Compressibility and crystal structure of sillimanite, Al2SiO5, at high pressure

The unit-cell dimensions and crystal structure of sillimanite at various pressures up to 5.29 GPa have been refined from single-crystal X-ray diffraction data. As pressure increases, a and b decrease linearly, whereas c decreases nonlinearly with a slightly positive curvature. The axial compression ratios at room pressure are β_a:β_b:β_c=1.22:1.63:1.00. Sillimanite exhibits the least compressibility along c, but the least thermal expansivity along a (Skinner et al. 1961; Winter and Ghose 1979). The bulk modulus of sillimanite is 171(1) GPa with K′=4 (3), larger than that of andalusite (151 GPa), but smaller than that of kyanite (193 GPa). The bulk moduli of the [Al1O₆], [Al2O₄], and [SiO₄] polyhedra are 162(8), 269(33), and 367(89) GPa, respectively. Comparison of high-pressure data for Al₂SiO₅ polymorphs reveals that the [SiO₄] tetrahedra are the most rigid units in all these polymorphic structures, whereas the [AlO₆] octahedra are most compressible. Furthermore, [AlO₆] octahedral compressibilities decrease from kyanite to sillimanite, to andalusite, the same order as their bulk moduli, suggesting that [AlO₆] octahedra control the compression of the Al₂SiO₅ polymorphs. The compression of the [Al1O₆] octahedron in sillimanite is anisotropic with the longest Al1-OD bond shortening by ～1.9% between room pressure and 5.29 GPa and the shortest Al1-OB bond by only 0.3%. The compression anisotropy of sillimanite is primarily a consequence of its topological anisotropy, coupled with the compression anisotropy of the Al-O bonds within the [Al1O₆] octahedron.     

五大连池火山群新期火山渣丘成因的探讨

火山渣丘,是火山区内的一种特殊的地质现象,以前地其成因国内外尚无详细探讨和描述,有的学者曾经统称为副火山。笔者通过实地调查,对这一结论提出新的见解,认为火山渣丘的形成是一复杂的地质现象,其成因具有多元性。这对探讨火山喷发规律,对火山地质地貌的准确描述与具有积极作用。     

四川木里耳泽岩溶型金矿床形成条件和成矿机制

四川本里耳泽金-菱铁矿建造矿床,赋存于上二叠统海相碳酸盐岩层中,矿化受古岩溶的严格控制,组成矿石的基本矿物为菱铁矿,金不均匀地分布于菱铁矿矿体内。成矿溶液来自加热的循环地下水。成矿过程分为早阶段和中-晚阶段。成矿温度为156-210℃,成矿深度小于1km.成矿物质主要来自地层。成矿热液呈碱性和弱还原性,贫硫,含中等盐度。矿床形成时的地质构造环境较稳定。这是我国仅见的一种特殊金矿类型。     

On matching the spectrum of Io: Variations in the photometric properties of sulfur-containing mixtures

The problem of comparing laboratory spectra of sulfur-containing binary mixtures with the spectrum of Io is discussed. For the satellite, the observable is the geometric albedo as a function of wavelength, whereas in the laboratory one often measures some other type of albedo. In a previous paper we demonstrated that for pure sulfur the multiplicative factor which converts the laboratory albedos to geometric albedos can be strongly wavelength dependent. The present paper demonstrates that this is also true for binary sulfur-containing mixtures. Furthermore, there is no universal conversion factor applicable to all binary mixtures, nor can the factor be interpolated for a particular mixture from the conversion factors of the two end members. The conversion factor is a function not only of the specific composition of a binary mixture, but of the relative particle size distributions of the two components, and must be measured specifically for each individual sample if a quantitative comparison between a laboratory sample and Io's surface is desired.     

黑龙江省与呼伦贝尔盟土地类型的划分及其分布规律

本文就土地研究的几个主要概念,即土地、土地分类、土地分级作了简要讨论,并结合黑龙江省及呼伦贝尔盟的具体条件,对为农、林、牧业服务的土地分类原则进行了初步探讨,还拟订了该区土地分级系统——土地类和土地型,及适合于大比例尺制图的土地组。在此基础上,将全区分为18个土地类、71个土地型。文章还从水平带性、垂直带性和土地结构三个方面,介绍了该区土地类型分布的一般规律。     

地学“开合律”及其在造山带研究中的意义

“开合律”是地学辩证法基本规律之一。本文概述了它的内容与特点,阐明它在造山带研究中的意义及运用它指导造山带研究的步骤,并根据目前已总结的5种“开”、“合”类型相应地提出了5种造山带类型。     

综合利用地震多参数预测油气藏

以吉林省境内红星构造带(已发现油田)和杨柳青构造带(未发现油田)为试验区,首先利用地震地层学方法,研究间接参数特征,确定有利相带和有效圈闭,并在有效圈闭上选择了39个2×2cm时窗。在时窗内提取与地震波动力学有关的信息,即频率、振幅、频谱能量等,然后对这种信息进行统计计算,获得振幅方差等九个参数并对其进行综合分析,从已知油气藏出发,对未知圈闭油气状况进行了三级预测,指出了最有利的勘探靶区。     

How to compare the surface of Io to laboratory samples

Since one does not know the photometric functions of various parts of Io, one cannot convert the observed geometric albedo of the satellite to a parameter more directly measurable in the laboratory. One must therefore convert laboratory reflectances to geometric albedos before quantitative comparisons between Io's surface and a laboratory sample are made. This procedure involves determining the wavelength dependence of the sample's photometric function. For substances such as sulfur, whose reflectance varies strongly with wavelength, it is incorrect to assume that the photometric function, and hence the ratio (laboratory reflectance/geometric albedo) is independent of wavelength. To illustrate this point, measurements of the color dependence of this ratio for sulfur are presented for the specific case in which the measured laboratory reflectance is the sample's normal reflectance. In general, unless the laboratory reflectance is precisely the geometric albedo, a wavelength-dependent correction factor must be determined before the laboratory sample can be compared quantitatively with Io's surface.     

膜分离技术的应用及发展趋势

综述世界和中国膜分离技术的发展，并对膜分离技术的基本特性、技术特点、膜材料、分类及膜分离装置进行了简单介绍；并介绍了膜分离法在化工及石油工业、食品工业、医药工业和医疗设备、生物技术和环境工程中的应用，并分析了膜分离技术将会在膜材料、新的膜过程和集成膜过程3个方面的发展趋势。同时指出如果能解决膜产品的价格、膜污染和膜分离性能的提高这3个膜的制约因素，膜分离技术将在人类社会的发展史上起到不可替代的作用。     

Genesis of monazite and Y zoning in garnet from the Black Hills, South Dakota

The paragenesis of monazite in metapelitic rocks from the contact aureole of the Harney Peak Granite, Black Hills, South Dakota, was investigated using zoning patterns of monazite and garnet, electron microprobe dating of monazite, bulk-rock compositions, and major phase mineral equilibria. The area is characterized by low-pressure and high-temperature metamorphism with metamorphic zones ranging from garnet to sillimanite zones. Garnet porphyroblasts containing euhedral Y annuli are observed from the garnet to sillimanite zones. Although major phase mineral equilibria predict resorption of garnet at the staurolite isograd and regrowth at the andalusite isograd, textural and mass balance analyses suggest that the formation of the Y annuli is not related to the resorption-and-regrowth of garnet having formed instead during garnet growth in the garnet zone. Monazite grains in Black Hills pelites were divided into two generations on the basis of zoning patterns of Y and U: monazite 1 with low-Y and -U and monazite 2 with high-Y and -U. Monazite 1 occurs in the garnet zone and persists into the sillimanite zone as cores shielded by monazite 2 which starts to form in the andalusite zone. Pelites containing garnet porphyroblasts with Y annuli and monazite 1 with patchy Th zoning are more calcic than those with garnet with no Y annuli and monazite with concentric Th zoning. Monazite 1 is attributed to breakdown of allanite in the garnet zone, additionally giving rise to the Y annuli observed in garnet. Monazite 2 grows in the andalusite zone, probably at the expense of garnet and monazite 1 in the andalusite and sillimanite zones. The ages of the two different generations of monazite are within the precision of chemical dating of electron microprobe. The electron microprobe ages of all monazites from the Black Hills show a single ca. 1713 Ma population, close to the intrusion age of the Harney Peak Granite (1715 Ma). This study demonstrates that Y zoning in garnet and monazite are critical to the interpretation of monazite petrogenesis and therefore monazite ages.