Factors Controlling the Fractionation and Seasonal Mobility Variations of Ga and In in Systems Impacted by Acidic Thermal Waters: Effects of Thermodynamics and Bacterial Activity

This work assessed both the fractionation and the seasonal mobility variations of Ga and In in systems impacted by acidic thermal waters. This was accomplished by performing thermodynamic calculations using the PHREEQC algorithm and by assessing the activity of acidophilic iron-oxidizing bacteria. The pH of the Kusatsu thermal waters in Gunma Prefecture, central Japan, is rapidly increased following the addition of a lime suspension. After an abrupt pH increase, under which conditions free ions of Ga and In and their complexes with Cl^? and SO₄^2? exist only in negligible quantities, the majority of dissolved Ga and In is removed by sorption onto suspended hydrous ferric oxides (HFOs). These HFOs are then transported to an artificial lake without significant sedimentation along the river. Subsequently, the suspended HFOs settle out and are added to sediments without significant fractionation between Ga and In. The Tamagawa thermal waters in Akita Prefecture, northeast Japan, are also treated with lime. However, complete neutralization requires mixing with some tributary streams, leading to a gradual downstream increase in pH. Dissolved Ga is, in general, sorbed by HFOs in upstream areas, leading to wide dispersal of Ga across the entire watershed. In comparison, In is transported to the lake inlet predominantly as a Cl^? complex species without significant removal along the river, with the majority being precipitated in an artificial lake, where Cl^? concentrations are too low to form stable complex species with In, and thus, dissolved In is sorbed by HFOs. As a result, In is effectively concentrated within downstream lakebed sediments, whereas Ga is dispersed along the river. Seasonal variations in Ga mobility within the Tamagawa field between snowmelt and low-flow seasons are primarily controlled by pH, because hydrolysis reactions of these metals, which are related to sorption reactions, tend to occur in the upstream regions in the snowmelt season. However, under warmer conditions, HFO formation preferably occurs due to the activity of acidophilic iron-oxidizing bacteria. Thus, under similar pH variations, dissolved Ga is more effectively removed by HFOs during warmer seasons. On the contrary, because HFOs are abundantly formed in low-flow season, even under colder conditions, before In hydrolysis reaction starts to occur, In mobility is less affected by water temperature and then bacterial activity.     

Jovian magnetosphere-ionosphere current system characterized by diurnal variation of ionospheric conductance

We developed a new numerical model of the Jovian magnetosphere-ionosphere coupling current system in order to investigate the effects of diurnal variation of ionospheric conductance. The conductance is determined by ion chemical processes that include the generation of hydrogen and hydrocarbon ions by solar EUV radiation and auroral electrons precipitation. The model solves the torque equations for magnetospheric plasma accelerated by the radial currents flowing along the magnetospheric equator. The conductance and magnetospheric plasma then change the field-aligned currents (FACs) and the intensity of the electric field projected onto the ionosphere. Because of the positive feedback of the ionospheric conductance on the FAC, the FAC is the maximum on the dayside and minimum just before sunrise. The power transferred from the planetary rotation is mainly consumed in the upper atmosphere on the dayside, while it is used for magnetospheric plasma acceleration in other local time (LT) sectors. Further, our simulations show that the magnetospheric plasma density and mass flux affect the temporal variation in the peak FAC density. The enhancement of the solar EUV flux by a factor of 2.4 increases the FAC density by 30%. The maximum density of the FAC is determined not only by the relationship between the precipitating electron flux and ionospheric conductance, but also by the system inertia, i.e., the inertia of the magnetospheric plasma. A theoretical analysis and numerical simulations reveal that the FAC density is in proportion to the planetary angular velocity on the dayside and to the square of the planetary angular velocity on the nightside. When the radial current at the outer boundary is fixed at values above 30 MA, as assumed in previous model studies, the peak FAC density determined at latitude 73°-74° is larger than the diurnal variable component. This result suggests large effects of this assumed radial current at the outer boundary on the system.     

Options for monitoring and estimating historical carbon emissions from forest degradation in the context of REDD+

Measuring forest degradation and related forest carbon stock changes is more challenging than measuring deforestation since degradation implies changes in the structure of the forest and does not entail a change in land use, making it less easily detectable through remote sensing. Although we anticipate the use of the IPCC guidance under the United Framework Convention on Climate Change (UNFCCC), there is no one single method for monitoring forest degradation for the case of REDD+ policy. In this review paper we highlight that the choice depends upon a number of factors including the type of degradation, available historical data, capacities and resources, and the potentials and limitations of various measurement and monitoring approaches. Current degradation rates can be measured through field data (i.e. multi-date national forest inventories and permanent sample plot data, commercial forestry data sets, proxy data from domestic markets) and/or remote sensing data (i.e. direct mapping of canopy and forest structural changes or indirect mapping through modelling approaches), with the combination of techniques providing the best options. Developing countries frequently lack consistent historical field data for assessing past forest degradation, and so must rely more on remote sensing approaches mixed with current field assessments of carbon stock changes. Historical degradation estimates will have larger uncertainties as it will be difficult to determine their accuracy. However improving monitoring capacities for systematic forest degradation estimates today will help reduce uncertainties even for historical estimates.     

Effects of the Chemical Compositions of Salars de Uyuni and Atacama Brines on Lithium Concentration during Evaporation

During Li recovery from salar brines, Li concentration is typically increased to about 60,000 mg L^?1 by evaporation. We investigated the concentration changes of Li, Na, K, Mg, Cl, SO₄, and B during evaporation of both natural Uyuni and artificial Atacama brines. The Uyuni brine exhibited a maximum Li concentration of 6810 mg L^?1 at 31 days of evaporation, at which point the majority of the Na and K in the brine was removed. The Li concentration decreased with further evaporation due to precipitation as Li₂SO₄, such that the level at the 56 day mark was approximately 4130 mg L^?1. In contrast, the artificial Atacama brine showed no pronounced Li precipitation, even after 54 days, at which point the Li concentration was 21,800 mg L^?1. The initial concentrations of Na and K in the Atacama brine were higher than those in the Uyuni brine, and the Atacama solution still retained K after 54 days of evaporation. The order of precipitation of cation species during the evaporation of both brines was: Na, followed by K, Mg, and Li. Thus, Li precipitation in the Atacama brine might be prevented due to the more favored precipitations of Na and K, such that significant Li removal did not occur in this brine.     

Structure and dynamics of the sudden acceleration of Kuroshio off Cape Shionomisaki

A sudden acceleration of the Kuroshio jet appears off Cape Shionomisaki in the high-resolution (horizontal resolution of 1/36°) JCOPE 2 ocean reanalysis data. Using this dataset, we investigated the structure of the Kuroshio acceleration. The increase in the velocity of the current is accompanied by a downstream flow separation from the coast and an outcrop of cold temperature inshore. The acceleration of Kuroshio appears when it takes a near-shore path. Cape Shionomisaki amplifies the responses to the Kuroshio flow by creating the zonal velocity acceleration toward the downstream region when the Kuroshio flows closer to the coast. The Kuroshio acceleration coincided with the topographic ridge on the continental shelf near Cape Shionomisaki. This relation suggests that the dynamics of the acceleration is linked to the topographic feature. We proposed an explanation of the Kuroshio acceleration using a hydraulic control theory. An analytical solution was applied to the coastal topography around the Kii Peninsula. The solution captured some aspects of the Kuroshio acceleration.     

July 2020 heavy rainfall in Japan: effect of real-time river discharge on ocean circulation based on a coupled river-ocean model

Ocean Dynamics - In July 2020, a stationary atmospheric front over Japan caused persistent, nearly continuous rain for most of the month that resulted in new historical highest rainfall records in...     

Oxygen and carbon isotope zonations of wall rocks around the Kamioka Pb---Zn skarn deposits, central Japan: application to prospecting

Mapping of the oxygen and carbon isotopic composition of hydrothermally altered wall rocks was conducted during blind ore prospecting for Pb---Zn skarn deposits in the Kamioka mining district, central Japan. The wall rocks consist of heterogeneous rock units. Oxygen and carbon isotope ratios were determined for 35 limestones and 33 silicate rocks from the area around the Mozumi deposit (3 km × 3 km) in the Kamioka mining district. The results (δ¹⁸O_spsmow of − 1.1 to + 17.3% and δ¹³C_sppdb of − 5.0 to +4.8% for limestones, and δ¹⁸O_spsmow of −0.8 to + 12.5% for silicate rocks) show isotope zonations of the wall rocks, with lighter isotopic compositions toward the center of mineralization. The isotope zonations likely formed by interaction of thermal waters with the wall rocks during skarn mineralization. The isotopically light zone indicates a higher paleotemperature or higher water-to-rock ratios, and occurs in the footwall of the 7Gohi fault. This structure is spatially related to the distribution of orebodies, indicating that the fault was the main conduit of the ore-forming fluids. The oxygen and carbon isotopic compositions of limestones vary regularly across limestone bodies hosted by the silicate wall rocks, suggesting that the thermal waters were pervasive throughout the wall rocks at the time of mineralization.An isotopically light zone was also found in the southeastern corner of the study area, where significant mineralization had yet to be identified. This suggested an extension of the extinct hydrothermal system to this area, and the possibility of hidden orebodies underneath. Recent drilling in this area has intercepted a zone 45 m thick with a grade of 13.4% Zn, 0.03% Pb and 8 g per metric ton at about 380 m depth.