Ocean anoxic events in the mid-Cretaceous simulated by a 3-D biogeochemical general circulation model

The mid-Cretaceous is well known for its ocean anoxic events. The causal mechanisms are controversial: stagnant deepwater, high biological productivity in the surface waters, and other possibilities have been suggested. Our study simulated the mid-Cretaceous ocean, using general circulation models combined with a marine biogeochemical cycle model to explore the relationship between thermohaline circulation and biogeochemical cycles and investigate the causes of ocean anoxic events. The simulated thermohaline circulation shows an unsteady inactive state. Oxygen concentrations in the deepwater decrease under the inactive state, but a horizontal gradient develops, with higher oxygen concentrations in the Tethys and lower concentrations in eastern Panthalassa. This is not due to the different ages of the deepwater but rather to the differences in biological productivity in the surface water, meaning that the relationship between thermohaline circulation and biogeochemical cycles under the inactive state is different from that in the present ocean. In the standard simulation, assuming the present level of the total amount of phosphate in the ocean, 29% of the bottom water is anoxic. The experiments increasing the amount of phosphate show its high sensitivity for extending the anoxic region with global-scale anoxia simulated under the doubled amount of phosphate. The high amount of phosphate would be reasonable because the inactive state would induce an imbalance of phosphate between riverine input and sediment output. Therefore, both the inactive thermohaline circulation and the increase in the total amount of phosphate in the ocean induce the global-scale anoxic condition in the deepwater.     

Roles of Physical Processes in the Carbon Cycle Using a Simplified Physical Model

A simplified physical model is proposed in this article to describe differences among basins in substance distributions which were not well described by previous simplified models. In the proposed model, the global ocean is divided into the Pacific/Indian Ocean (PI), the Atlantic Ocean (AT), the Southern Ocean and the Greenland/Iceland/Norwegian Sea. The model is consisted of five physical parameters, namely the air-sea gas exchange, the thermohaline circulation, the horizontal and vertical diffusions, and the deep convection in the high-latitude regions. Individual values of these parameters are chosen by optimizing model distribution of natural ¹⁴C as a physical tracer. The optimal value for a coefficient of vertical diffusion in the low-latitude region is 7.5 × 10^–5 [m²s^–1]. Vertical transports by the Antarctic Bottom Water and the North Atlantic Deep Water are estimated at 1.0 Sv and 9.0 Sv. Global-mean air-sea gas exchange time is calculated at 9.0 years. Using these optimal values, vertical profiles of dissolved inorganic carbon without biological production in PI and AT are estimated. Oceanic responses to anthropogenic fluctuations in substance concentrations in the atmosphere induced by the industrialization and nuclear bomb are also discribed, i.e., the effects appear significantly in AT while a signal is extremely weak in PI. A time-delay term is effective to make the PI water older near the bottom boundary.     

Late Quaternary faulting along the western margin of the Poronaysk Lowland in central Sakhalin, Russia

Sakhalin Island straddles an active plate boundary between the Okhotsk and Eurasian plates. South of Sakhalin, this plate boundary is illuminated by a series of M_w 7–8 earthquakes along the eastern margin of the Sea of Japan. Although this plate boundary is considered to extend onshore along the length of Sakhalin, the location and convergence rate of the plate boundary had been poorly constrained. We mapped north-trending active faults along the western margin of the Poronaysk Lowland in central Sakhalin based on aerial photograph interpretation and field observations. The active faults are located east of and parallel to the Tym–Poronaysk fault, a terrane boundary between Upper Cretaceous and Neogene strata; the active faults appear to have reactivated the terrane boundary at depth in Quaternary time. The total length of the active fault zone on land is about 140 km. Tectonic geomorphic features such as east-facing monoclinal and fault scarps, back-tilted fluvial terraces, and numerous secondary faults suggest that the faults are west-dipping reverse faults. Assuming the most widely developed geomorphic surface in the study area formed during the last glacial maximum at about 20 ka based on similarities of geomorphic features with those in Hokkaido Island, we obtain a vertical component of slip rate of 0.9–1.4 mm/year. Using the fault dip of 30–60°W observed at an outcrop and trench walls, a net slip rate of 1.0–2.8 mm/year is obtained. The upper bound of the estimate is close to a convergence rate across the Tym–Poronaysk fault based on GPS measurements. A trenching study across the fault zone dated the most recent faulting event at 3500–4000 years ago. The net slip associated with this event is estimated at about 4.5 m. Since the last faulting event, a minimum of 3.5 m of strain, close to the strain released during the last event, has accumulated along the central portion of the active strand of the Tym–Poronaysk fault.     

A Paleogene magmatic overprint on Cretaceous seamounts of the western Pacific

The West Pacific Seamount Province (WPSP) represents a series of short-lived Cretaceous hotspot tracks. However, no intraplate volcanoes in advance of petit-spot volcanism erupted near a trench have been identified after the formation of the WPSP on the western Pacific Plate. This study reports new ages for Paleogene volcanic edifices within the northern WPSP, specifically the Ogasawara Plateau and related ridges, and Minamitorishima Island. These Paleogene ages are the first reported for basaltic rocks on western Pacific seamounts, in an area that has previously only yielded Cretaceous ages. The newly found Paleogene volcanisms overprint the Early–middle Cretaceous volcanic edifices, because the seamount or paleo-island material-covered reefal limestone caps on these edifices are uniformly older than the Paleogene volcanism identified in this study. This study outlines several possible causative factors for the Paleogene volcanism overprinting onto existing Cretaceous seamounts, including volcanism related to lithospheric stress, or a younger hotspot track within the northern part of the WPSP that records magmatism from ~60 Ma.     

Comment on “Evaluation of palaeo-oxygenation of the ocean bottom cross the Permian–Triassic boundary” by Kakuwa (2008): Was the Late Permian deep-superocean really oxic?

Nearly 15 years after the proposal of the superanoxia concept (Isozaki, Y., 1994. Superanoxia across the Permo–Triassic boundary: record in accreted deep-sea pelagic chert in Japan. In: Embry, A.F., Beauchamp, B., Glass, D.J. (Eds.), Pangea: Global Environments and Resources. Memoir, Canadian Society of Petroleum Geologists, 17, pp. 805–812.), it is an appropriate timing to re-evaluate its geological context with the updated dataset. Kakuwa (Kakuwa, Y., 2008. Evaluation of palaeo-oxygenation of the ocean bottom across the Permian–Triassic boundary. Global and Planetary Change 63, 40–56.) lately discussed that the deep-sea anoxia across the Permian–Triassic boundary (P–TB) may have been much shorter than previously proposed, on the basis of ichnofabrics and geochemical data; however, his interpretations of the data do not appear straightforward nor persuading, and thus his claim is likely misled. Here we raise comments to his explanation on the following four issues: 1) invalid application of ichnofabric indices for shallow sea sediments to deep-sea cherts, 2) misinterpretation of Ce anomaly as a redox indicator, 3) improper application of various redox sensitive trace elements, and 4) questionable interpretations of δ³⁴S data of pyrites.     

Contribution of abiogenic and biogenic particles to trace-metal composition of phytoplankton assemblages in seawater of Shimizu Port, Japan

The contribution of abiogenic and biogenic particles to trace-metal (As, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, Sb, Ti, V, and Zn) composition was investigated for phytoplankton (primarily diatoms) collected in Shimizu Port, a coastal seawater region. Except for Cd, the trace metals occurred predominantly in lithogenic or nonlithogenic abiogenic particles associated with plankton. In contrast, it is likely that Cd in seawater is taken up intracellularly, and not adsorbed extracellularly by phytoplankton. The lower P-normalized quotas of Cd in Shimizu Port than in offshore regions may be because plankton are dominated by diatoms.     

Geochemical Features and Tectonic Setting of Greenstones from Kunimiyama, Northern Chichibu Belt, Central Shikoku, Japan

Abstract. We report whole‐rock chemical data for the greenstones from the Kunimiyama area in the Northern Chichibu Belt and their implications on the tectonic setting of these rocks. The Kunimiyama greenstones are associated with stratiform fer‐romanganese deposits or bedded cherts in the northern part of the study area, but are closely associated with a thick limestone block or bedded cherts in the southern part. The constituent minerals of greenstones are albitized plagioclase, clinopy‐roxene, chlorite, calcite, epidote, pumpellyite, prehnite, quartz, celadonite, sericite and opaque minerals such as iron oxyhy‐droxide and hematite. These mineral assemblages, epidote + pumpellyite + chlorite and chlorite + pumpellyite + prehnite, suggest that the metamorphic grade of greenstones from the Kunimiyama area is prehnite‐pumpellyite facies. The whole‐rock chemical compositions of greenstones associated with ferromanganese deposits are generally similar to those of normal mid‐ocean ridge basalt (N‐MORB). In contrast, the chemical compositions of the greenstones associated with the limestone block are comparable to those of ocean island alkaline basalt. Greenstones associated with bedded cherts are of enriched MORB and ocean island basalt, as well as N‐MORB origins, suggesting they probably formed as a result of plume‐related MOR volcanism in the Panthalassa Ocean in Early Permian and by tectonic mixing of ocean island basalts with oceanic ridge crustal fragments during accretion/subduction processes. These geological and geochemical lines of evidence suggest that the Kunimiyama greenstones are allochthonous blocks of accreted oceanic crust and seamounts. The ferromanganese deposits are frequently accompanied by reddish greenstones. Compared to common greenish greenstones, the reddish greenstones are characterized by high MnO and rare earth element contents and distinct negative Ce anomalies, implying a slight contribution of hydro thermal component forming the ferromanganese deposits.     

Validation of precipitation over Japan during 1985–2004 simulated by three regional climate models and two multi-model ensemble means

We dynamically downscaled Japanese reanalysis data (JRA-25) for 60 regions of Japan using three regional climate models (RCMs): the Non-Hydrostatic Regional Climate Model (NHRCM), modified RAMS version 4.3 (NRAMS), and modified Weather Research and Forecasting model (TWRF). We validated their simulations of the precipitation climatology and interannual variations of summer and winter precipitation. We also validated precipitation for two multi-model ensemble means: the arithmetic ensemble mean (AEM) and an ensemble mean weighted according to model reliability. In the 60 regions NRAMS simulated both the winter and summer climatological precipitation better than JRA-25, and NHRCM simulated the wintertime precipitation better than JRA-25. TWRF, however, overestimated precipitation in the 60 regions in both the winter and summer, and NHRCM overestimated precipitation in the summer. The three RCMs simulated interannual variations, particularly summer precipitation, better than JRA-25. AEM simulated both climatological precipitation and interannual variations during the two seasons more realistically than JRA-25 and the three RCMs overall, but the best RCM was often superior to the AEM result. In contrast, the weighted ensemble mean skills were usually superior to those of the best RCM. Thus, both RCMs and multi-model ensemble means, especially multi-model ensemble means weighted according to model reliability, are powerful tools for simulating seasonal and interannual variability of precipitation in Japan under the current climate.     

Development of a Ground-Based LIF Instrument for Measuring HOx Radicals: Instrumentation and Calibrations

An instrument for measuringtropospheric OH/HO₂ radicals by laser-inducedfluorescence developed in our laboratory is presentedin detail. It is based on FAGE (fluorescence assay bygas expansion) technique and OH is both excited anddetected at 308 nm corresponding to its A-X(0,0) band.The alignment of the laser beam, the design of thesample gas inlet, and the devices for the fluorescencedetection are optimized so as to reduce the backgroundsignal while keeping the OH sensitivity as high aspossible. A thermalized position of the expanding gasbeam is probed in our system and we did not observe asevere decrease of the HO_x sensitivities under humidconditions. An optical fiber is used for deliveringthe laser light to the fluorescence detection cellmounted outside at a high position. Thus the laserbeam alignment is by far simplified and is made highlyreproducible, once settled properly. For thecalibration, two methods are employed: a system withlaser absorption measurements of OH and a system ofsimultaneous photolysis of H₂O and O₂. Thecalibration factors are compared well within thecombined uncertainty. Using the latter system, theconversion efficiency of HO₂ to OH by NO additionis measured to be around 90%. The detection limitsfor OH and HO₂ (S/N = 2) are estimated to be3.3 × 10⁶ and 3.6 × 10⁶cm^–3 at noon,respectively, with an integration time of 1 min. Theresults of test observations at our institute are alsopresented.     

Study of the relationship between non-dimensional roughness length and wave age, effected by wave directionality

Relationship between the non-dimensional roughness length and inverse of wave age has been discussed without consideration of wave directions, though wind wave field consists of various directional component waves. In this study we observe wave heights by an array of four wave gauges at the Hiratsuka Tower of (Independent Administrative Institution) National Research Institute for Earth Science and Disaster Prevention (NIED), Japan, and discuss the effect of wave directionality. As a result, the data sets were classified into two different groups according to the directional wave spectrum distribution. In case 1 only swell and wind waves exist and in case 2 there exist wave components from several directions. It is shown that the case of multiple-directional component waves (case 2) may affect the non-dimensional roughness length and friction velocity.