Efficacy of Hollow‐Fiber Ultrafiltration for Microbial Sampling in Groundwater

The goal of this study was to test hollow‐fiber ultrafiltration as a method for concentrating in situ bacteria and viruses in groundwater samples. Water samples from nine wells tapping a shallow sandy aquifer in a densely populated village in Bangladesh were reduced in volume approximately 400‐fold using ultrafiltration. Culture‐based assays for total coliforms and Escherichia coli, as well as molecular‐based assays for E. coli, Bacteroides, and adenovirus, were used as microbial markers before and after ultrafiltration to evaluate performance. Ultrafiltration increased the concentration of the microbial markers in 99% of cases. However, concentration factors (CF = post‐filtration concentration/pre‐filtration concentration) for each marker calculated from geometric means ranged from 52 to 1018 compared to the expected value of 400. The efficiency was difficult to quantify because concentrations of some of the markers, especially E. coli and total coliforms, in the well water (WW) collected before ultrafiltration varied by several orders of magnitude during the period of sampling. The potential influence of colloidal iron oxide precipitates in the groundwater was tested by adding EDTA to the pre‐filtration water in half of the samples to prevent the formation of precipitates. The use of EDTA had no significant effect on the measurement of culturable or molecular markers across the 0.5 to 10 mg/L range of dissolved Fe²⁺ concentrations observed in the groundwater, indicating that colloidal iron did not hinder or enhance recovery or detection of the microbial markers. Ultrafiltration appears to be effective for concentrating microorganisms in environmental water samples, but additional research is needed to quantify losses during filtration.     

Iodine and bromine contents in the Palaeoproterozoic Hotazel iron formation, Transvaal Supergroup, South Africa: A reconnaissance study

A reconnaissance bulk geochemical study was carried out on ten samples from the Palaeoproterozoic Hotazel iron formation, South Africa, with emphasis on iodine and bromine abundances. Very low-absolute contents recorded for both halogens, i.e. 0.08–0.26 μg/g for I and 0.35–1.23 μg/g for Br, indicate that they should largely have been lost during burial diagenesis. Bulk I/Br ratios (0.08–0.50), however, show marginal variation across the selected sample set and broadly resemble those that typify recent marine sediments containing organic matter. The possibility emerges that both elements are organic matter-sourced and may thus provide a potential proxy for the role of biological processes during deposition and diagenesis of Precambrian iron formations.     

Unprecedented rates of landslide and surface erosion along a newly constructed road in Yunnan, China

Field measurements conducted 4 years after the construction of a new portion of the Weixi?CShangri-La road in Yunnan, China, reveal that unprecedented rates of mass wasting occurred along the road with much of this sediment directly impacting the headwaters of the Mekong River. Landslide erosion (including dry ravel) exceeded 33,000 t ha^?1 year^?1 along the most severely eroded sections of the road and averaged more than 9,600 t ha^?1 year^?1 along the surveyed 23.5 km of road; these values are the highest ever reported for road-related landslides. While surface erosion was only about 7% of the total erosion from the road, it is still more than an order of magnitude higher than typical surface erosion rates from disturbed lands in Southeast Asia. Combined landslide and surface erosion from this road delivered an estimated 19 times more sediment to the river than the remaining 99.6% of the contributing catchment. These sediment inputs are aggrading local channels, promoting downstream sediment transport, degrading aquatic habitat, and creating the possibility for a future debris flood or hyperconcentrated flow.     

Experimental determination of F and Cl partitioning between lherzolite and basaltic melt

We experimentally determined F and Cl partition coefficients together with that of 19 trace elements (including REE, U-Th, HFSE and LILE) between basaltic melt and lherzolite minerals: olivine, orthopyroxene, clinopyroxene, plagioclase and garnet. Under conditions from 8 to 25 kbars and from 1,265 to 1,430°C, compatibilities of F and Cl are globally ordered as D ^Cpx/melt > D ^Opx/melt > D ^Grt/melt > D ^Ol/melt > D ^Plag/melt, and D _F ^mineral/melt is larger than D _Cl^mineral/melt. Four other major results were brought to light. (1) Chlorine partition coefficients positively correlate with the jadeite component in orthopyroxene, and increase of the CaTs component promotes Cl incorporation in clinopyroxene. (2) Variations of fluorine partition coefficients correlate strongly with melt viscosity. (3) F and Cl partition coefficients correlate with the Young’s modulus (E ₀) of pyroxene octahedral sites (M sites) and with Raman vibrational modes of pyroxenes. This demonstrates a fundamental interaction between the M site of pyroxenes and the incorporation of F and Cl. (4) We also determined the parameters of the lattice-strain model applied to 3+ cation trace elements for the two M sites in orthopyroxene and clinopyroxene: D ₀^M1, D ₀^M2, r ₀^M1, r ₀^M2, E ₀^M1 and E ₀^M2.     

Granulite formation in a Gondwana fragment: petrology and mineral equilibrium modeling of incipient charnockite from Mavadi, southern India

We report a new occurrence of incipient charnockite from Mavadi in the Trivandrum Granulite Block (TGB), southern India, and discuss the petrogenesis of granulite formation in an arrested stage on the basis of petrography, geothermobarometry, and mineral equilibrium modeling. In Mavadi, patches and lenses of charnockite (Kfs?+?Qtz?+?Pl?+?Bt?+?Grt?+?Opx?+?Ilm?+?Mag) of about 30 to 220 cm in length occur within Opx-free Grt-Bt gneiss (Kfs?+?Qtz?+?Pl?+?Bt?+?Grt?+?Ilm). The application of mineral equilibrium modeling on the charnockite assemblage in the NCKFMASHTO system to constrain the conditions of charnockitization defines a P–T range of 800 °C at 4.5 kbar to 850 °C at 8.5 kbar, which is broadly consistent with the results from the conventional geothermobarometry (810–880 °C at 7.7–8.0 kbar) on these rocks. The P–T conditions are lower than the peak metamorphic conditions reported for the ultrahigh-temperature granulites from this area (T?>?900 °C). The heterogeneity in peak P–T conditions within the same crustal block might be related to local buffering of metamorphic temperatures by the Opx-Bt-Kfs-Qtz assemblage. The result of T versus mole H₂O (M(H₂O)) modeling demonstrated that the Opx-free assemblage in the Grt-Bt gneiss is stable at M(H₂O)?=?0.3 to 1.5 mol%, and orthopyroxene occurs as a stable mineral at M(H₂O) <0.3 mol%, which is consistent with the petrogenetic model of incipient charnockite related to the lowering of the water activity and stabilization of orthopyroxene through the breakdown of biotite by dehydration caused by the infiltration of CO₂-rich fluid from external sources. We also propose a possible alternative mechanism to form charnockite from Grt-Bt gneiss through slight variations in bulk-rock chemistry (particularly for the K- and Fe-rich portion of Grt-Bt gneiss) that can enhance the stability of orthopyroxene rather than that of biotite, with K-metasomatism playing a possible role.     

Chromitite and peridotite from Rayat, northeastern Iraq, as fragments of a Tethyan ophiolite

Ophiolitic rocks (chromitites and serpentinized peridotites) were petrologically examined in detail for the first time from Rayat, in the Iraqi part of the Zagros thrust zone, an ophiolitic belt. Almost all the primary silicates have been altered out, but chromian spinel has survived from alteration and gives information about the primary petrological characteristics. The protolith of the serpentinite was clinopyroxene-free harzburgite with chromian spinel of intermediate Cr# (= Cr/[Cr + Al] atomic ratio) of 0.5 to 0.6. The harzburgite with that signature is the most common in the mantle section of the Tethyan ophiolites such as the Oman ophiolite, and is the most suitable host for chromitite genesis. Except for one sample, which has Cr# = 0.6 for spinel, the Cr# of spinel is high, around 0.7, in chromitite. The variation in Cr# of spinel in chromitite observed here has been also reported in the Oman ophiolite. The peridotite with chromitite pods exposed at Rayat was derived from an ophiolite similar in petrological character to the Oman ophiolite, one of the typical Tethyan ophiolites (fragments of Tethyan oceanic lithosphere). This result is consistent with the previous interpretation based on geological analysis.     

Temperature evolution from the <Emphasis Type="Italic">δ</Emphasis><Superscript>18</Superscript>O record of Hani peat,Northeast China,in the last 14000 years

From the last deglaciation to the Holocene, the Greenland Ice Core (GISP2) δ ¹⁸O records as well as the records of ice-rafted debris on the surface of the North Atlantic have revealed a succession of sudden cooling events on the centennial to millennial scales. However, the temperature proxy records are rarely studied systematically and directly to ensure that this air temperature cooling pattern simultaneously existed in the East Asian Region, in addition to the repeated pattern occurring in the Greater Atlantic Region. A peat cellulose δ ¹⁸O temperature proxy record proximately existing for 14000 years was picked up from the Hani peat in Jilin Province, China. It suggests by comparison that the sudden cooling events, such as the Older Dryas, Inter-Allerød, Younger Dryas, and nine ice-rafted debris events of the North Atlantic, are almost entirely reiterated in the temperature signals of Hani peat cellulose δ ¹⁸O. These cooling events show that the repeatedly occurring temperature cooling pattern not only appeared in the North Atlantic Region in the high latitudes, but also in the Northwest Pacific Region in the middle latitudes. The climate change events marking the start of the Holocene Epoch, the Holocene Megathermal, the “8.2 kyr” event, the “4.2 kyr” event, the Medieval Warm Period, and the Little Ice Age are further discussed. The sensitivity response of Hani peat cellulose δ ¹⁸O to the land surface temperature and the reason for the age accuracy of peat cellulose ¹⁴C are also discussed based on the characteristics of the peat bog environment.     

Quantification of the effect of forest harvesting versus climate on streamflow cycles and trends in an evergreen broadleaf catchment

ABSTRACT

A new method known as Unobserved Components–Dynamic Harmonic Regression (UC-DHR) was applied to a 39-year record of rainfall and streamflow for three sub-catchments of the Sarukawa Experimental Watershed in southwestern Japan. Some 25% of the timber was harvested from one of the sub-catchments in May–July 1982 and the objective was to quantify the magnitude of this effect relative to the effects of climate cycles (e.g. Southern Oscillation Index). The observed effects of inter-annual climate cycles (i.e. 0.89–1.36 mm/d) were seen to be comparable (i.e. 0.70–1.17 mm/d) to the effects of harvesting 25% of the standing timber. This result underlines the importance of always quantifying the effect of climate on streamflow response when harvesting impacts are studied.

Editor D. Koutsoyiannis; Associate editor T. Okruszko