Ruthenium-ion-catalyzed oxidation of asphaltenes and oil-source correlation of heavy oils from the Lunnan and Tahe oilfields in the Tarim Basin, NW China

The identification of marine source rocks in the Tarim Basin is debated vigorously. The intention of this paper is to investigate the asphahenes in heavy oils from the Lunnan and Tabe oilfields and Well TD2 with ruthenium-ions-catalyzed oxidation technique (RICO), in order to explore its role in oil-oil and oil-source correlations, The RICO products included n-alkanoic acids, α,ω-di-n-alkanoic acids, branched alkanoic acids, tricyclic terpanoic acids, hopanoic acids, gammacerane carboxylic acid , regular sterane carboxylic acids and 4-methylsterane carboxylic acids. The n-alkyl chains and biomarkers bounded on the asphaltenes were of unsusceptibility to biodegradation. The distribution and absolute concentrations of n-alkanoic acids in the RICO products of heavy oils from the Lunnan and Tabe oilfields are different from those of Well TD2. The biomarkers bounded on the asphahenes, especially steranes, have a distribution trend similar to that of the counterparts in saturates. The sterane carboxylic acids and 4-methylsterane carboxylic acids in the RICO products of heavy oils from the Lunnan and Tahe oilfields, dominated by C30 sterane and C31 4-methylsterane carboxylic acids, respectively, are significantly different from those of the heavy oils of Well TD2, whose dominating sterane and 4-methylsterane carboxylic acids are C28 sterane and C29 4-methylsterane acids, respectively. The RICO products of the asphaltenes further indicate that the Middle-Upper Ordovician may be the main source rocks for heavy oils from the Lunnan and Tabe oilfields.     

An invariance in the carbazoles of petroleum

A remarkable invariance in the ratio of 1,3-dimethylcarbazole （DMC） to 1,6-DMC was discovered in crude oils from the Pearl River Mouth Basin, South China Sea. The remarkably invariant ratio is kept at a constant of about unity regardless of their concentrations, sources or maturities for the sampies. In combination with the molecular structures of 1,3- and 1,6-DMCs, the invariance might indicate that the nitrogen compounds share a common precursor with a skeleton of 1-methylcarbazole and are formed through methylation at C3 and C6 with an essentially identical rate.     

土地利用总体规划实施评价与修编的研究

本文在客观评价上一轮土地利用总体规划的基础上，结合新一轮土地利用总体规划修编的背景和国家宏观调控下的土地政策变化趋势，提出了当前福建省土地利用总体规划修编和今后实施的有关建议，以更好地指导新一轮土地利用总体规划的修编工作。     

庙岛群岛旅游资源评估与可持续利用

庙岛群岛旅游资源丰富。本文运用特尔斐法（Delphi）及层次分析法（AHP）构建庙岛群岛旅游资源开发价值评估模型，定性与定量相结合，对10个条件适宜的岛屿进行评估。进而提出优化庙岛群岛旅游资源空间结构，实现可持续利用的若干对策。     

云南东北部拱王山末次冰期

1 Introduction The Gongwang mountains constitute one of the few high m ountains of irrefutable late Pleistocene glaciation in eastern China. This area is one of the m ost extensively studied Quaternary geologicallocationsin eastern China and the interpret…     

Grassland productivity in an alpine environment in response to climate change

Situated in a climatically stressful environment, alpine grassland is sensitive to subtle climate changes in its productivity. We remedy the current deficiency in studying grassland productivity by taking the integrated effect of all relevant factors into consideration. The relative importance of temperature, rainfall and evaporation to the alpine grassland productivity in western China was determined through analysis of their relationship with the normalized difference vegetation index (NDVI) between 1981 and 2000. Climate warming stimulated grassland productivity in the 1980s, but hampered it in the 1990s. Temperature is more important than rainfall to grassland productivity early in the growing season. However, their relative importance is reversed late in the growing season. Monthly summer month rainfall modified by maximum monthly temperature is a good predictor of alpine grassland productivity at 62.0 per cent. However, the best predictor is water deficiency, which is able to improve the estimation accuracy to 78.3 per cent. Hence, the impact of temperature on grassland productivity is better studied indirectly through evaporation.     

Gas accumulation from oil cracking in the eastern Tarim Basin: A case study of the YN2 gas field

Oil and gas exploration in eastern Tarim Basin, NW China has been successful in recent years, with several commercial gas accumulations being discovered in a thermally mature to over-mature region. The Yingnan2 (YN2) gas field, situated in the Yingnan structure of the Yingjisu Depression, produces gases that are relatively enriched in nitrogen and C₂₊ alkanes. The δ¹³C₁ (−38.6‰ to −36.2‰) and δ¹³C₂ values (−30.9‰ to −34.7‰) of these gases are characteristic of marine sourced gases with relatively high maturity levels. The distributions of biomarkers in the associated condensates suggest close affinities with the Cambrian–Lower Ordovician source rocks which, in the Yingjisu Sag, are currently over-mature (with 3–4%Ro). Burial and thermal maturity modeling results indicate that paleo-temperatures of the Cambrian–Lower Ordovician source rocks had increased from 90 to 210 °C during the late Caledonian orogeny (458–438 Ma), due to rapid subsidence and sediment loading. By the end of Ordovician, hydrocarbon potential in these source rocks had been largely exhausted. The homogenization temperatures of hydrocarbon fluid inclusions identified from the Jurassic reservoirs of the YN2 gas field suggest a hydrocarbon emplacement time as recent as about 10 Ma, when the maturity levels of Middle–Lower Jurassic source rocks in the study area were too low (<0.7%Ro) to form a large quantity of oil and gas. The presence of abundant diamondoid hydrocarbons in the associated condensates and the relatively heavy isotopic values of the oils indicate that the gases were derived from thermal cracking of early-formed oils. Estimation from the stable carbon isotope ratios of gaseous alkanes suggests that the gases may have been formed at temperatures well above 190 °C. Thus, the oil and gas accumulation history in the study area can be reconstructed as follows: (1) during the late Caledonian orogeny, the Cambrian–Lower Ordovician marine source rocks had gone through the peak oil, wet gas and dry gas generation stages, with the generated oil and gas migrating upwards along faults and fractures to form early oil and gas accumulations in the Middle–Upper Ordovician and Silurian sandstone reservoirs; (2) since the late Yanshanian orogeny, the early oil accumulations have been buried deeper and oil has undergone thermal cracking to form gas; (3) during the late Himalayan orogeny, the seals for the deep reservoirs were breached; and the gas and condensates migrated upward and eventually accumulating in the relatively shallow Jurassic reservoirs.     

Migrating pingos in the permafrost region of the Tibetan Plateau, China and their hazard along the Golmud–Lhasa railway

Most pingos in the permafrost region of the high northern Tibetan Plateau form along active fault zones and many change position annually along the zones and thus appear to migrate. The fault zones conduct geothermal heat, which thins permafrost, and control cool to hot springs in the region. They maintain ground-water circulation through broken rock in an open system to supply water for pingo growth during the winter in overlying fluvial and lacustrian deposits. Springs remain after the pingos thaw in the summer. Fault movement, earthquakes and man's activities cause the water pathways supplying pingos to shift and consequently the pingos migrate.

The hazard posed to the new Golmud–Lhasa railway across the plateau by migrating pingos is restricted to active fault zones, but is serious, as these zones are common and generate large earthquakes. Pingos have damaged the highway and the oil pipeline adjacent to the railway since 2001. One caused tilting and breaking of a bridge pier and destroyed a highway bridge across the Chumaerhe fault. Another has already caused minor damage to a new railway bridge. Furthermore, the construction of a bridge pier in the North Wuli fault zone in July–August 2003 created a conduit for a new spring, which created a pingo during the following winter. Measures taken to drain the ground-water via a tunnel worked well and prevented damage before the railway tracks were laid. However, pier vibrations from subsequent train motion disrupted the drain and led to new springs, which may induce further pingo growth beneath the bridge.

The migrating pingos result from active fault movement promoting artesian ground-water circulation and changing water pathways under the seasonal temperature variations in the permafrost region. They pose a serious hazard to railway construction, which, in turn can further disturb the ground-water conduits and affect pingo migration.     

程裕淇主编《中国地层典》记失

文章列数了《中国地层典》5个方面的重要失误:不是中国地层名称全览性的工具书,急于采用处于争议中的术语,大量地层单位名称的出处因考证不到位而形成张冠李戴,采用的历史优先律不是国际共识,在编撰过程中建立新名称。文章用选出的泰山杂岩、滹沱系、秦岭片岩和仑山石灰岩4个名称为例说明《中国地层典》对其出处的考证不到位,进而论证《中国地层典》的诸多解释可信度低。文章严肃地指出“历史优先律”给中国地层学造成的不良后果:它破坏了地层命名法的标准性,颠倒了中国地层命名史,干扰了中国地层名称的管理。     

甘肃华亭地区铀矿化信息遥感提取方法

从分析ETM各波段图像的信息特征入手,在黄土覆盖等环境因素干扰严重的地区,利用遥感技术对其铀矿化的信息进行了提取.在ERDAS软件的支持下,应用图像融合、波段比值、主成分分析、光谱指数等技术方法,对ETM遥感影像数据进行增强处理.其中,图像融合与传统的图像融合略有不同,是在进行图像融合前将原始图像（ETM1～5,7）进行低通滤波处理,使得融合后的图像既保留高分辨率数据的空间信息,又保留低分辨率数据的光谱信息.在对研究区的遥感数据进行增强处理后,选取有利波段组合,圈定了有利铀成矿的远景区.