The relationship between the isotopic content of precipitation and the precipitation amount in tropical regions

General circulation models (GCMs) fitted with stable isotope schemes are widely used to interpret the isotope–climate relationship. However, previous studies have found that the spatiotemporal isotope/precipitation correlation simulated by GCMs is stronger and more widespread than the observed value. To understand the reason for this failure, we investigated the factors influencing the empirically well-known isotope/precipitation relationship, or precipitation amount effect, in the tropics using newly obtained daily precipitation isotope monitoring data over Asia. As in previous studies, we found an apparent correlation between the long-term monthly mean isotopic content and the corresponding precipitation amount (local precipitation) observed at sub-tropical island stations. Furthermore, on a monthly timescale, the isotopic variability of precipitation for these stations was more clearly related to the regional precipitation amount than to local precipitation. This correlation of isotopic content with the regional precipitation amount was observed at the equatorial (Maritime Continent) stations. For these stations, isotope/local precipitation relationships only appeared over longer timescales, with different regression line slopes at each station. However, at the coastal stations, there was a strong linear relationship between the monthly mean isotopic content and corresponding regional precipitation, and regression line slopes were spatially uniform. For the two sub-tropical terrestrial (Indochina Peninsula) stations, the isotopic minimum appeared without any relationship to rainfall amount but usually occurred at the leeward station during the rainy season. These results suggest that the isotopic variations of precipitation did not depend on the ’local’ rain-out history but on the rain-out process in the surrounding region. However, local rainfall events were associated not only with large-scale disturbances but also with regional circulation. Thus, the scale difference of controlling factors between local rainfall amount and isotopic value results in the weakening of the rainfall amount effect at the observation site and in the discrepancy between GCM simulations and observations. This finding suggests that regional precipitation–isotope relationships should be compared with GCM results. Additionally, because the isotope signal reflects the rain-out history at a regional scale, evaluation of the isotopic field using isotopic GCMs will be useful not only to reconstruct paleoclimate conditions but also to examine how GCMs can reproduce real atmospheric circulation over the tropics.     

A static predictor of seismic demand on frames based on a post‐elastic deflected shape

Predictors of seismic structural demands (such as inter‐storey drift angles) that are less time‐consuming than nonlinear dynamic analysis have proven useful for structural performance assessment and for design. Luco and Cornell previously proposed a simple predictor that extends the idea of modal superposition (of the first two modes) with the square‐root‐of‐sum‐of‐squares (SRSS) rule by taking a first‐mode inelastic spectral displacement into account. This predictor achieved a significant improvement over simply using the response of an elastic oscillator; however, it cannot capture well large displacements caused by local yielding. A possible improvement of Luco's predictor is discussed in this paper, where it is proposed to consider three enhancements: (i) a post‐elastic first‐mode shape approximated by the deflected shape from a nonlinear static pushover analysis (NSPA) at the step corresponding to the maximum drift of an equivalent inelastic single‐degree‐of‐freedom (SDOF) system, (ii) a trilinear backbone curve for the SDOF system, and (iii) the elastic third‐mode response for long‐period buildings. Numerical examples demonstrate that the proposed predictor is less biased and results in less dispersion than Luco's original predictor. Copyright © 2006 John Wiley & Sons, Ltd.     

Photometric properties of the Arp 220 super star clusters

We investigate the photometric properties of six super stellar clusters (SSCs) seen in both the optical and near-infrared Hubble Space Telescope images of the local ultraluminous starburst galaxy Arp 220. Three of the SSCs are located in the central 0.5-kpc region. The remaining three are in the circumnuclear region between 0.5 and 2.5 kpc from the centre. Comparing the observed spectral energy distributions (SEDs) of the SSCs with the Starburst99 models of Leitherer et al., we confirm that all three nuclear SSCs are heavily obscured     Considering the results from this comparison in conjunction with measurements of the near-infrared CO absorption index and of millimetre CO linewidths and luminosities, we estimate the ages of the nuclear SSCs to be 10⁷–10⁸ yr. The bolometric luminosity of the three nuclear SSCs is at most one-fifth of the total bolometric luminosity of Arp 220. On the other hand, the circumnuclear SSCs have little internal extinction     These contribute negligibly to the total bolometric luminosity.     

ESR analysis of the Nojima fault gouge, Japan, from the DPRI 500 m borehole

Abstract Electron spin resonance (ESR) analyses of quartz grains in fault gouge were performed for a core sample taken from the Nojima Fault that moved during the 1995 Kobe earthquake (Hyogo-ken Nanbu earthquake). Distribution of radiation-induced defects in the gouge at a depth of 389.4 m was measured by extracting quartz grains from seven discrete positions within 30 mm of the fault plane on the granite side. The decrease in E'₁ and Al centers was observed within 2 mm of the fault plane, suggesting partial annealing due to faulting. Partial annealing even at that depth suggested that conventional ESR dating, which is based on the hypothesis of complete annealing during faulting, was not applicable. Theoretical calculations of the temperature rise and of the thermal annealing of defects have been made by assuming a simple annealing model of heat generation on the fault plane. Thermal energy was calculated to have been approximately 8 MJ/m² to explain the profile of the heat-affected region. Thermal energy was much larger than the one estimated from hydrothermal solution, and corresponded to the frictional heat calculated for a normal stress of 20 MPa, a displacement of 2 m, and a frictional coefficient of 0.2.     

Kuroko and Hydrocarbon Deposits from Northern Honshu,Japan: A Possible Common Hydrothermal/Magmatic Origin?

Abstract. Northern Honshu is the most important area for mineral and oil resources in Japan. Many kuroko deposits and oil and gas fields are distributed in two belts along the northeast Japan arc, the kuroko metal‐belt on the Pacific side and the oil‐belt on the Sea of Japan side. The kuroko deposits are located mainly in the Green Tuff strata which formed as a result of submarine vol‐canism during the late Miocene and Pliocene. Most of the source rocks of the oil and gas deposits formed at the same time as the kuroko deposits and some of them are located in reservoirs of hydrothermally‐altered volcanic rocks in the Green Tuff region. There is general agreement that the kuroko deposits formed as a result of submarine hydrothermal and magmatic activity whereas almost all petroleum geologists and geochemists consider that hydrocarbon deposits were generated independently of such activity. Since the discovery of hydrothermally‐generated petroleum in the Guaymas Basin, Gulf of California, however, it is clear that petroleum can be formed almost instantaneously in terrestrial and submarine hydrothermal areas. The paleo‐northeastern Sea of Japan is therefore considered to be a potential area for hydrothermal petroleum generation because thick organic‐rich sediments overlie an active submarine volcanic area. Several lines of geological and geochemical evidence suggest the possibility of hydrothermally‐enhanced maturation of organic matter and the contribution of magmatic activity to the formation of these deposits. Although most of the oil and gas in northern Honshu has been generated conventionally as a consequence of the high geothermal gradients there, it appears that some of the oil and gas fields may have formed as a result of extensive hydrothermal and magmatic activity during the late Miocene to Pliocene. Because of the much steeper angle of the faults in the vicinity of the Hokuroku basin than in the Akita basin, the magmatic contribution to the kuroko mineralization would have been far greater than to the oil and gas deposits of the Niigata and Akita basins. We therefore propose a strong relationship between metal and oil and gas generation in northern Honshu based on the structure and tectonics of the northern Honshu arc‐backarc system.     

Bonding character of SiO2 stishovite under high pressures up to 30 Gpa

 The charge density and bond character of the rutile-type structure of SiO₂ (stishovite) under compression to 30 GPa were investigated by X-ray diffraction study using synchrotron radiation and AgKα rotating anode X-ray generator through a newly devised diamond-anvil cell. The valence electron density was determined by least-squares refinement including the κ parameter and the electron population in the X-ray atomic scattering parameters. The oxygen κ-parameter of SiO₂ is 0.94 under ambient conditions and 1.11 at 29.1 GPa and the silicon valence changes from +2.12(8) at ambient pressure to +2.26(15) at 29.1 GPa. These values indicate that the electron distributions are more localized with increasing pressure. The difference Fourier map shows the deformation of the valence electron distribution and the bonding electron population in residual electron densities. The bonding electron observed from the X-ray diffraction study is interpreted by molecular orbital calculations. The deformation of SiO₆octahedra and the bonding electron density of stishovite structures are elucidated from the overlapping electron orbits. The O–O distances of shared and unshared edge of SiO₆ octahedra change with the cation ionicity. The repulsive force between the two cations in the adjacent octahedron makes its shared edge shorter. The pressure changes of the apical and equatorial Si–O interatomic distances are explained by the electron density of state (DOS) of Si and electron configuration. Received: 7 January 2002 / Accepted: 6 May 2002     

Unique Geochemistry of Sedimentary Iron Deposit Formed by Biologically Induced Mineralization

Abstract: Major, trace, and rare earth element contents were determined for sedimentary iron ores from the Gunma iron deposit. The deposit was precipitated from a spring water on the hillside of the active Kusatsu-Shirane Volcano. The ores are mainly composed of goethite and jarosite with various proportions of silicified andesitic detritus. Microbial fossils are often preserved well in goethite-rich ores. Goethite was likely precipitated by both inorganic and biogenic (biologically induced mineralization; BIM) processes, whereas jarosite was precipitated inorganically from the spring water. Si, Ti, Al, Mn, Mg, Ca, Na, Co, Rb, Y, Zr, Nb, Hf, Ta, U, and middle-heavy REEs (Sm-Lu) in the ores are dominantly derived from a detrital component (silicified andesitic rocks). On the other hand, Zn and V are likely to have been inorganically coprecipitated with goethite. Preferential uptake of P, Sc, Cu, Mo, Ba, Th, and light REEs occurs in the BIM ores. Unique enrichment of these elements is a promising indicator of biomineralization for ancient sedimentary iron deposits.     

Sequential high-pressure transformations of FeGeO3 high-P clinopyroxene (C 2 /c) at temperatures up to 365 ¯C

 In order to elucidate high-pressure transformations of high-P clinopyroxene (C2/c) at kinetically low temperature where atoms are not thermally activated, the transformation processes of FeGeO₃ clinopyroxene (C2/c) have been investigated at pressures up to 20 GPa and 365 °C by powder X-ray diffraction using a synchrotron radiation source and TEM observation. With increasing pressure up to 20 GPa at room temperature, FeGeO₃ high-P clinopyroxene (C2/c) reversibly transforms into a new high-pressure phase, FeGeO₃(II). On increasing the temperature up to 365 °C, this phase rapidly transforms into FeGeO₃ ilmenite within about 2 h. Intensity analysis of the X-ray diffraction pattern reveals that the high-pressure phase of FeGeO₃(II) has an intermediate structure between clinopyroxene and ilmenite: the cation arrangement is similar to that of clinopyroxene and the oxygen arrangement is similar to that of ilmenite. The comparison of the crystal structures of these polymorphs suggests that clinopyroxene to FeGeO₃(II) and FeGeO₃(II) to ilmenite transformations are performed by the slight deformation of the oxygen packing and the short-range movement of cations, respectively. It is shown that this high-P clinopyroxene transforms into ilmenite through a low-activation energy path under the low-temperature condition. Received: 30 August 2000 / Accepted: 10 February 2001