil properties such as soil organic matter, salinity, total nitrogen and Al (p < 0.01), but TP was just significantly correlated with TN and Al (p < 0.05). 相似文献
The zircon SHRIMP dating of the Zhangtiantang granite gave an age of 159±7 Ma., which shows that the granite was produced
at the early Late Jurassic. The Ar-Ar plateau ages of biotite and K-feldspar from the Zhangtiantang pluton are 153.2±1.1 Ma
and 135.8±1.2 Ma, respectively. The Ar-Ar anti-isochrone ages of biotite and K-feldspar are 152.5±1.7Ma and 135.4±2.7Ma, respectively.
The ages represent the isotopic closure ages of minerals in the pluton. The Zhangtiantang granites are regarded as peraluminous
crust-derived type granites to possess the typical geochemical characteristics of calc-alkaline rocks on continental margin,
with enriched Si, K, Al (average value of A/CNK as 1.18), HREE, Rb, U, and Th, heavily depleted V, Cr, Co, Ni, Ti, Nb-Ta,
Zr, Sr, P, and Ba, strongly negative Eu and common corundum normative (average value of C as 1.84). The εNd(t) values of the Zhangtiantang granite are −5.84 to −7.79, and t2DM values are 1.69 to 1.83 Ga, which indicates partial melting of continental-crust metamorphic sedimentary rocks during the
Middle Proterozoic.
The cooling history of the Zhangtiantang granitic pluton indicates that the cooling velocity of pluton was faster (about 67°C/Ma)
from zircon (158 Ma) to biotite (152 Ma), and was slower (about12°C/Ma) from biotite (152.5 Ma) to K-feldspar (135.8 Ma).
It can be deduced that the temporal gap (about 10 Ma) between the granite formmation and W-Sn mineralization in South China
may be related to ordinary magma-hydrothermal processes by the variational cooling curve of the pluton. The Zhangtiantang
pluton was formed in a compressive setting, with differentiation evolution and mineralization occurring in a relative relaxation
setting. 相似文献