液化场地地震反应的离散元数值模拟

采用一个描述饱和砂土中固相颗粒和液相流体耦合的离散元数值模型,固相颗粒采用离散元的颗粒流理论(PFC)模拟,液相流体通过求解平均Navier-Stokes方程的计算流体动力学(CFD)技术计算.采用上述模犁数值模拟了在地震荷载作用液化场地的加速度、剪应力、剪应变时程以及超孔隙水压力和土层表面位移的发展过程.数值模拟结果...     

Comparison of daily and sub-daily SWAT models for daily streamflow simulation in the Upper Huai River Basin of China

Despite the significant role of precipitation in the hydrological cycle, few studies have been conducted to evaluate the impacts of the temporal resolution of rainfall inputs on the performance of SWAT (soil and water assessment tool) models in large-sized river basins. In this study, both daily and hourly rainfall observations at 28 rainfall stations were used as inputs to SWAT for daily streamflow simulation in the Upper Huai River Basin. Study results have demonstrated that the SWAT model with hourly rainfall inputs performed better than the model with daily rainfall inputs in daily streamflow simulation, primarily due to its better capability of simulating peak flows during the flood season. The sub-daily SWAT model estimated that 58 % of streamflow was contributed by baseflow compared to 34 % estimated by the daily model. Using the future daily and 3-h precipitation projections under the RCP (Representative Concentration Pathways) 4.5 scenario as inputs, the sub-daily SWAT model predicted a larger amount of monthly maximum daily flow during the wet years than the daily model. The differences between the daily and sub-daily SWAT model simulation results indicated that temporal rainfall resolution could have much impact on the simulation of hydrological process, streamflow, and consequently pollutant transport by SWAT models. There is an imperative need for more studies to examine the effects of temporal rainfall resolution on the simulation of hydrological and water pollutant transport processes by SWAT in river basins of different environmental conditions.     

Dynamic Analysis of a Single-Column Platform (II)

This paper describes the study of a single-column structure used as well-head platform. In order to check the reliability of computation theory and programme, model tests have been carried out. The paper introduces the conclusion of tests and the dynamic properties of single-column platform are obtained.     

Metal Ion Extraction with Bipyridine Derivatives as Chelating Ligands in Supercritical Carbon Dioxide

Three fluorinated bipyridine ligands have been designed and synthesized as chelating agents for the extraction of metal ions in supercritical CO₂ (sc‐CO₂). The ligand solubilities in sc‐CO₂ were investigated at different temperatures and pressures, and the measured data have been correlated using a semiempirical model. The calculated results showed satisfactory agreement with the experimental data. Based on these data, metal ion extraction with the three compounds as chelating agents in sc‐CO₂ was performed from spiked filter paper, whereby ligand 1 showed the highest extraction efficiency, especially for Ni²⁺ and Cu²⁺. The extraction constants, K_ex, of the three chelating ligands were seen to increase with increasing extraction efficiency for the same metal ion in the same extraction system.     

Dipole tilt controls bow shock location and flaring angle

The dipole tilt angle has been found to affect Earth’s bow shock. This work presents a quantitative relationship between the dipole tilt angle and the bow shock location and flaring angle. We collected a large data set of bow shock crossings from four different satellites (IMP 8, Geotail, Magion 4, and Cluster), including some recent crossings obtained during 2012–2013. The results from a statistical analysis demonstrate that: (1) the subsolar standoff distance increases but the flaring angle decreases with increasing dipole tilt angle; (2) when the dipole tilt angle changes sign from negative to positive, the dayside bow shock moves toward Earth and the shift can be as much as 2.29 R _E, during which the flaring angle increases; and (3) the shape of bow shock in the northern and southern hemispheres differs. For the northern hemisphere bow shock, with increasing positive/negative dipole tilt angle, the flaring angle increases/decreases. While for the southern hemisphere, the trend is the opposite; with increasing positive/negative dipole tilt angle, the flaring angle decreases/increases. These results are helpful for future bow shock modeling that needs to include the effects of dipole tilt angle.     

重庆市乡村义务教育资源可得性差异及影响因素

以国家统筹城乡教育发展试验区的重庆市乡村地区为例,采用Densi-Graph城乡识别法进行行政区划内部格网尺度的精准识别,在此基础上探究义务教育资源可得性水平的空间差异及影响因素。结果表明：1)基于Densi-Graph城乡识别法的重庆市城乡差异显著,乡村区域面积达79 752 km²,占区域总面积的96.82%。城市部分面积为2 616 km²,占区域总面积的3.18%。2)重庆市义务教育资源可得性水平具有显著的空间集聚与关联特征,并呈现由中心城区向外递减的格局。3)政府重视程度、社会经济发展水平、交通设施水平、自然地理环境均与义务教育资源可得性水平具有显著相关性。4)交通站点密度与教育投入是影响义务教育资源可得性水平的主导因子,二者与各项因子的交互叠加作用增强效果显著;影响机制上,地形起伏度与坡度是乡村义务教育资源可得性水平的限制条件,社会经济是基础,交通是关键,教育投入是核心。     

Two methods for pore network of porous media

Two approaches of generating pore networks of porous media are presented to capture the pore fabric. The first methodology extracted pore structure from a computer simulated packing of spheres. The modified Delaunay tessellation was used to describe the porous media, and modified Nelder–Mead method in conjunction with three pore‐merging algorithms was used to generate the pore size and coordination number distributions of the randomly packed spheres. The Biconical Abscissa Asymmetric CONcentric bond was used to describe the connection between two adjacent voids. This algorithm was validated by predicting pore structure of a cubic array of spheres of equal radius with known pore sizes, throat sizes and coordination number distributions. The predicted distributions of pore structure agreed well with the measured. Then, the algorithm was used to predict pore structure and permeability of randomly packed spherical particles, and predicted permeability values were compared with published experimental data. The results showed that the predicted permeability values were in good agreement with those measured, confirming the proposed algorithm can capture the main flow paths of packed beds. The second methodology generated an equivalent pore network of porous media, of which the centers of voids were located in a regular lattice with constant pore center distance. However, this network allowed for matching both main geometrical and topological characteristics of the porous media. A comparison of the two approaches suggested that the second approach can also be used as a predictive tool to quantitatively study the microscopic properties of flow through porous media. Copyright © 2012 John Wiley & Sons, Ltd.     

C_(60)研究现状及前景

碳除了具有传统观念上的石墨和金刚石两种同素异形体外,近年来人们又发现了第三种同素异形体———Ｃ６０。Ｃ６０以其独特的类似足球状的结构及性能,吸引了各国的科学家,对Ｃ６０的研究在全世界范围内如火如荼地开展起来。笔者在总结Ｃ６０的合成技术、分子结构与性能的基础上,探索了Ｃ６０作为一种新型材料所具有的应用潜力;回顾了从Ｃ６０发现至今十多年的研究历程,并首次将Ｃ６０的研究过程分成三个阶段,即起步阶段（１９８５年～１９９０年）、起飞阶段（１９９１年～１９９３年）和成熟阶段（１９９４年以后）;预测了Ｃ６０及其化合物的应用性研究将成为今后研究的重点和热点。最后,对当前Ｃ６０研究中存在的问题和难点进行了讨论。     

腾龙洞造成的洪涝灾害及治理方案的优选

湖北省利川市毗邻清江,其下游腾龙洞清江伏流段阻流壅水严重,影响到了城区.本文通过对腾龙洞形态结构特点及其周围地质环境的研究,认为该地下河入口(落水洞)至银河洞尾一段过水断面狭窄,阻流壅水是造成利川市城郊遭受水灾的主要原因.治理时,以隧道加溶洞方案最为经济