Active manipulation of the selective alignment by two laser pulses

This paper solves numerically the full time-dependent Schrõdinger equation based on the rigid rotor model, and proposes a novel strategy to determine the optimal time delay of the two laser pulses to manipulate the molecular selective alignment. The results illustrate that the molecular alignment generated by the first pulse can be suppressed or enhanced selectively, the relative populations of even and odd rotational states in the final rotational wave packet can be manipulated selectively by precisely inserting the peak of the second laser pulse at the time when the slope for the alignment parameter by the first laser locates a local maximum for the even rotational states and a local minimum for the odds, and vice versa. The selective alignment can be further optimised by selecting the intensity ratio of the two laser pulses on the condition that the total laser intensity and pulse duration are kept constant.     

Structural, curvature and electronic properties of Rh adsorption on armchair single-walled carbon nanotube

This paper systematically studies the rolling effects of the (n, n) single-wall carbon nanotubes (SWCNT) with different curvatures on Rh adsorption behaviours by using density functional theory. The outside charge densities of SWCNTs are found to be higher than those inside, and the differences decrease with the increase of the tube radius. This electronic property led to the discovery that the outside adsorption energies are higher than the inside ones, and that the differences are reduced with the increase of the tube radius. Partial density of states and charge density difference indicate that these strong interactions induce electron transfer between Rh atoms and SWCNTs.     

Compressibility and crystal structure of sillimanite, Al2SiO5, at high pressure

The unit-cell dimensions and crystal structure of sillimanite at various pressures up to 5.29 GPa have been refined from single-crystal X-ray diffraction data. As pressure increases, a and b decrease linearly, whereas c decreases nonlinearly with a slightly positive curvature. The axial compression ratios at room pressure are β_a:β_b:β_c=1.22:1.63:1.00. Sillimanite exhibits the least compressibility along c, but the least thermal expansivity along a (Skinner et al. 1961; Winter and Ghose 1979). The bulk modulus of sillimanite is 171(1) GPa with K′=4 (3), larger than that of andalusite (151 GPa), but smaller than that of kyanite (193 GPa). The bulk moduli of the [Al1O₆], [Al2O₄], and [SiO₄] polyhedra are 162(8), 269(33), and 367(89) GPa, respectively. Comparison of high-pressure data for Al₂SiO₅ polymorphs reveals that the [SiO₄] tetrahedra are the most rigid units in all these polymorphic structures, whereas the [AlO₆] octahedra are most compressible. Furthermore, [AlO₆] octahedral compressibilities decrease from kyanite to sillimanite, to andalusite, the same order as their bulk moduli, suggesting that [AlO₆] octahedra control the compression of the Al₂SiO₅ polymorphs. The compression of the [Al1O₆] octahedron in sillimanite is anisotropic with the longest Al1-OD bond shortening by ～1.9% between room pressure and 5.29 GPa and the shortest Al1-OB bond by only 0.3%. The compression anisotropy of sillimanite is primarily a consequence of its topological anisotropy, coupled with the compression anisotropy of the Al-O bonds within the [Al1O₆] octahedron.     

山东中新世山旺组生物群的古生态

山东临朐产出的中新世山旺组化石群,保存精美、属种分异度高。50多年来,经发掘和研究,目前已从约30余米的硅藻页岩沉积中报导了真菌、硅藻、介形虫、孢粉、昆虫、鱼类、两栖动物、爬行类、鸟类、哺乳动物及遗迹化石等十几个门类的化石,共计400余属700多种。本文总结了化石与周围无机界的关系、化石的埋藏特征、形成原因以及相关古生态学问题――古气候、古温度、古纬度、古地形、山旺湖的水文性质、湖水的季节性变化与硅藻页岩的纹层、动植物群的营养结构以及山旺盆地的沉积历史。     

江西安远路迳金伯利质煌斑岩筒的Rb-Sr同位素年龄及其地质意义

报道了赣南安远县路迳金伯利质煌斑岩筒的 Rb-Sr等时线地质年龄 :t=( 3 7.6± 2 .2 ) Ma,初始值 [n( 87Sr) / n( 86Sr) ] i=0 .70 5 17± 0 .0 0 0 12。     

综合勘探在武汉军山长江大桥勘察中的应用

单一的勘探手段很难适应高速公路基本建设对勘察设计的高水平、高质量和高效率的要求。将钻探、地震勘探、重力勘探、磁法勘探、电视测井、声波测井等勘探手段综合运用于武汉军山大桥地质勘察中，不但精确探明了桥墩处地层岩性的风化程度，裂隙的位置、产状、规模，岩石完整性等，准确提供了岩石的力学参数，而且缩短了勘察周期，降低了成本。     

有机酸对长石溶解度影响的热力学研究

为明确认识有机酸（草酸、醋酸）对长石溶解度及储层次生孔隙发育的影响，本文利用热力学方法，计算了不同温度、酸度下钾长石在含有醋酸根0.05mol/L、草酸0.0055mol/L的溶液中的溶解度及草酸和醋酸对溶液酸度的影响，计算的结果表明醒酸根与铝的络合作用只发生在偏酸性的溶液体系中，并且随温度升高要求酸度增加，实际的络合能力降低，醋酸根的络合作用对长石溶解度的增加作用极及有限，最高时不足一倍；但醋酸能有效地缓冲溶液酸度，从而提高长石溶解度。草酸根与铝的络合作用发生在弱碱性至酸性条件下，温度升高，络合能力增加，络合效应对长石溶解度，草酸根上铝的络合作用发生在弱碱性至酸性条件下，温度升高，络合能力增加，络合效应对长石溶出量的增加最多可达2个数量级以上，草酸的浓度太低无法通过缓冲溶液在较高的酸度下来促进长石的溶解，草酸和醒酸能否促进储层次生孔隙的发育取决于盆地流体的酸度及组成流体的缓冲体系。     

滇西菲红超基性岩风化壳铂族元素地球化学行为

近年来在世界不同地区进行了风化过程中铂族元素的地球化学行为研究。作为中国西南部的第一个实例，本文研究了云南西部菲红超基性岩体上发育的红土风化剖面。矿物学和微量元素地球化学研究证明该风化壳是超基性岩风化的结果。文中详细讨论了风化壳的地质、矿物学、红土化和铂族元素地球化学特征。结果表明，风化壳的红土化程度不高，仍处于红色粘土阶段；风化壳上部的表层土壤带和铁质粘土带中铂族元素总量至少富集了3．57－7．87倍，其中Ru和Pd的富集程度较大,Ir的富集程度中等，Pt和Rh的富集程度较小，使得铂族元素的配分模式由基岩的Pt富集型转变为风化壳的Ru-Pt富集型，证明红土化过程中铂族元素发生了分异。     

The Songpan-Garzê Massif: Its Relation to the QinlingFold Belt and Yangtze Platform and Developmental History1

Abstract Whether there existed the Songpan-Garzê massif is a controversial problem. This paper expounds and proves that the old basement of the massif is represented by the pre-Sinian granitic rock series. This massif and the South Qinling fold belt might both be a part of the old Yangtze platform. Rifting generated by the Caledonian orogeny in the terminal Early Palaeozoic caused the massif to be disintegrated from the northwestern part of the Yangtze platform. This disintegration, however, was not thorough, and the rift troughs were later gradually closed and filled up. The Emei taphrogeny that was initiated in the Early Permian Maokou'an Stage involved a second disintegration of this massif from the Yangtze platform. The rift line largely goes along the Muli-Pingwu line. This rifting belongs to synchronous extensional rifting at peripheries of the Yangtze platform and in its interior, showing that the posterior, lateral and interior extension resulting from rapid northward shift of the Yangtze platform led to isolation of this massif together with South Qinling from their adjacent areas. During the Ladinian Stage, the Songpan-Garzê massif and southern Qinling sank strongly en masse. This subsidence continued till the end of the Late Triassic when the late Indosinian movement caused the sea trough to be closed and Songpan-Garzê and southern Qinling to be folded and uplifted and become mountains.     

川黔湘交境寒武纪层序划分

根据层序地层学的基本原理和概念，以露头剖面研究为基础将川黔湘交境寒武素划分为１６个三级层序，其中下统含７个中统３个，上统６个，既有Ⅰ型层序又有Ⅱ型层序，具倾斜边缘的盆地中形成的Ⅰ型层序仅发育在早寒武世早期，共２个；具台缘斜坡的盆地中形成的Ⅰ型层序发育在台地形成及发展阶段，即早寒武世后期至晚寒武世早中期，共５个。上述层序的详细研究为海平面升降和加里东早期的构造运动的认识提供了新的基础。