The role of arsenic-bearing rocks in groundwater pollution at Zimapán Valley, México

 Interaction of groundwater with As-bearing rocks has been proposed as one of three main sources of arsenic at Zimapán valley, México. The complexity of the geology and hydrogeology of the valley make it difficult to identify the natural causes of arsenic poisoning. Samples from the different rock outcrops and water from wells tapping various rock formations were analyzed. The rocks from mineralized areas contained higher concentrations of arsenic with respect to the same formations in non-mineralized areas. The arsenic minerals arsenopyrite, scorodite, and tennantite were identified in some rock samples. Higher temperature and lower Eh values were found for those wells containing more arsenic. The physicochemical characteristics of these naturally polluted well waters could be produced by arsenopyrite oxidation. The geochemical model PHREEQCI was used to perform the inverse modeling of two wells located along the same fault. Arsenopyrite oxidation and scorodite dissolution appear to be the geochemical processes producing the natural pollution according to the model. The release and transport of arsenic mainly occur through fractures within the cretaceous limestones where the most productive wells are drilled. The presence of arsenic should be expected also in other formations near mineralized zones in the Zimapán Valley. Field determinations of Eh and T could be used to detect potentially polluted wells. Received: 29 April 1999 / Accepted: 18 July 2000     

Known and unknown earthquakes through some European periodicals of the eighteenth century

Since the eighteenth century, pioneer seismologists have used information from the periodical press to compile their lists of European earthquakes. A systematic reading of three eighteenth century periodicals –Gaceta de Madrid (1701–1750), Gazeta de Lisboa (1715–1751) and Mercure de France (1732–1763) – has been carried out in the frame of the EC project ‘Review of Historical Seismicity in Europe (RHISE)’. The retrieval of earthquake records provides data on European and Mediterranean earthquakes. Sources and records are here analysed to verify their reliability and to understand the significance of the earthquake information they supply. Special attention has been paid to earthquakes that affected Italian territory, by means of a comparison between records and space-time, intensity parameters of the Italian seismic catalogue: this comparison shows that about 45% of the earthquakes mentioned by the periodicals are unknown in the Italian catalogue, and that 30% of them are damaging earthquakes.     

The 2000 April multiwavelength campaign of GRS 1915+105

We report results from multiwavelength observations of the microquasarGRS 1915+105 performed during the 2000 April campaign. This is one ofthe biggest campaigns ever made for this source covering the broadband from radio to γ-rays. Multiwavelength light curves compiledfrom all the data reduced up to date and broad band spectra obtainedwith ASCA and RXTE are presented.     

Report of the Science Community Workshop on the proposed First Sample Depot for the Mars Sample Return Campaign

The Mars 2020/Mars Sample Return (MSR) Sample Depot Science Community Workshop was held on September 28 and 30, 2022, to assess the Scientifically-Return Worthy (SRW) value of the full collection of samples acquired by the rover Perseverance at Jezero Crater, and of a proposed subset of samples to be left as a First Depot at a location within Jezero Crater called Three Forks. The primary outcome of the workshop was that the community is in consensus on the following statement: The proposed set of ten sample tubes that includes seven rock samples, one regolith sample, one atmospheric sample, and one witness tube constitutes a SRW collection that: (1) represents the diversity of the explored region around the landing site, (2) covers partially or fully, in a balanced way, all of the International MSR Objectives and Samples Team scientific objectives that are applicable to Jezero Crater, and (3) the analyses of samples in this First Depot on Earth would be of fundamental importance, providing a substantial improvement in our understanding of Mars. At the conclusion of the meeting, there was overall community support for forming the First Depot as described at the workshop and placing it at the Three Forks site. The community also recognized that the diversity of the Rover Cache (the sample collection that remains on the rover after placing the First Depot) will significantly improve with the samples that are planned to be obtained in the future by the Perseverance rover and that the Rover Cache is the primary target for MSR to return to Earth.     

A seismotectonic study of the Southeastern Alaska Region

We compare relocations of recent (1973–2005) and historic (1919–1972) earthquakes to geologic and geophysical (gravity, aeromagnetic, and uplift) information to determine the relationship of seismicity to crustal deformation in southeastern Alaska. Our results suggest that along strike changes in the structure of the Pacific plate may control the location of the ends of rupture zones for large earthquakes along the offshore Queen Charlotte fault system in the southern portion of the study area. There is a marked increase in background seismicity in the northern portion of the study area where the Fairweather fault begins to bend toward the northwest and crustal uplift due to glacial unloading exceeds 20 mm/year. Focal mechanisms indicate that thrust and reverse mechanisms predominate in the region of maximum uplift, as might be expected by the decrease in ice sheet thickness. The diffuse nature of seismicity between the Fairweather and Denali faults in the northern study area suggests a complex interaction between plate/microplate interactions and glacial unloading, making it difficult to determine the optimal fault orientation for failure in moderate magnitude (5.5 to 6.5) earthquakes within this region.     

Impacts of landscape fragmentation on simulated precipitation fields in the Amazonian sub-basin of Ji-Paraná using the Eta model

Numerical studies on impacts of landscape fragmentation due to land use and land cover change (LUCC) on precipitation fields over the Ji-Paraná basin in the Amazon region are carried out using atmospheric Eta model. Experiments consider historical data about LUCC over the basin from 1978 to 2000 and compare simulations under LUCC conditions with simulations under pristine conditions. In agreement with previous observational studies, model results do not show statistically significant impacts on precipitation in the region. Results indicate that variability in precipitation in this region is mainly controlled by large-scale atmospheric characteristics and soil moisture conditions. However, some limitations are identified in the model simulations, mainly associated to the diurnal cycle of precipitation.     

Mapping Titan's surface features within the visible spectrum via Cassini VIMS

Titan shows its surface through many methane windows in the 1–5 $\mathrm{\mu }\mathrm{m}$ region. Windows at shorter wavelengths also exist, polluted by scattering off of atmospheric haze that reduces the surface contrast. At visible wavelengths, the surface of Titan has been observed by Voyager I, the Hubble Space Telescope, and ground-based telescopes. We present here global surface mapping of Titan using the visible wavelength channels from Cassini's Visual and Infrared Mapping Spectrometer (VIMS). We show global maps in each of the VIMS-V channels extending from 0.35 to 1.05 $\mathrm{\mu }\mathrm{m}$. We find methane windows at 0.637, 0.681, 0.754, 0.827, 0.937, and $1.046\mathrm{\mu }\mathrm{m}$ and apply an RGB color scheme to the 0.754, 0.827 and $0.937\mathrm{\mu }\mathrm{m}$ windows to search for surface albedo variations. Our results show that Titan appears gray at visible wavelengths; hence scattering albedo is a good approximation of the Bond albedo. Maps of this genre have already been made and published using the infrared channels of VIMS. Ours are the first global maps of Titan shortward of $0.938\mathrm{\mu }\mathrm{m}$. We compare the older IR maps to the new VIMS-V maps to constrain surface composition. For instance Tui Regio and Hotei Regio, referred to as $5\text{‐}\mathrm{\mu }\mathrm{m}$ bright spots in previous papers, do not distinguish themselves at all visible wavelengths. The distinction between the dune areas and the bright albedo spots, however, such as the difference between Xanadu and Senkyo, is easily discernible. We employ an empirically derived algorithm to remove haze layers from Titan, revealing a better look at the surface contrast.     

Occurrence and concentration of caffeine in Oregon coastal waters

Caffeine, a biologically active drug, is recognized as a contaminant of freshwater and marine systems. We quantified caffeine concentrations in Oregon's coastal ocean to determine whether levels correlated with proximity to caffeine pollution sources. Caffeine was analyzed at 14 coastal locations, stratified between populated areas with sources of caffeine pollution and sparsely populated areas with no major caffeine pollution sources. Caffeine concentrations were measured in major water bodies discharging near sampling locations. Caffeine in seawater ranged from below the reporting limit (8.5 ng/L) to 44.7 ng/L. Caffeine occurrence and concentrations in seawater did not correspond with pollution threats from population density and point and non-point sources, but did correspond with storm event occurrence. Caffeine concentrations in rivers and estuaries draining to the coast ranged from below the reporting limit to 152.2 ng/L. This study establishes the occurrence of caffeine in Oregon's coastal waters, yet relative importance of sources, seasonal variability, and processes affecting caffeine transport into the coastal ocean require further research.     

The quasar-frame velocity distribution of narrow C iv absorbers

We report on a survey for narrow (full widths at half-minimum <600 km s⁻¹) C  iv absorption lines in a sample of bright quasars at redshifts  1.8 ≤ z < 2.25  in the Sloan Digital Sky Survey. Our main goal is to understand the relationship of narrow C  iv absorbers to quasar outflows and, more generally, to quasar environments. We determine velocity zero-points using the broad Mg  ii emission line, and then measure the absorbers' quasar-frame velocity distribution. We examine the distribution of lines arising in quasar outflows by subtracting model fits to the contributions from cosmologically intervening absorbers and absorption due to the quasar host galaxy or cluster environment. We find that a substantial number (  ≥43 ± 6  per cent) of absorbers with   W ^λ1548₀ > 0.3  Å in the velocity range  +750 ≲ v ≲+ 12 000  km s⁻¹ are intrinsic to the active galactic nucleus outflow. This 'outflow fraction' peaks near   v =+2000  km s⁻¹ with a value of   f _outflow≃ 0.81 ± 0.13  . At velocities below   v ≈+ 2000  km s⁻¹, the incidence of outflowing systems drops, possibly due to geometric effects or to the over-ionization of gas that is nearer the accretion disc. Furthermore, we find that outflow absorbers are on average broader and stronger than cosmologically intervening systems. Finally, we find that ∼14 per cent of the quasars in our sample exhibit narrow, outflowing C  iv absorption with   W ^λ1548₀ > 0.3  Å, slightly larger than that for broad absorption line systems.