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121.
A numerical study of mechanical behavior of a cement paste under mechanical loading and chemical leaching 下载免费PDF全文
Based on relevant experimental data of a petroleum cement paste under mechanical loading and chemical leaching, an elastic‐plastic model is first proposed by taking into account plastic shearing and pore collapse. The degradation of mechanical properties induced by the chemical leaching is characterized by a chemical damage variable which is defined as the increase of porosity. Both elastic and plastic properties of the cement paste are affected by the chemical damage. The proposed model is calibrated from and applied to describe mechanical responses in triaxial compression tests respectively on sound and fully leached samples. In the second part, a phenomenological chemical model is defined to establish the relationship between porosity change and calcium dissolution process. The dissolution kinetics is governed by a diffusion law taking into account the variation of diffusion coefficient with calcium concentration. The chemical model is coupled with the mechanical model, and both are applied to describe mechanical response of cement paste samples subjected to progressive chemical leaching and compressive stresses. Comparisons between experimental data and numerical results are presented. 相似文献
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Zhongwu Li Hao Peng Binggeng Xie Chun Liu Xiaodong Nie Danyang Wang Mei Huang Haibing Xiao Lin Shi Xuqin Zhang Jieyu Jiang 《水文研究》2020,34(6):1446-1459
Exploring the chemical characterization of dissolved organic matter (DOM) is important for understanding the fate of laterally transported organic matter in watersheds. We hypothesized that differences in water-extractable organic matter (WEOM) in soils of varying land uses and rainfall events may significantly affect the quality and the quantity of stream DOM. To test our hypotheses, characteristics of rainfall-runoff DOM and WEOM of source materials (topsoil from different land uses and gullies, as well as typical vegetation) were investigated at two adjacent catchments in the Loess Plateau of China, using ultraviolet–visible absorbance and excitation emission matrix fluorescence with parallel factor analysis (PARAFAC). Results indicated that land-use types may significantly affect the chemical composition of soil WEOM, including its aromaticity, molecular weight, and degree of humification. The PARAFAC analysis demonstrated that the soils and stream water were dominated by terrestrial/allochthonous humic-like substances and microbial transformable humic-like fluorophores. Shifts in the fluorescence properties of stream DOM suggested a pronounced change in the relative proportion of allochthonous versus autochthonous material under different rainfall patterns and land uses. For example, high proportions of forestland could provide more allochthonous DOM input. This study highlights the relevance of soils and hydrological dynamics on the composition and fluxes of DOM issuing from watersheds. The composition of DOM in soils was influenced by land-use type. Precipitation patterns influenced the proportion of terrestrial versus microbial origins of DOM in surface runoff. Contributions of allochthonous, terrestrially derived DOM inputs were highest from forested landscapes. 相似文献
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Mingjuan Xie Geping Luo Olaf Hellwich Amaury Frankl Wenqiang Zhang Chunbo Chen Chen Zhang Philippe De Maeyer 《水文研究》2021,35(12):e14444
The study of water fluxes is important to better understand hydrological cycles in arid regions. Data-driven machine learning models have been recently applied to water flux simulation. Previous studies have built site-scale simulation models of water fluxes for individual sites separately, requiring a large amount of data from each site and significant computation time. For arid areas, there is no consensus as to the optimal model and variable selection method to simulate water fluxes. Using data from seven flux observation sites in the arid region of Northwest China, this study compared the performance of random forest (RF), support vector machine (SVM), back propagation neural network (BPNN), and multiple linear regression (MLR) models in simulating water fluxes. Additionally, the study investigated inter-annual and seasonal variation in water fluxes and the dominant drivers of this variation at different sites. A universal simulation model for water flux was built using the RF approach and key variables as determined by MLR, incorporating data from all sites. Model performance of the SVM algorithm (R2 = 0.25–0.90) was slightly worse than that of the RF algorithm (R2 = 0.41–0.91); the BPNN algorithm performed poorly in most cases (R2 = 0.15–0.88). Similarly, the MLR results were limited and unreliable (R2 = 0.00–0.66). Using the universal RF model, annual water fluxes were found to be much higher than the precipitation received at each site, and natural oases showed higher fluxes than desert ecosystems. Water fluxes were highest during the growing season (May–September) and lowest during the non-growing season (October–April). Furthermore, the dominant drivers of water flux variation were various among different sites, but the normalized difference vegetation index (NDVI), soil moisture and soil temperature were important at most sites. This study provides useful insights for simulating water fluxes in desert and oasis ecosystems, understanding patterns of variation and the underlying mechanisms. Besides, these results can make a contribution as the decision-making basis to the water management in desert and oasis ecosystems. 相似文献
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Xue‐Bin Du Xi‐Nong Xie Yong‐Chao Lu Liang Zhang Wei Peng Yun‐Peng Li 《Geological Journal》2015,50(4):465-476
Pressure measurements using drill stem tests and estimates from log data calculation indicate that three vertically stacked regional pressure compartments exist in the Qikou Depression of Bohai Bay Basin, N. China. The compartments comprise hydrostatic, upper weak, and lower overpressure systems. Laterally, overpressure (pressure coefficient > 1.2) occurs in the deeper areas and weakens gradually from the centre to the margin of the depression. The accumulation of oil and gas exhibits the interesting characteristics of oil‐bearing layers above gas‐bearing layers in the Qikou Depression. The pattern can be accounted for by the evolution of overpressure system, the maturity process of the source rock and the main fault activity. In the late Dongying Formation (Ed, 30 Ma), the lower overpressure system began to form shape, and the hydrocarbon sources generated a large volume of oil. However, because there was no migration pathway, the oil only accumulated in the original strata. In the late Guantao Formation (Ng, 12 Ma), the gas was generated, the upper overpressure system formed gradually, and the activity of the main fault gradually increased. Then, the overpressure pushed the early gathered oil to flow from the lower overpressure system into the upper overpressure system. Afterwards, the activity of the main fault decreased again and remains weak until now. Thus, later generated natural gas cannot keep migrating along the main fault and can only accumulate in the lower overpressure system. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
127.
The integration of Sensor Web Enablement services with other Open Geospatial Consortium (OGC) Web Services as Geospatial Processing Workflows (GPW) is essential for future Sensor Web application scenarios. With the help of GPW technology, distributed and heterogeneous OGC Web Services can be organized and integrated as compound Web Service applications that can direct complicated earth observation tasks. Under the Sensor Web environment, asynchronous communications between Sensor Web Services are common. We have proposed an asynchronous GPW architecture for the integration of Sensor Web Services into a Web Service Business Process Execution Language workflow technology. We designed a Sensor Information Accessing and Processing workflow, an asynchronous GPW instance, to take an experiment of observing and mapping ozone over Antarctica. Based on our results, our proposed asynchronous workflow method shows the advantages of taking environmental monitoring and mapping tasks. 相似文献
128.
Jingui Xu Yunqian Kuang Bo Zhang Yonggang Liu Dawei Fan Xiaodong Li Hongsen Xie 《Physics and Chemistry of Minerals》2016,43(5):315-326
Synchrotron-based in situ angle-dispersive X-ray diffraction experiments were conducted on a natural uvite-dominated tourmaline sample by using an external-heating diamond anvil cell at simultaneously high pressures and temperatures up to 18 GPa and 723 K, respectively. The angle-dispersive X-ray diffraction data reveal no indication of a structural phase transition over the P–T range of the current experiment in this study. The pressure–volume–temperature data were fitted by the high-temperature Birch–Murnaghan equation of state. Isothermal bulk modulus of K 0 = 96.6 (9) GPa, pressure derivative of the bulk modulus of \(K_{0}^{\prime } = 12.5 \;(4)\), thermal expansion coefficient of α 0 = 4.39 (27) × 10?5 K?1 and temperature derivative of the bulk modulus (?K/?T) P = ?0.009 (6) GPa K?1 were obtained. The axial thermoelastic properties were also obtained with K a0 = 139 (2) GPa, \(K_{a0}^{\prime }\) = 11.5 (7) and α a0 = 1.00 (11) × 10?5 K?1 for the a-axis, and K c0 = 59 (1) GPa, \(K_{c0}^{\prime }\) = 11.4 (5) and α c0 = 2.41 (24) × 10?5 K?1 for the c-axis. Both of axial compression and thermal expansion exhibit large anisotropic behavior. Thermoelastic parameters of tourmaline in this study were also compared with that of the other two ring silicates of beryl and cordierite. 相似文献
129.
南美厄瓜多尔Oriente盆地斜坡带发育的白垩系Napo组高伽马特征的UT海绿石砂岩段是成熟探区新发现的隐蔽含油层段。本文分析了海绿石砂岩储层的矿物组成、孔隙结构、成岩作用、物性特点,并结合烃源岩评价与石油空间分布探讨海绿石砂岩油藏的成藏特征。海绿石粘土矿物以颗粒形式存在,与石英共同构成海绿石砂岩的颗粒组分,海绿石砂岩的孔隙结构具有双峰特征,束缚水含量高,属于中-低孔、中-低渗储层类型,孔隙类型主要是剩余粒间孔。海绿石砂岩储层中石英次生加大属Ⅱ级,长石碎屑颗粒发生溶蚀作用,含铁碳酸盐类胶结物发育,结合泥岩低的I/S混层比和高的最高峰温值Tmax,指示海绿石砂岩层段属于中成岩阶段A期的产物。与海绿石砂岩油藏紧邻的大面积分布的Ⅱ1腐泥型成熟烃源岩就是缓翼斜坡带的生烃中心,大面积连续发育的海绿石砂岩与之构成优越的源储组合,有利于上生下储式成藏。海绿石砂岩油藏表现为近源性、成藏晚期性等特点,规模发育的海绿石砂岩储层得以成藏的主要运聚机制是体积流和扩散流运聚机制。这对盆地其它油区同类油藏的发现具有重要的借鉴意义。 相似文献
130.
运用地电化学技术在内蒙古半干旱草原风成砂浅覆盖区朝不楞多金属矿外围开展了1∶50000面积性勘查工作,并与常规土壤测量开展了对比研究。结果表明:(1)从元素异常强度、衬度、规模及与已知矿体空间对应性等方面对比,地电化学测量比常规土壤测量具有显著优越性;(2)地电化学测量在区域上显现出Ag-Pb-Zn-Bi-Cd及Cu-Co-Cr-Fe-La-Mo-Ni两套元素异常组合,与已知见矿钻孔中探测到的矽卡岩型铁矿及热液型铅锌矿均有出现具有较好的对应性;(3)在工区东部及东南部未知区发现多处异常强度、规模较大的多元素组合异常,建议开展进一步的勘查工作,以实现该矿区找矿突破。 相似文献