An original method for characterizing internal waves

This study consisted in the characterization of internal waves in the south of the Strait of Messina (Italy). The observational data consisted in thermistor string profiles from the Coastal Ocean Acoustic Changes at High frequencies (COACH06) sea trial.An empirical orthogonal function analysis is applied to the data. The first two spatial empirical modes represent over 99% of the variability, and their corresponding time-dependent expansion coefficients take higher absolute values during internal wave events. In order to check how the expansion coefficients vary during an internal wave event, their time derivative, called here changing rates, are computed. It shows that each wave of an internal wave train is characterized by a double oscillation of the changing rates. At the front of the wave, both changing rates increase in absolute value with opposite sign, and then decrease to become null at the maximum amplitude of the wave. At the rear of the wave, the changing rates describe another period, again with opposite sign. This double oscillation can be used as a detector of internal waves, but it can also give information on the width of the wave, by measuring the length of the oscillation, as this information may sometimes be hard to read straight out of the data. When plotting the changing rates one versus another, the resulting scatter diagram puts on a butterfly shape that illustrates well this behaviour.     

Copper isotopes as monitors of redox processes in hydrothermal mineralization

The stable copper isotope composition of 79 samples of primary and secondary copper minerals from hydrothermal veins in the Schwarzwald mining district, South Germany, shows a wide variation in δ⁶⁵Cu ranging from −2.92 to 2.41‰. We investigated primary chalcopyrite, various kinds of fahlores and emplectite, as well as supergene native copper, malachite, azurite, cuprite, tenorite, olivenite, pseudomalachite and chrysocolla. Fresh primary Cu(I) ores have at most localities copper isotope ratios (δ⁶⁵Cu values) of 0 ± 0.5‰ despite the fact that the samples come from mineralogically different types of deposits covering an area of about 100 by 50 km and that they formed during three different mineralization events spanning the last 300 Ma. Relics of the primary ores in oxidized samples (i.e., chalcopyrite relics in an iron oxide matrix with an outer malachite coating) display low isotope ratios down to −2.92‰. Secondary Cu(I) minerals such as cuprite have high δ⁶⁵Cu values between 0.4 and 1.65‰, whereas secondary Cu(II) minerals such as malachite show a range of values between −1.55 and 2.41‰, but typically have values above +0.5‰. Within single samples, supergene oxidation of fresh chalcopyrite with a δ value of 0‰ causes significant fractionation on the scale of a centimetre between malachite (up to 1.49‰) and relict chalcopyrite (down to −2.92‰). The results show that—with only two notable exceptions—high-temperature hydrothermal processes did not lead to significant and correlatable variations in copper isotope ratios within a large mining district mineralized over a long period of time. Conversely, low-temperature redox processes seriously affect the copper isotope compositions of hydrothermal copper ores. While details of the redox processes are not yet understood, we interpret the range in compositions found in both primary Cu(I) and secondary Cu(II) minerals as a result of two competing controls on the isotope fractionation process: within-fluid control, i.e., the fractionation during the redox process among dissolved species, and fluid-solid control, i.e., fractionation during precipitation involving reactions between dissolved Cu species and minerals. Additionally, Rayleigh fractionation in a closed system may be responsible for some of the spread in isotope compositions. Our study indicates that copper isotope variations may be used to decipher details of natural redox processes and therefore may have some bearing on exploration, evaluation and exploitation of copper deposits. On the other hand, copper isotope analyses of single archeological artefacts or geological or biological objects cannot be easily used as reliable fingerprint for the source of copper, because the variation caused by redox processes within a single deposit is usually much larger than the inter-deposit variation.     

Transcrystalline melt migration in clinopyroxene

Glass inclusions in clinopyroxene phenocrysts from La Sommata (Vulcano Island, Aeolian Arc) were reheated and submitted to a sustained thermal gradient. Each remelted inclusion undergoes a transient textural and chemical reequilibration and concomitantly begins to migrate along a crystallographic direction, at a small angle with the thermal gradient. The completion of morphological evolution requires a characteristic time that is governed by chemical diffusion. Chemical reequilibration results in the formation of a colored halo that delineates the former location and shape of the inclusion after it has migrated away. Transcrystalline migration proceeds by dissolution of the host clinopyroxene ahead and precipitation astern. Its rate is not limited by Fick’s law, but by the crystal-melt interface kinetics. Clinopyroxene dissolution and growth are slower than for olivine in similar conditions but obey the same analytical law, which can be transposed to equally or more sluggish melting or crystallization events in nature. When a gas bubble is initially present, it responds to elastic forces by quickly shifting toward the cold end of the inclusion, where it soon becomes engulfed as an isolated fluid inclusion in the reprecipitated crystal. This study confirms that transcrystalline melt migration, beside its possible implications for small-scale melt segregation and fluid-inclusion generation in the Earth’s mantle, provides an experimental access to interfacial kinetic laws in near-equilibrium conditions.     

Near‐surface temperatures and heat balance of bare outcrops exposed to solar radiation

Subsurface temperatures in rocks naturally fluctuate under the influence of local meteorological conditions. These fluctuations play a role in mechanical weathering, thus creating the environmental conditions conducive to natural hazards such as rockfalls and providing important sediment source terms for landscape evolution. However, the physics that control heat penetration into rocks are not fully understood, which makes the underground thermal state difficult to interpret when temperature measurements are available and even more difficult to estimate for unmonitored sites. This is an important lacuna given possible impacts of future climate change on mechanical weathering processes. The natural daily variations of subsurface temperatures were investigated on a bare gneiss outcrop exposed to solar radiation, where temperatures at various depths (up to 50 cm), as well as the solar radiation reaching a pyranometer, were monitored hourly for several months. This detailed times series of thermal data was used to gain insight into the heat balance at the inclined free surface of the rock mass. Attention was focused on two major contributors to the heat balance; the heat flux entering the rock mass through conduction and the incoming shortwave (solar) radiation. A Fourier decomposition of the temperature measurements provided an estimate of the in situ thermal conductivity of the rock and was used to calculate the conductive term. The shortwave radiation term was determined on the basis of the pyranometer measurements adjusted to account for the angle of incidence of the sun. It is shown that, throughout clear‐sky periods, heat exchanges at the surface are mainly controlled by direct solar radiation during the day, and by a roughly constant outgoing heat flux during the night. Subsurface temperatures can be reliably estimated with a semi‐infinite medium model whose boundary condition is derived from an analytical insolation model that takes atmospheric attenuation into account. Copyright © 2011 John Wiley & Sons, Ltd.     

The April 2010 North African heatwave: when the water vapor greenhouse effect drives nighttime temperatures

Climate Dynamics - North Africa experienced a severe heatwave in April 2010 with daily maximum temperatures ( $$T_{max}$$ ) frequently exceeding $$40\,^{\circ }\mathrm{C}$$ and daily minimum...     

Petrology and provenance of a very‐low‐titanium picrite clast in lunar highland regolith breccia 15295

Clast 100 in regolith breccia 15295 could be a key to resolving the relationship(s) between mare basalts and lunar picritic glasses. The clast is basaltic, with texture, mineralogy, mineral compositions, and calculated bulk composition suggesting that it crystallized in a thick lava flow or shallow intrusive body from a very‐low‐titanium (VLT) basaltic magma. The estimated bulk composition of clast 15295,100 is primitive (i.e., magnesian) compared to those of known VLT basalts, and is very close to those of VLT picritic green glasses, especially the Apollo 14 A green glass. From these similarities, we infer that clast 15295,100 is a crystalline product of a picritic magma similar to the Apollo 14 A glass. Clementine and M³ remotely sensed data of the lunar surface were used to find areas that have chemical compositions consistent with those of clast 15295,100, not only near the Apollo 15 site, but in a broad region surrounding the site. Two regions are consistent with clast's 15295,100 compositional data. The larger region is in southern Mare Imbrium, and a smaller region is in the eastern half of Sinus Aestuum. These locations should be considered as candidates for future missions focusing on sample science.     

WAVERYS: a CMEMS global wave reanalysis during the altimetry period

Ocean Dynamics - As part of the Copernicus Marine Service, WAVERYS is the multi-year wave reanalysis that provides global wave data with a fine grid resolution of 1/5°. This wave reanalysis...     

GLONASS ambiguity resolution of mixed receiver types without external calibration

GLONASS processing from mixed receiver types is typically subject to unmodeled inter-frequency phase biases which prevent carrier phase ambiguity parameters from converging to integers. Receiver-dependent values have been proposed to mitigate the contribution of these biases, but are still subject to a number of issues, such as firmware updates. Recent studies have demonstrated that the origin of inter-frequency biases is a misalignment between phase and code observations, and could be calibrated to first order by manufacturers. In this contribution, a calibration-free method for GLONASS ambiguity resolution is presented in which ambiguities naturally converge to integers. A mandatory condition is that two GLONASS satellites with adjacent frequency numbers are observed simultaneously, although this condition can be relaxed once a fixed solution has been obtained. This approach then permits the integration of different receiver types and firmware versions into seamless processing.