我国土壤中铜的污染现状与修复研究进展

铜是动植物必需的微量营养元素,但过量的铜会严重影响动植物的生长。近年来,随着工农业的迅速发展,土壤铜污染已成为重要的土壤环境污染问题之一。土壤铜污染不仅降低土壤环境质量,而且影响植物、土壤微生物、土壤酶活性等的平衡稳定发展,并威胁农产品质量安全。文中综述现阶段我国土壤铜污染的来源、污染现状,分析了土壤铜污染的特点及对土壤生态系统的危害,介绍土壤铜污染的预防方法,分析并总结目前用于治理土壤铜污染的修复技术原理、适用性及其国内外研究与发展动态,进一步提出未来我国土壤铜污染修复技术有待深入研究的相关问题,以期为我国土壤铜污染的研究和修复治理提供参考。     

考虑钙质砂细观颗粒形状影响的液体拖曳力系数试验

钙质砂作为南海岛礁填筑常用的岩土材料,其渗透性很大程度上决定着填筑后土体的固结和沉降。拖曳力系数是表达流体对土体颗粒表面力的参数,也是表征颗粒状土体渗透能力的一个重要参数,目前国内外对钙质砂拖曳力系数的研究十分有限。首先引入一个修正的三维参数 对钙质砂这种天然非规则颗粒材料的形状进行定量描述,然后开展一系列单个钙质砂颗粒在液体中沉降试验,利用高速相机记录颗粒沉降过程,结合图像处理技术获得颗粒沉降平衡速度Ut,进而计算出拖曳力系数CD和雷诺数Re,最后拟合出包含CD、Re及 三个参数的钙质砂拖曳力系数半经验模型。结果发现,在相同雷诺数条件下钙质砂的形状系数 越大,拖曳力系数越小。通过与其他研究结果对比发现,其表面微孔隙越发育,拖曳力系数越小的规律。该模型能够考虑不规则颗粒形状对拖曳力系数的影响,从而提高对土体渗透性预测的精度,对南海岛礁填筑工程中钙质砂固结和沉降的计算也具有重要意义。     

基于立体层析反演的低频模型构建在深水区储层反演中的应用:以南海深水W构造为例

建立准确的低频模型是波阻抗反演中的重要环节,它直接影响着波阻抗反演结果的准确性。但是,常规模型建立方法的准确性受钻井数量影响明显,钻井数量越多,模型的准确性越高。在海洋深水油气勘探过程中,由于勘探费用昂贵,钻井数量非常少,很难通过常规方法建立准确的低频模型。特别是在沉积体横向特征变化较大时,地震反演的可靠性受到巨大影响。本文首先介绍了立体层析速度反演的基本理论和数据域、成像域立体层析速度反演的计算过程,综合数据域立体层析与成像域立体层析的优势获得了高精度速度模型;然后结合有限的钻井进行标定,构建出地震反演所需的低频模型,有效提升了低频模型的精度,使其达到可真实反映较大规模地质异常体的尺度;最后,将其应用于南海深水区W构造的勘探实践,提升了反演结果横向预测的准确性。     

叠加风场在南海台风浪数值后报中的应用研究

根据经验风场与NCEP再分析风场的优缺点,采用两者相叠加的方式构造了一种叠加风场,与实测风速资料对比验证显示该风场精度较高。以叠加风场数据为输入,采用WAVEWATCH Ⅲ模式对南海海域有显著影响的8场台风进行计算,结果显示叠加风场计算南海台风浪具有较高的精度和可靠性。     

基于水淘选分级的长江口及邻近海域表层沉积物中磷的形态分布和迁移转化

磷是一种重要的生源要素,在河口、边缘海的初级生产中发挥重要作用,了解沉积物中磷的形态分布和迁移转化有助于深入了解该区域生态系统动力学。于2013年3月在长江口及邻近海域采集了表层沉积物样品,利用水淘选方法对沉积物进行了分级,并采用化学连续提取法分析了未分级和分级沉积物样品中的6种磷形态含量:可交换态磷、活性有机磷、铁结合态磷、自生磷灰石磷、碎屑磷和难分解有机磷,讨论了该区域沉积物中磷的形态分布、选择性输运过程和迁移转化。沉积物中总磷含量在14.0~18.4 μmol/g,其中碎屑磷是其主要成分,占54.5%,其次是有机磷和难分解有机磷,分别占到15.1%和13.1%。不同粒级沉积物中磷形态含量不同,可交换态磷、活性有机磷、铁结合态磷、自生磷灰石磷和难分解有机磷随粒级增加含量逐渐降低,而碎屑磷主要集中在粗粒级（大于32 μm）沉积物中。基于各粒级磷形态的质量分布,发现小于32 μm粒级的沉积物中各磷形态含量从长江口向浙闽沿岸逐渐增加,向外海方向逐渐减小,而大于32 μm沉积物的变化趋势与此相反,体现了不同形态磷的选择性输运。随粒径增大,总有机碳对有机磷比值（TOC/Or-P）先降低后升高,在大粒级沉积物中,TOC/Or-P比值较高主要是因为陆源有机碳贡献较高,而在小粒级沉积物中,主要是由于有机磷的迁移和转化更为活跃,体现了细颗粒物中有机磷相对有机碳的优先分解。本研究表明,从分级的角度可以对河口、边缘海的磷循环有一个更全面的认识。     

基于稳定性同位素的普里兹湾南极大磷虾不同发育阶段食性转变分析

As one of the most common and dominant species in the Southern Ocean, Antarctic krill(Euphausia superba)play a significant role in food web structure and the process of energy flow. The diet of Antarctic krill in the Prydz Bay during austral summer of 2012/2013 was investigated and the ontogenetic shift in krill diet was evaluated using the stable isotope method. The nitrogen stable isotope values(δ~(15) N) of adults((2.78±0.58)‰) were much higher than those of juveniles((1.69±0.70)‰), whereas the carbon stable isotope values(δ~(13) C) of adults(–(28.26±1.08)‰) were slightly lower than those of juveniles(–(27.48±1.35)‰). Particulate organic matter(POM)from 0, 25, and 50 m depth combined(0/25/50 m) represented phytoplankton food items. The results showed that phytoplankton food items in surface water and mesozooplankton were two essential food items for Antarctic krill in the Prydz Bay during summer. POM(0/25/50 m) contributes 56%–69% and 26%–34% to the diet of juvenile and adult krill, respectively, whereas mesozooplankton composes 13%–34% and 58%–71% of the diet of juvenile and adult krill, respectively. Thus, an ontogenetic diet shift from POM(0/25/50 m), which consists mainly of phytoplankton, to a higher trophic level diet containing mesozooplankton, was detected. The capacity for adults to consume more zooplankton food items may minimize their food competition with juveniles, which rely mostly on phytoplankton food items. This suggests "diet shift with ontogeny" which may somehow help krill keep their dietary energy budget balanced and well adapted to the Antarctic marine ecosystem as a dominant species.     

南海东北部冷泉区沉积物中有机质来源的生物标志物分析与环境指示意义

Multi-biomarker indexes were analyzed for two piston cores from potential cold seep areas of the South China Sea off southwestern Taiwan. Total organic carbon(TOC) normalized terrestrial(n-alkanes) and marine(brassicasterol, dinosterol, alkenones and iso-GDGTs) biomarker contents and ratios(TMBR, 1/Pmar-aq, BIT) were used to evaluate the contributions of terrestrial and marine organic matter(TOM and MOM respectively) to the sedimentary organic matter, indicating that MOM dominated the organic sources in Core MD052911 and the sedimentary organic matter in Core ORI-_(86)0-22 was mainly derived from terrestrial inputs, and different morphologies were the likely reason for TOM percentage differences. BIT results suggested that river-transported terrestrial soil organic matter was not a major source of TOM of sedimentary organic matter around these settings.Diagnostic biomarkers for methane-oxidizing archaea(MOA) were only detected in one sample at 172 cm depth of Core ORI-_(86)0-22, with abnormally high iso-GDGTs content and Methane Index(MI) value(0.94). These results indicated high anaerobic oxidation of methane(AOM) activities at or around 172 cm in Core ORI-_(86)0-22.However in Core MD052911, MOA biomarkers were not detected and MI values were lower(0.19–0.38), indicated insignificant contributions of iso-GDGTs from methanotrophic archaea and the absence of significant AOM activities. Biomarker results thus indicated that the discontinuous upward methane seepage and insufficient methane flux could not induce high AOM activities in our sampling sites. In addition, the different patterns of TEX_(86) and U_(37)~(K′) temperature in two cores suggested that AOM activities affected TEX_(86)37 temperature estimates with lower values in Core ORI-_(86)0-22, but not significantly on TEX_(86) temperature estimates in Core MD052911.     

Evaluating the relationship between spatial heterogeneity and temporal variability of larval fish assemblages in a coastal marine ecosystem (Haizhou Bay,China)

In coastal marine ecosystems, spatial patterns of larval fish assemblages (LFAs) tend to exhibit geographic stability because of relatively stable spawning site selection and predictable oceanographic phenomena such as eddies. To evaluate the relationship between spatial heterogeneity and temporal variability of LFAs, we conducted a high spatiotemporal resolution ichthyoplankton survey from April to July in 2013 in the shallow waters (<20 m) of Haizhou Bay, China. Our analysis indicated three distinct assemblages, which were stable geographically but exhibited a gradual and directional change of species composition and abundance over our study period. Sea surface temperature was the most important environmental co‐variate for determining temporal variability of LFAs, likely owing to temperature effects of species composition and spawning period selection of adult fish, along with known temperature‐dependent survival rates of larval fish. Study of LFA spatiotemporal dynamics is essential for improved understanding of adult fish spawning behavior, and has potential to inform design and implementation of conservation and management measures (e.g. marine protected areas) in coastal systems.     

辽河口邻近海域小型底栖生物的空间分布及季节变化

本文研究了辽河口邻近海域2013年8月、10月和2014年5月3个航次小型底栖生物的种类及其空间分布,分析了小型底栖生物丰度和生物量的季节变化。结果表明,3个航次（夏季、秋季和春季）小型底栖生物的平均丰度分别为（264±83） ind/（10 cm2）、（216±85） ind/（10 cm2）和（227±67） ind/（10 cm2）,平均生物量分别为（272±125）μg/（10 cm2）、（207±89）μg/（10 cm2）和（244±103）μg/（10 cm2）。与其他研究海域相比,辽河口小型底栖的丰度和生物量处于较低水平。共鉴定出了14个小型生物类群,按照丰度排序,线虫是最优势的类群,夏季、秋季和春季3个航次占总丰度的比例分别为94.0%、92.5%和90.8%;其他优势类群为多毛类、桡足类和双壳类。小型底栖生物量的优势类群则为多毛类（41.1%~44.0%）,高于线虫（33.8%~36.5%）,其次是双壳类（2.6%~6.7%）。水平分布的研究表明,调查海域近岸入海口小型底栖生物的丰度和生物量普遍低于近海海域,但是秋季时近岸分布与近海差距不大。垂直分布的研究表明,95.9%的小型底栖生物分布于0~5 cm的表层沉积物中。小型底栖生物的丰度和生物量在夏季时都达到高峰值。与环境因子的相关分析表明,小型底栖生物的数量分布与盐度和水深呈极显著正相关（P<0.01）,与叶绿素a呈显著正相关（P<0.05）。     

改进型中心管模型能量转换性能试验及样机设计

为了提高中心管振荡水柱波浪能利用技术能量转换效率,基于新的认识和目前常用的2.4米导航灯标,对中心管尾部设计了三种模型并在造波水槽中进行能量转换性能试验。试验结果表明:直管型中心管俘获宽度比最高达到了70.25%,但通频带宽度窄;加长喇叭口型中心管略好于喇叭口型中心管;在喷咀比为0.02条件下,加长喇叭口型中心管浮体有较高双峰俘获宽度比,波峰为40.0%,波谷为31.6%,通频带宽,为随机波下高效转换创造了条件。最高俘获宽度比和双峰通频带特性实验数据结果都优于历史文献值。根据试验数据对一些适合小型海洋仪器供电的样机进行了设计,设计的样机具有较高的性价比。