离线固相萃取螯合富集分离-ICP-MS测定海水中的稀土元素

通过测定条件优化、方法比对等实验建立了一种固相萃取小柱离线螯合富集分离电感耦合等离子体质谱仪测定海水中稀土元素的方法。海水样品通过调节p H后,进入VAC ELUT SPS24 Agilent圆形固相萃取装置,其主要基体物质的去除率高于97%;萃取富集的优化条件是海水样品p H 4.0~7.0,海水进入萃取柱速率2 m L/min,硝酸洗脱液浓度为1 mol/L;方法对稀土元素的加标回收率为83%~108%,14种稀土元素的检出限为0.057~0.613 ng/L,RSD10%;该方法与氢氧化铁共沉淀法富集稀土元素比对测定结果一致,方法具有准确度与精密度高、操作简便快速等优点,可用于海水样品中稀土元素的定量精确测量。     

楚科奇海盆M04柱晚更新世以来沉积古环境记录

对"中国第五次北极科考"采自楚科奇海盆的M04柱进行粒度、冰筏碎屑、黏土矿物、岩心XRF扫描、沉积物颜色分析,初步建立了楚科奇海盆晚更新世MIS4期以来的沉积地层框架。MIS4期以来,楚科奇海盆M04柱沉积物粒度和黏土矿物组成具有明显的冰期/间冰期变化特征,冰期沉积物粒度分布以双峰态为主,由洋流搬运和海冰搬运沉积组分组成,伊利石含量高、高岭石含量低;间冰期沉积物具有三峰态粒度分布特征,由海冰搬运、洋流搬运和冰山搬运沉积组分组成,伊利石含量低、高岭石含量高。通过M04柱黏土矿物组合类型与北冰洋边缘海盆的表层沉积物黏土矿物组合类型对比表明,晚更新世以来楚科奇海盆沉积环境发生显著变化:温暖的间冰期受波弗特涡流驱动,波弗特海为研究区的物源输入提供了主要贡献;寒冷的冰期表层环流呈反向输运,细颗粒物源碎屑以东西伯利亚海的输入为主。     

Variations of methane stable isotopic values from an Alpine peatland on the eastern Qinghai-Tibetan Plateau

Acta Geochimica - Isotopic signature is a powerful tool to discriminate methane (CH4) source types and constrain regional and global scale CH4 budgets. Peatlands on the Qinghai-Tibetan Plateau are...     

渤海莱州湾地区晚更新世以来有孔虫特征反映的古环境变化

Controlled by climate changes, there were three large-scale transgressions and regressions around the Bohai Sea during the late Quaternary, which were accepted by most geologists. However, a big controversy still exists about the time when the transgressions occurred separately. In order to find out the process of the paleoenvironmental changes around the Bohai Sea in the late Quaternary, the foraminifera assemblages from a new borehole Lz908 in the southern coast of the Laizhou Bay were studied, and then the transgressive strata were indentified. Combined with accelerator mass spectrometry radiocarbon 14C（AMS14C） and optically stimulated luminescence（OSL） ages, the occurrence time of these transgressions were re-determined. The result showed that three major large-scale transgressions occurred separately at the beginning of marine isotopic stage 7（MIS7）, the last interglacial period（MIS5） and the Holocene. In addition, a small-scale transgression occurred in the mid-MIS6, and the corresponding transgressive stratum was deposited. The transgressive deposition of MIS3 was also discovered in this study. However, the characteristics of the foraminifera indicated the environment during this period was colder than that in the MIS5. By comparison with the global sea-level changes, the paleoenvironmental changes around the Bohai Sea in the late Quaternary can be consistent with the global climate changes.     

南大西洋沉积物中多环芳香化合物的组成特征研究

10 samples of sediments obtained from the South Mid-Atlantic Ridge were measured for the abundances and distributions of polycyclic aromatic compounds(PAHs). The total concentrations of PAHs(∑PAHs) ranged from 2.768 to 9.826 μg/g dry sediment. The ∑PAHs was higher in sample 22V-TVG10 and sample 26V-TVG05 which were close to hydrothermal fields, with the lowest value in sample 22V-TVG14 which was farthest from hydrothermal fields, suggesting a probable hydrothermal origin of ∑PAHs of samples. Approximately nine kinds of PAHs were identified, and low molecular mass tricyclic and tetracyclic aromatic compounds were predominant in the samples. The concentrations of fluoranthene which were typical as hydrothermal alteration compounds were the highest among PAHs with dry weight between 0.913–3.157 μg/g. The phenanthrene homologue was most abundant in the samples, and the ratios between parent phenanthrene and methylphenanthrene which probably reflected the degree of hydrothermal alteration ranged from 0.097 to 1.602. The sample 22V-TVG10 possessing a maximum ratio value showed the intense influence of the hydrothermal alteration on this sample, which might further imply that PAHs in sediments were mainly derived from the hydrothermal alteration.     

关于天气预报问题

天气预告昔日各国完全采用经验法(Empirical method);自挪威学旅之气团分析,及极面学说发生以後,最近各国已次续采纳。我国在十年前,竺可桢氏已有介绍文章,吕炯先生在数年前亦曾应用极面学说分析长江下游之风暴。其後有黄厦千,赵九章,朱炳海诸先生亦曾致力於气团分析工作,皆具卓见。近日有涂长望先生之中国气团分     

降雨对浅层水流阻力的影响

通过实验室人工降雨水槽试验,研究了降雨影响下浅层水流的阻力规律。根据试验中观察到的物理现象及对实测资料的分析,讨论了降雨对浅层水流特性的影响,提出了"伪层流"的概念,建立了不同流区的Darcy-Weisbach阻力系数∫的估算式。研究成果可用于坡面流计算及土壤侵蚀模拟等方面。     

多点地质统计学建模研究进展

从精细油藏描述中地质建模的意义和现状入手,介绍了多点地质统计学建模研究现状及其与传统地质建模方法的差 异。以辽河盆地西部凹陷某蒸汽驱试验区为例,分析了多点地质统计学建模中建模的基础、训练图像的建立、多点地质统计学 建模与传统地质建模相比所具有的优势等内容。指出多点地质统计学在井间预测方面具有明显优于其他传统建模方法的特 点。在文献调研基础上,结合自身工作实践,探讨了多点地质统计学建模目前存在的问题和未来的发展方向。指出未来多点 地质统计学建模的发展方向主要包括多信息综合地质成因分析基础上的训练图像获取、多点地质统计学算法进行改进和完善 和多点地质统计学建模方法应用领域的扩大等。     

太湖地区HJ-1卫星CCD数据反演气溶胶及大气校正

针对HJ-1卫星CCD数据,利用改进的暗像元法反演气溶胶光学厚度(AOD),再利用反演的AOD对其进行大气校正。将反演的气溶胶与地基太阳光度计数据进行对比验证,发现当反演的AOD值大于0.2时,反演值与地基观测值的相关系数为0.964,符合MODIS业务化反演AOD的精度要求。再将反演得到的气溶胶带入6S辐射传输模型中,对HJ-1卫星CCD数据进行大气校正实验。结果表明,该方法能有效提高HJ-1卫星CCD数据大气校正的精度,更好地复原地物的真实光谱信息。     

长江三峡地区的夷平面在宜昌地区白垩纪—第四纪沉积物中的反映

通过对湖北宜昌地区白垩纪-第四纪沉积演化的研究,发现存在3个明显的沉积旋回,每个旋回由下部颗粒粗大的砾石层和上部颗粒较细小的粉砂-泥质层组成。3个沉积旋回对应了宜昌以西三峡地区3期构造演化旋回,同时反映了三峡地区3期夷平面的存在。结合前人研究结果、古生物化石和对第四系善溪窑组的测年数据,认为3期夷平面形成时代分别为:鄂西期夷平面形成于白垩纪晚期-古近纪的始新世,山原期夷平面形成于上新世-早更新世初,云梦期夷平面形成于早更新世末-中更新世早期。