络合剂淋洗Cu污染粉土的土柱试验研究

以当前我国备受关注的土体污染为背景,通过土柱试验研究了不同络合剂对Cu的淋洗效果,结果表明:乙二胺四乙酸二钠二水合物（ethylenediaminetetraacetic acid disodium saltdihydrate,EDTA）淋洗效果最佳,柠檬酸（citric acid,CIT）次之,氨三乙酸三钠盐单水合物（nitrilotriacetic acid trisodium salt monohydrate, NTA）淋洗效果相对最差;使用不同浓度的EDTA淋洗负载量为150 mg/kg的Cu污染土,浓度增大并未有效促进Cu的解吸,而较小浓度（0.005 mol/L）的EDTA是有效且经济的浓度,其对Cu的去除率达84%;0.015 mol/L的EDTA淋洗不同负载量的Cu污染土,随负载量增加,淋洗率下降,最高去除率为84%,但去除量增加;研究结果可为重金属污染土的淋洗修复工艺提供理论参考依据。     

辽宁阜新北部至内蒙古库伦旗地区第四系冲、洪积沉积特征

辽宁阜新北部至内蒙古库伦旗地区的第四系冲、洪积地层分布广泛,但由于冲、洪积物岩性、岩相比较单调,在纵、横向上变化快,不易进行深入的研究.根据成因、孢粉以及形成时代将研究区第四系冲、洪积物划分出中更新统冲积物、上更新统冲洪积物、下全新统冲洪积物、中全新统冲积物、上全新统冲积物5个填图单位.不同时期的冲、洪积物沉积特征及沉积环境各具特色,形成了不同的地貌特征.确定冲、洪积物的沉积标志,并对其进行详细的划分,可以为研究区甚至我国整个北方地区提供第四系冲、洪积物各方面深入研究的资料.     

利用GPR天线-目标极化的瞬时属性分析方法探测LNAPL污染土壤

轻非水相流体(LNAPL)泄漏后会对土壤和地下水造成严重污染,为了准确探测出LNAPL泄漏范围,本文将GPR天线-目标极化的瞬时属性分析方法应用于轻非水相流体污染土壤探测的研究中。采用注入柴油的石英砂砂箱在实验室建立污染土壤模型,利用探地雷达对该污染土壤分别进行天线方位为0°、90°的测量。LNAPL土壤污染物形状、大小、结构并不规则,因此可以通过0°和90°方位天线测量来分析天线-目标极化特征,了解目标物的走向、形状等地下介质信息。通过对预处理后的包含天线-目标极化特征的信息进行瞬时属性分析,LNAPL污染范围可以被清晰地识别,提高了GPR探测能力。     

Study on the deformation and failure modes of filling slope in loess filling engineering: a case study at a loess mountain airport

Lvliang airport is a typical loess filling engineering located in 20.5 km north of Lvliang City in Shanxi Province, China. By the end of March 2012, 14 fissures extending more than 7.5 m were observed in a loess-filled slope, of which the longest fissure is up to 82 m. Field monitoring and laboratory tests have been performed to investigate the slope failure modes. The test program includes wetting tests on unsaturated compacted samples and stress path tests on saturated samples. Field monitoring and observations show that differential settlement caused by non-homogeneity in compacted loess density might lead to the formation of fissures in the loess-filled slope. It was founded that the wetting deformation contributed to the development of differential settlement. Fissures are the essential factor for the loess-filled slope failure. Four deformation stages exhibit in the loess-filled slope prior final failure including development of the fissures, softening of the compacted loess, creeping of the slope leading edge and fissuring of the trailing edge and formation of the through-sliding surface. Development of the sliding surface mainly includes upward and downward expansion of the fissures. Upward expansion is a wetting failure process in loading condition, while downward expansion is a load-off wetting process. In addition, development of the sliding surface is accelerated by softening of the compacted soils as a result of water infiltration. Therefore, the key for taking countermeasures against filling landslides is to monitor and control the development of differential settlement and fissures in the slope shoulders. Digging out and extra-filling the fissures are an effective way for preventing these landslides.     

An insight into the surface velocity of Inylchek Glacier and its effect on Lake Merzbacher during 2006–2016 with Landsat time-series imagery

Mountain glacier is one of the extremely sensitive indicators for climate change, and its surface motion distribution and corresponding variation are valuable information for understanding ice mass exchange and glacier dynamics. This paper presents the long-term ice velocity distributions of Inylchek Glacier in the Tianshan region by pixel-tracking algorithm with time-series Landsat imagery acquired during 2006–2016. Then the monitored ice motion fields of Inylchek Glacier were carefully analyzed and revealed a generally similar spatial distribution characteristic. Most of the ice of the North Inylchek Glacier remains in a stagnant state except for the upstream part, but a relatively high velocity of 20–40 cm/day with an RMSE of 3 cm/day was observed on most part of the South Inylchek Glacier, except for the slow-moving glacier terminus. We also state the glacier dynamics around Lake Merzbacher and their possible effect on its glacier lake outburst flood (GLOF) risk. Besides, the surface velocity distribution on South Inylchek Glacier surface during the ablation period from 2014 to 2016 was also established and also compared with annual velocity. The corresponding difference yields that there is a positive relation between ice motion and temperature variation. Therefore, the time-series ice surface motion yielded by the Landsat imagery thus could provide us an efficient and low-cost way to analyze the current state and changes in glaciers, thanks to the continuous and regular spaceborne observations provided by the Landsat satellites.     

Development and verification of the comprehensive model for physical properties of hydrate sediment

Natural gas hydrate is widely distributed all over the world and may be a potential resource in the near future, whereas hydrate dissociation during the development affects wellbore stability and drilling safety. However, the present modeling of hydrate reservoir parameters ignored the influence of effective stress and only considered the hydrate saturation. In this paper, a series of stress sensitivity experiments for the unconsolidated sandstone were carried out, and the influence of mean effective stress on physical parameters was obtained; a comprehensive model for the physical parameters of hydrate reservoir was developed subsequently. With the help of ABAQUS finite element software, the established comprehensive model was verified by the use of the wellbore stability numerical model of hydrate reservoir. The verification results show that ignoring the effect of mean effective stress on the parameters of hydrate formation aggravates the invasion of drilling fluid into the hydrate formation. Besides, ignoring the stress sensitivity of reservoir physical parameters will underestimate the wellbore instability during hydrate drilling, which will be a threat to the safety of gas hydrate drilling. At the end of the drilling operation, the maximum plastic strain of the model for considering and not considering stress sensitivity was 0.0145 and 0.0138, respectively. Therefore, the established comprehensive model will provide a theoretical support for accurately predicting the engineering geological disasters in hydrate development process.     

Mechanical behavior and micro-structure of cement kiln dust-stabilized expensive soil

In this study, the effects of cement kiln dust (CKD) on the swelling properties, strength properties, and microstructures of CKD-stabilized expansive soil were investigated. Samples were prepared and stabilized with different CKD content ratios, ranging from 0 to 18% by dry mass. The results obtained show that the maximum swelling pressures decrease exponentially with increases in CKD content. Both the cohesion and unconfined compressive strength (UCS) increase at ratios below 10% CKD and then decrease slightly, above that ratio. CKD can also improve the strength of saturated, expansive soil. There is no visible change of UCS for soil without CKD when cured, while the UCS of a sample with 10% CKD content after curing for 90 days is higher than that after curing for only 1 day. This indicates that CKD can improve the long-term strength of expansive soil. Finally, microstructure analysis reveals that the addition of CKD reduces the montmorillonite content of expansive soil and decreases its swelling properties. The addition of CKD also changes the pore volume distribution, both the size and amount of macro-pores and micro-pores decrease with increase in CKD content. For saturated samples, the size of macro-pores is obviously reduced, while that of micro-pores is slightly increased for both treated and untreated soils. Hydration and saturation processes make the soil structure become dispersive which results in a lower strength, and adding CKD can restrain this process. The suggested optimal CKD content is between 10 and 14% and with a curing time of more than 27 days.     

Application of instantaneous amplitude gradient for ground penetrating radar signal analyses

Ground penetrating radar (GPR) is an effective geophysical method for environmental and engineering exploration. However, significant background interference occurs around most work sites, which increases the difficulty of analyzing and interpreting GPR profiles. For time-distance profile analyses, more accurate results can be obtained using the instantaneous parameters of the analytic signals. In this study, these instantaneous parameters are extracted and compared using 1D model waveform and 2D model strong interference profiles. The results show that the instantaneous amplitude gradient effectively reflects the model information, even under strong interference. The instantaneous amplitude gradient is applied to GPR survey data from a study site, and the results indicate that the technique reflects the underground structure information of the survey area. Drilling verification further confirms that the instantaneous amplitude gradient accurately reflects the underground structure information.     

嫩江科洛地区晚侏罗世深熔花岗岩对嫩江-黑河构造带的响应

通过对嫩江-黑河构造带内的岩石建造研究,在嫩江科洛地区识别出一套深熔花岗岩体,岩石宏观上为一套具非典型花岗岩结构的深熔型侵入岩,具交代结构、斑杂状构造和眼球状构造。对深熔花岗岩进行了锆石LA-ICP-MS U-Pb年龄测试,获得了3组不谐和的U-Pb年龄: 390 Ma、157~163 Ma和113 Ma。其中,113 Ma年龄代表了岩石遭受后期变质热事件年龄; 157~163 Ma的年龄代表了原岩结晶年龄。综合分析深熔花岗岩成因,认为其主要与嫩江-黑河断裂深部韧性剪切热效应作用下发生的深熔有关,深熔花岗岩的划分和厘定为深入研究嫩江-黑河断裂带在中生代的活动提供了新的素材。     

吉林永吉县头道沟地区镁铁—超镁铁质岩U-Pb年代学研究及地质意义

吉林省永吉县头道沟地区出露许多与头道沟岩组相伴产出的镁铁—超镁铁质岩,鉴于其处于长春-延吉构造带附近而受到业内关注,但由于缺少高精度年代学资料,制约了对区域大地构造的深入研究。本文采用锆石U-Pb(LA-ICP-MS)方法,对镁铁—超镁铁质岩进行了年代学研究。变质辉绿岩年龄为270±5 Ma,变质橄榄岩中捕获锆石最小年龄为297 Ma,考虑岩石组合及二者紧密相伴产出,认为二者均形成于中二叠世。镁铁—超镁铁质岩中捕获的锆石记录了华北克拉通及其北缘多次重要的构造热事件。其中,变辉绿岩中获得446±6 Ma的年龄与变质橄榄岩中获得的不一致线下交点434±240 Ma年龄共同对应了华北克拉通北缘早古生代的重要构造岩浆热事件;大量的1.8~2.4Ga年龄对应古元古代辽吉造山带热事件;1377 Ma、1542 Ma与蓟县系建造时代对应;869~997 Ma与青白口系建造时代对应;在变质辉绿岩中还存在众多3.0~3.2Ga锆石年龄。分析上述年龄结构及龙岗陆块北缘古生代地质体分布特征,推测研究区深部可能存在古老的变质基底,同时也表明研究区出露的镁铁—超镁铁质岩形成于陆内构造环境,而非蛇绿岩的组成成分,这对深化区域大地构造研究具有重要意义。