典型矿区深层地下水重金属含量特征及健康风险评价——以皖北矿区为例

以皖北矿区为例,分析测试了不同含水层(松散、煤系、太灰、奥灰)中的6种重金属元素(Cd、Cr、Cu、Zn、Pb、Ni),对其含量特征及健康风险评价进行了研究。结果表明,6种重金属在不同含水层含量大小次序各不一样,从整体来看,研究区地下水中所测重金属含量依次为NiZnPbCuCdCr,与太灰水一致;整体地下水中Cr、Cu和Zn均未超过(GB/T14848—93)中Ⅲ类水质标准,Cd、Pb和Ni有部分水样超过标准限值。化学致癌物Cd和Cr在各含水层所致健康危害风险值数量级在10-6~10-4 a-1,Cr健康风险值在各含水层中均大于Cd,Cr在煤系含水层危害风险值(1.29×10-4 a-1)已超过美国环境保护局(USEPA)最大可接受风险(1×10-4 a-1),为研究区首要的环境健康风险管理控制指标。化学非致癌物Cu、Zn、Pb、Ni四种重金属健康危害风险值较小,数量级在10–11~10-8 a-1,Pb和Ni健康危害风险值相对较高,也应引起重视。各含水层总的健康风险值大小次序为:煤系太灰奥灰松散,前三者已超过国际辐射防护委员会(ICRP)推荐的(5×10-5 a-1)最大可接受风险,其中煤系含水层总的健康风险值为1.46×10-4 a-1,已超过USEPA(1×10-4 a-1)推荐的最大可接受风险。对矿区深层地下水开展重金属含量分析和健康风险评价,可为地下水水资源的开采利用和保护提供参考。     

Se and Te mineralization in albitites and prospects of the metasomatites for Au,Salla-Kuolajarvi belt,Northern Karelia

On the basis of the complex of geological features, the eastern flank of the Salla-Pana-Kuolajarvi belt is a prospect structure for gold mineralization in the U-bearing albitites and related acid and mafic metasomatites. Visible tellurides and selenides, which are typical of gold deposits of the Fe-Co-Au-U group in the adjacent territory of Finland within the Salla-Pana-Kuolajarvi belt, were found in the Ozerny occurrence as a result of studies. Native gold is found in association with tellurides. Molybdenite from the occurrence has a high Re content up to 0.3%.     

Metallogenic and Metamorphic Age of the Hongtoushan Copper–Zinc Massive Sulfide Deposit,Liaoning Province,China

The Hongtoushan copper–zinc deposit is the only large Archean volcanogenic massive sulfide (VMS) deposit in China. This paper presents new information on the timing of metallogenesis and metamorphism of the deposit, including new cathodoluminescence (CL) images, and Th U^?1 and LA–ICP–MS U–Pb dating on zircons of the biotite–plagioclase gneiss and plagioclase–amphibole gneiss that host the deposit. The CL images and Th U^?1 ratios indicate that the zircons within the gneiss are of metamorphic origin. LA–ICP–MS dating of the plagioclase–amphibole gneiss yielded the upper intercept ages of 2549 Ma, and the biotite–plagioclase gneiss yielded the upper intercept ages of 2552 Ma and 2550 Ma correspondingly, indicating that the mineralization of the deposit occurred at around 2550 Ma. The rims of zircons within these host rocks yielded younger U–Pb ages at 2529, 2520 and 2515 Ma, identical to the age of felsic intrusive rocks in the study area. This suggests that the Hongtoushan VMS deposit underwent initial metamorphism and deformation at around 2520 Ma by the intrusion of granite magmas.     

Controlling Factors,Accumulation Model and Target Zone Prediction of the Coal‐bed Methane in the Huanghebei Coalfield,North China

The Huanghebei Coalfield, one of the coal production bases in North China, was considered as a coalfield without coal‐bed methane (CBM) during past decades. In recent years, however, CBM has been discovered in coal‐bearing successions. In order to understand the CBM geological characteristics and accumulation process in this area, fifteen coal samples were collected and analyzed with respect to coal maceral and reflectance. The result shows that the gas distribution is uneven and the content varies in different areas even for the same coal bed. The storage of CBM is affected by geological factors such as burial depth, geological structures, and magmatic intrusion, among which the former two are more important in the formation of CBM. Deep burial of coal beds with the presence of cap‐rock mudstone can seal CBM. The CBM is also accumulated and preserved at the place where normal faults are distributed. Magmatic intrusion causes contact metamorphism and controls the CBM formation by heating the coal‐bearing successions. The obtained data indicate the geological conditions in northeastern Zhaoguan Mine are preferable for CBM formation and conservation; recent exploration estimates the CBM geological reserves up to 282.16 Mm³ and average of reserve abundance at 0.1662 × 10⁸ m³ km^?2. The Changqing Mine is a potential prospect in terms of CBM exploration since its geological conditions (structures and burial depth) are similar to the Zhaoguan Mine and its cap rock is even better.     

辽西花坤头营子地区旋卷构造特征浅析

辽宁西部花坤头营子地区旋卷构造是板块碰撞陆内造山作用结果.该构造由内环、外环及推覆体三部分组成.内环为一个完整的莲花状构造体系,由中心向外,岩石地层单位呈一圈一圈的,由老向新排列.外环为以雾迷山组为主体的北东向的瓦房子复背斜核部.内环与外环以塌陷断层、旋转挤压断层分隔.与该构造有关的矿产有铅锌、锰矿.     

大兴安岭西坡银都赋矿岩体LA-ICP-MS锆石U-Pb定年及其成因意义

银都矿床位于内蒙古大兴安岭西坡,为受断裂控制的银多金属矿床。该矿床的岩体主要为石英闪长岩。该岩体中的锆石分为岩浆锆石和热液锆石两类:岩浆锆石无色透明,自形长柱状,具有典型的振荡环带特征;而热液锆石呈浅褐色,半透明—不透明,等轴状,其暗色增生边明显切过了核部岩浆锆石结构。热液锆石相对岩浆锆石具有低Th/U和LREE,高Hf和HREE的特征。银都岩体岩浆锆石的206Pb/238 U加权平均年龄为(451.8±7.8)Ma,属加里东期,为岩体的结晶年龄;热液锆石的206 Pb/238 U加权平均年龄为(337.0±7.7)Ma,属中石炭世,代表了热液作用的年龄。热液锆石年龄表明,该区在337Ma左右经历了一次强烈的热液作用,该期热液作用可能与该区造山峰期的变质作用有关。本区的地质特征和流体包裹体特征表明,本区银矿的形成很可能与这期热液活动密切相关。     

川南地区龙马溪组页岩有机质特征及其对页岩含气量的影响

四川盆地南部地区广泛发育下古生界寒武系、志留系等多套海相页岩层,其中龙马溪组是该区页岩气勘探开发的重点目标层。根据钻井岩心资料,通过有机碳、热解、碳同位素、等温吸附等地球化学实验分析,对川南地区下志留统龙马溪组页岩的有机质特征及其对页岩含气量的影响进行了研究。结果表明,川南地区龙马溪组页岩有机碳含量较高(平均1.53%),有机质类型较好(Ⅰ型和Ⅱ1型),热演化程度高(Ro为1.94%~2.42%),且页岩含气量较高(平均1.85m3/t)。页岩有机质特征是影响页岩含气量的主要因素,有机质丰度、有机质类型和热演化程度三者共同决定了川南地区龙马溪组页岩的含气量。     

“平、剖面三维联动编辑”的实现途径

基于对平、剖面三维联动编辑的概念、动因的探讨及相关研究成果的认识,提出了平、剖面三维联动编辑的几何原理与实现途径,如:地质曲面的表达、基于等高线的曲面构建、剖面图的构建、以及平面图与剖面图的联动修改方法。并对三维地质建模的需求、矿产资源勘探应提交的三维地质模型、三维地质建模的数据标准以及广义的三维联动编辑等问题进行了延伸讨论。认为平、剖面三维联动编辑可能成为三维建模软件推广应用中的"杀手级应用"。     

黑龙江七星河含煤盆地古近纪-新近纪沉积相及层序地层特征

黑龙江省东部七星河盆地是一新生代聚煤盆地,其含煤地层为古近系宝泉岭组、新近系富锦组。宝泉岭组由各级砂岩、泥岩、炭质泥岩以及褐煤组成,发育滨浅湖相、深-半深湖相、三角洲平原相,属于湖泊沉积体系、三角洲沉积体系。富锦组主要由泥岩、粉砂岩、中砂岩、含砾粗砂岩及煤层、炭质泥岩、硅藻岩组成,发育滨浅湖相、扇三角洲平原相,分别属于湖泊沉积体系和扇三角洲沉积体系。层序SI相当于宝泉岭组,发育低位体系域、湖侵体系域和高位体系域,煤层主要发育高位体系域中后期,成煤环境以滨浅湖淤积沼泽为主。层序SII相当于富锦组,主要发育湖侵体系域、高位体系域,局部地区发育低位体系域,煤层亦主要发育高位体系域中后期,成煤环境以扇三角洲淤积沼泽和滨浅湖淤积沼泽为主。层序SI、SII的高位体系域中后期,盆地基底沉降速率和物源供给处于相对平衡状态,主要发育了扇三角洲淤积沼泽、滨浅湖和滨浅湖淤积沼泽环境,发育可采煤层。     

Evaluation of I-wall in New Orleans with back-calculated total stress soil parameters

This study back-calculated moduli and shear strength of soils in London Canal Ave., New Orleans, using full-scale load test data, and re-evaluated the behavior of the I-wall to explore how the existing levees and floodwalls may be reliably retrofitted and future levees and floodwalls may be designed. From the back-calculation, it turned out that the moduli of the field soils were mostly higher (1–12 times) than magnitudes appeared in Interagency Performance Evaluation Task Force (IPET). But the shear strength of a water-glazed Marsh layer in the gap turned out to be substantially lower (0.2–0.25 times) than the magnitude appeared in IPET. This much strength reduction was confirmed by field vane shear tests: tests with artificial water infiltration into the field vane hole presented immeasurably low disturbed strength and resulted in very high sensitivity that might contributed to the failure. This study also shows that the gap development and strength reduction in the water-glazed Marsh layer are two main causes of levee failure, which have been predicted in previous research. The stiffer-than-expected moduli of underlain layers did not affect the failure mechanism of the levee substantially because these underlain layers remained elastic. Therefore, retrofitting solutions should be the ones that may prevent the gap development and to reinforce the Marsh layer.