ICP-MS测定土壤样品中Pb、Cd、Cr的不确定度评定

建立了ICP-MS测定土壤样品中Pb、Cd、Cr的不确定度数学模型,分别计算了标准储备液、校正曲线拟合、样品制备过程、分析信号强度及重复性试验等分量的不确定度,根据以上结果计算出标准不确定度。计算结果表明,不确定度主要来源于标准储备液制备和稀释以及重复性实验,该结论对分析过程质量控制、分析方法研究有一定的参考价值。     

青海东昆仑尕林格铁多金属矿床辉石闪长岩U-Pb年代学及地球化学特征

对青海尕林格矿区与成矿有关的辉石闪长岩的地球化学特征研究显示,该辉石闪长岩属于偏铝质、钙碱性系列岩石,明显富集活泼不相容元素Th、U和轻稀土元素,相对亏损高场强元素Nb、Ta、Ti和P,具弱的负Eu异常(δEu介于0.924~0.962)。岩石εHf(t)值为-3.79~-1.70,二阶段模式年龄为TDM2为1 223~1 339 Ma。尕林格闪长岩锆石LA-ICP-MS U-Pb加权平均年龄为228±2 Ma(MSWD=0.32),为晚三叠世。综合前人研究成果,认为在巴颜喀拉地块与东昆仑地块碰撞-后碰撞转换阶段俯冲的阿尼玛卿洋壳板片发生断离,引起地幔物质上涌至古老的下地壳底部,使其发生部分熔融并混入部分幔源物质,形成尕林格辉石闪长岩石。     

Status of two <Emphasis Type="Italic">Coreius</Emphasis> species in the Three Gorges Reservoir,China

Dam construction alters natural flow regimes which, in turn, cause significant changes in fish communities during and after impoundment. The construction of the Three Gorges Reservoir, from impoundment of the Changjiang (Yangtze) River, China, may have affected native fish species. Thus, the status of two lotic freshwater fish species, Coreius heterodon and C. guichenoti, were monitored in the Three Gorges Reservoir, including fish abundance, individual composition, growth, condition, and mortality. Data on both species were gathered from upstream, midstream and downstream areas of the reservoir and, where available, from studies published before and after dam construction. Lower abundance, slower growth, a less diversified age structure, poorer fish condition (indicated by hepatosomatic index) and higher mortalities were recorded in sites nearest the dam compared with upstream areas. Furthermore, after final impoundment, individual Coreius species inhabiting the area changed, with young individuals becoming more abundant, while upstream of the reservoir the two Coreius species became smaller at a given age. The results show that the status of the two Coreius species was subject to dramatic changes after impoundment.     

基于小波分析的海洋平台实时结构健康监测

由于海洋平台结构长期处于恶劣的海洋环境中,并受到各种载荷的交互作用,结构容易产生各种形式的损伤。因此,对海洋平台进行实时监测有着十分重要的现实意义。以单筒简易导管架平台为例,主要在结构损伤的判定和定位两方面对海洋平台的实时结构健康监测进行研究,结果表明通过对结构响应信号进行小波分析,小波变换系数和小波包能量分布可以很好地定义损伤识别指标。     

Long-term effects of di-octyl phthalate on the expression of immune-related genes in <Emphasis Type="Italic">Tegillarca granosa</Emphasis>

Di-octyl phthalate (DOP) is widely used as a plasticizer in the plastics industry. As a result, DOP is often found in marine water ecosystems where many species are exposed to it. Our objective was to evaluate the effect of long-term (14 d) DOP exposure (2.6, 7.8, or 31.2 mg/L) on the expression of immunerelated genes in Tegillarca granosa. The expression of small heat shock protein (sHSPs) and tissue inhibitor of metalloproteinase (TIMP) were highest in clams exposed to 31.2 mg/L DOP on days 7 and 14. The relative expression of Tg-ferritin, superoxide dismutase (SOD), and metallothionein (MT) increased initially then decreased as the concentration of DOP increased. The hemoglobin of T. granosa (Tg-HbI) exhibited two distinct expression patterns at two time points. Our results suggest that the immune response of T. granosa against DOP pollution varies depending on the dose. Additionally, we identified some immune-related genes that are promising candidates for biomarkers of DOP.     

Impacts of climate change on net primary productivity in arid and semiarid regions of China

In recent years, with the constant change in the global climate, the effect of climate factors on net primary productivity(NPP) has become a hot research topic. However, two opposing views have been presented in this research area: global NPP increases with global warming, and global NPP decreases with global warming. The main reasons for these two opposite results are the tremendous differences among seasonal and annual climate variables, and the growth of plants in accordance with these climate variables. Therefore, it will fail to fully clarify the relation between vegetation growth and climate changes by research that relies solely on annual data. With seasonal climate variables, we may clarify the relation between vegetation growth and climate changes more accurately. Our research examined the arid and semiarid areas in China(ASAC), which account for one quarter of the total area of China. The ecological environment of these areas is fragile and easily affected by human activities. We analyzed the influence of climate changes, especially the changes in seasonal climate variables, on NPP, with Climatic Research Unit(CRU) climatic data and Moderate Resolution Imaging Spectroradiometer(MODIS) satellite remote data, for the years 2000–2010. The results indicate that: for annual climatic data, the percentage of the ASAC in which NPP is positively correlated with temperature is 66.11%, and 91.47% of the ASAC demonstrates a positive correlation between NPP and precipitation. Precipitation is more positively correlated with NPP than temperature in the ASAC. For seasonal climatic data, the correlation between NPP and spring temperature shows significant regional differences. Positive correlation areas are concentrated in the eastern portion of the ASAC, while the western section of the ASAC generally shows a negative correlation. However, in summer, most areas in the ASAC show a negative correlation between NPP and temperature. In autumn, precipitation is less important in the west, as opposed to the east, in which it is critically important. Temperatures in winter are a limiting factor for NPP throughout the region. The findings of this research not only underline the importance of seasonal climate variables for vegetation growth, but also suggest that the effects of seasonal climate variables on NPP should be explored further in related research in the future.     

CMIP5 model-simulated onset,duration and intensity of the Asian summer monsoon in current and future climate

A number of significant weaknesses existed in our previous analysis of the changes in the Asian monsoon onset/retreat from coupled model intercomparison project phase 3 (CMIP3) models, including a lack of statistical significance tests, a small number of models analysed, and limited understanding of the causes of model uncertainties. Yet, the latest IPCC report acknowledges limited confidence for projected changes in monsoon onset/retreat. In this study we revisit the topic by expanding the analysis to a large number of CMIP5 models over much longer period and with more diagnoses. Daily 850 hPa wind, volumetric atmospheric precipitable water and rainfall data from 26 CMIP5 models over two sets of 50-year periods are used in this study. The overall model skill in reproducing the temporal and spatial patterns of the monsoon development is similar between CMIP3 and CMIP5 models. They are able to show distinct regional characteristics in the evolutions of Indian summer monsoon (ISM), East Asian summer monsoon (EASM) and West North Pacific summer monsoon (WNPSM). Nevertheless, the averaged onset dates vary significantly among the models. Large uncertainty exists in model-simulated changes in onset/retreat dates and the extent of uncertainty is comparable to that in CMIP3 models. Under global warming, a majority of the models tend to suggest delayed onset for the south Asian monsoon in the eastern part of tropical Indian Ocean and Indochina Peninsula and nearby region, primarily due to weakened tropical circulations and eastward shift of the Walker circulation. The earlier onset over the Arabian Sea and part of the Indian subcontinent in a number of the models are related to an enhanced southwesterly flow in the region. Weak changes in other domains are due to the offsetting results among the models, with some models showing earlier onsets but others showing delayed onsets. Different from the analysis of CMIP3 model results, this analysis highlights the importance of SST warming patterns over both the tropical Pacific and Indian Oceans in affecting the modelling results. The increased atmospheric moisture content offsets some effects of the delayed onset and results in increased rainfall intensity during the active monsoon period. The deficiencies of using rainfall alone in assessing the potential changes of the monsoon system are also shown in this study.     

Calculation and accuracy evaluation of TGD from IFB for BDS

With the development of new global navigation satellite system applications, the demand of high accurate positioning navigation timing (PNT) service becomes urgent. For precise PNT, the timing group delay (TGD) is regarded as an important parameter in the satellite navigation message. Instead of using the absolute receiver hardware delay, a method based on receiver inter-frequency bias (IFB, i.e., differential receiver hardware delay between different frequencies) calibration is presented to deal with the rank deficiency of a calculation matrix and to reduce jumps in TGD solutions in BDS. The double-differenced pseudorange obtained from a pair of zero baseline receivers is used to evaluate the IFB calibration accuracy. The estimated precision of TGD is evaluated and compared with GPS TGD provided by IGS. In order to ensure the quality of assessment, a method based on the difference of dual-frequency ionospheric delay is proposed to compare the accuracy of the estimated TGD and broadcast TGD. Finally, the effect of TGD on the user equivalent range error is analyzed. The analysis result shows that for BDS IGSO satellites, the precision of TGD1, which is the differential hardware delay between B1 (1561.098 MHz) and B3 (1268.52 MHz) frequencies, is better than 0.5 ns, and for GEO and MEO satellites the TGD1 is better than 1 and 2 ns, respectively. The precision of TGD2 of all satellites, which is the differential hardware delay between B2 (1207.14 MHz) and B3 frequencies, is better than 0.5 ns. The accuracy analysis result reveals that the proposed TGD estimation method can provide better results when compared with the broadcast data.