Clinoamphibole lamellae in diopside of garnet lherzolite from Alpe Arami,Bellinzona, Switzerland

Porphyroclastic diopside in garnet lherzolite from Alpe Arami, Bellinzona, Switzerland includes optically-visible clinoamphibole lamellae with a composition intermediate between pargasite and edenite. X-ray and electron microscopic observations show that the diopside crystal contains sub-microscopic thin clinoamphibole lamellae parallel to (010), which have coherent interfaces to the host. A kind of planar defect parallel to (010) in clinopyroxene structure, as suggested by Chisholm (1973), is shown here to correspond to intercalation of a 9 Å lattice fringe of double-chain structure in the electron micrograph of the diopside. The thin clinoamphibole lamellae are observed to be segregated domains consisting of two and more 9 Å fringes.From the chemical characteristics and textural relations of the development of such clinoamphiboles, the chemical change required to form them is considered to have been caused principally by decreasing solubility of atoms such as Na, Al and Cr in clinopyroxene structure during the retrogressive reequilibration. Also, a possibility of finite solid solution of clinoamphibole in clinopyroxene is discussed.     

Chemistry and Sulfur Isotopes in a Chert-dominant Sequence around the Stratiform Manganese Deposit of the Noda-Tamagawa Mine, Northern Kitakami Terrane, Northeast Japan: Implication for Paleoceanographic Environmental Setting

Abstract. Chemistry and sulfur isotopes are analyzed for a series of rocks in the chert‐dominant sequence around the stratiform manganese ore deposit of the Noda‐Tamagawa mine in the northern Kitakami Terrane, northeast Japan. The sequence is litholog‐ically classified into six units in ascending order: lower bedded chert, lower black shale, massive chert, manganese ore, upper black shale, and upper bedded chert. The rocks around the manganese ore deposit exhibit anomalous enrichment in Ni (max. 337 ppm), Zn (102) and U (30) in the upper part of lower bedded chert, Mo (122), Tl (79) and Pb (33) in the lower black shale, MnO, Cu (786) and Co (62) in the manganese ore, and As (247) and Sb (17) in the upper black shale. The aluminum‐normalized profiles reveal zonal enrichment of redox‐sensitive elements around the manganese bed: Zn‐Ni‐Fe‐Mo‐U(‐Co), Tl‐Pb(‐Mo), Mn‐Fe‐Cu‐V‐Cr‐Co(‐Zn) and As‐Sb in ascending order. The uppermost part of the lower bedded chert and black shale exhibit negative Ce/Ce* values, whereas the massive chert, manganese ore and lower part of the upper bedded chert display positive values. The isotopic δ³⁴S values are 0±6 % in the lower part of the lower bedded chert, ‐19 to ‐42 % in the upper part of the lower bedded chert, ‐36 to ‐42 % in the lower black shale, ‐28 to ‐35 % in the massive chert, manganese ore and upper black shale, and ‐23±5 % in the upper bedded chert. Thus, there is a marked negative shift in δ³⁴S values in the lower bedded chert, and an upward‐increasing trend in δ³⁴S through the manganese ore horizon. The present data provide evidence for a change in the paleoceanographic environmental resulting from inflow of oxic deepwater into the stagnant anoxic ocean floor below the manganese ore horizon. This event is likely to have triggered the precipitation of manganese oxyhydroxides. The redistribution of redox‐sensitive elements through the formation of metalliferous black shale and manganese carbonate ore may have occurred in association with bacterial decomposition of organic matter during early diagenesis of initial manganese oxyhydroxides.     

U-Pb and Pb-Pb ages of zircons from basaltic eucrites: Implications for early basaltic volcanism on the eucrite parent body

We have undertaken petrologic and SHRIMP U-Th-Pb isotopic studies on zircons from basaltic eucrites (Yamato [Y]-75011, Y-792510, Asuka [A]-881388, A-881467 and Padvarninkai) with different thermal and shock histories. Eucritic zircons are associated with ilmenite in most cases and have subhedral shapes in unmetamorphosed and metamorphosed eucrites. Some zircons in highly metamorphosed eucrites with granulitic texture occur alone in pyroxene, and typically have rounded to subrounded shapes due to recrystallization. Superchondritic Zr/Hf ratios of eucritic zircons indicate that they crystallized from incompatible element-rich melts after crystallization of ilmenite. Concentrations of uranium and thorium in zircons in the unmetamorphosed eucrite Y-75011 are higher than those in metamorphosed eucrites.The U-Pb systems of eucritic zircons are almost concordant but some zircon grains show reverse discordance. Radiogenic lead-loss up to 48% from zircons is observed in the shock-melted eucrite Padvarninkai. The ²⁰⁷Pb-²⁰⁶Pb ages of zircon in Y-75011 (4550 ± 9 Ma, n = 5) are nearly identical, within analytical uncertainty, to the ages of zircons from the metamorphosed eucrite Y-792510 (4545 ± 15 Ma, n = 13), the highly metamorphosed eucrites A-881388 (4555 ± 54 Ma, n = 5) and A-881467 (4558 ± 13 Ma, n = 8), and the shock-melted eucrite Padvarninkai (4555 ± 13 Ma, n = 18). The averaged ²⁰⁷Pb-²⁰⁶Pb age of zircon from five eucrites analyzed in this study is 4554 ± 7 Ma (95% confidence limits, n = 49), indistinguishable from the averaged U-Pb age (4552 ± 9 Ma) of the same samples. Because of the high closure temperature of lead in zircon (T_closure = ∼1050°C with a cooling rate of 0.2°C/yr), the ²⁰⁷Pb-²⁰⁶Pb ages of eucritic zircon do not represent metamorphic ages but crystallization ages of extrusive lavas.This fact strongly suggests that volcanism of the eucrite parent body occurred at a very early stage of the Solar System history, 7-20 Ma after CAI formation (4567.2 ± 0.6 Ma), thus basaltic eucrites crystallized from parental magmas within a short interval following the differentiation of their parent body. The U-Pb ages of eucritic zircons are older than the U-Pb, Sm-Nd and Rb-Sr ages of some basaltic eucrites, which is consistent with differences in closure temperatures of each isotopic system, and suggests that thermal and shock metamorphism affected the isotopic systems of pyroxene, plagioclase and phosphates.     

The Stannern trend eucrites: Contamination of main group eucritic magmas by crustal partial melts

We report on the petrology of a new eucrite belonging to the Stannern trend and discuss the origin of this trend. The eucrite Northwest Africa 4523 (NWA 4523) is an equilibrated eucrite consisting of dark clasts embedded in a fine-grained crystallized matrix. Two types of clasts have been observed: medium-grained ophitic/subophitic clasts, and very fine-grained clasts. Despite textural differences, the clasts display the same mineralogy, in particular the same kind of pyroxenes with pigeonitic cores containing sparse exsolution lamellae, and augitic rims, zoned plagioclases and the occurrence of K-feldspar. The major and trace element abundances of a large medium-grained clast are very similar to Stannern or Bouvante.The Stannern trend eucrites are characterized by high incompatible trace element abundances. Their trace element patterns normalized to a representative Main Group eucrite, exhibit significant Eu, Sr and Be negative anomalies. In this paper, we show that contamination of Main Group eucritic magmas by melts derived by partial melting of the asteroid’s crust can successfully explain both the high incompatible trace elements concentrations and the distinctive Eu, Sr, Be anomalies shown by the Stannern trend eucrites. This model is in agreement with the view that Stannern and some Main Group-Nuevo Laredo trend eucrites have been contemporaneously erupted, and with the probable assumption that Stannern trend eucrites formed rather late in the history of the 4-Vesta’s crust.     

Observed response of marine boundary layer cloud to the interannual variations of summertime Oyashio extension SST front

Active roles of both sea surface temperature (SST) and its frontal characteristics to the atmosphere in the mid-latitudes have been investigated around the western boundary current regions, and most studies have focused on winter season. The present study investigated the influence of the variation of the summertime Oyashio extension SST front (SSTF) in modulating low-level cloud properties (i.e., low-level cloud cover [LCC], cloud optical thickness [COT], and shortwave cloud radiative effect [SWCRE]) on inter-annual timescales, based on available satellite and Argo float datasets during 2003–2016. First, we examined the mechanism of summertime SSTF variability itself. The strength of the SSTF (S_SSTF), defined as the maximum horizontal gradient of SST, has clear inter-annual variations. Frontogenesis equation analysis and regression analysis for subsurface temperature indicated that the inter-annual variations of the summertime S_SSTF in the western North Pacific are closely related to the variations of not surface heat flux, but western boundary currents, particularly the Oyashio Extensions. The response of low-level cloud to intensified S_SSTF is that negative SWCRE with positive COT anomaly in the northern flank of the SSTF can be induced by cold SST anomalies. The spatial scale of the low-level cloud response was larger than the SST frontal scale, and the spatial distribution of the response was mainly constrained by the pathways of Kuroshio and Oyashio Extensions. Multi-linear regression analysis revealed that the local SST anomaly played largest role in modulating the SWCRE and COT anomalies among the cloud controlling factors (e.g., estimated inversion strength, air-temperature advection) accounting for more than 50% of the variation. This study provides an observational evidence of the active role of local SST anomalies in summertime associated with the western boundary currents to the oceanic low-level cloud.

     

The Ganges and Brahmaputra rivers in Bangladesh: basin denudation and sedimentation

Every year the Ganges and Brahmaputra rivers in Bangladesh transport 316 and 721 million tonnes of sediment, respectively. These high loads of suspended sediment reflect the very high rate of denudation in their drainage basins. The average mechanical denudation rate for the Ganges and Brahmaputra basins together is 365 mm 10³ yr⁻¹. However, the rate is higher in the Brahmaputra Basin than that in the Ganges Basin. Several factors, including mean trunk channel gradient, relief ratio, runoff, basin lithology and recurring earthquakes are responsible for these high denudation rates. Of the total suspended sediment load (i.e. 1037 million tonnes) transported by these rivers, only 525 million tonnes (c. 51% of the total load) are delivered to the coastal area of Bangladesh and the remaining 512 million tonnes are deposited within the lower basin, offsetting the subsidence. Of the deposited load, about 289 million tonnes (about 28% of the total load) are deposited on the floodplains of these rivers. The remaining 223 million tonnes (about 21% of the total load) are deposited within the river channels, resulting in aggradation of the channel bed at an average rate of about 3·9 cm yr⁻¹. Although the Brahmaputra transports a higher sediment load than the Ganges, the channel bed aggradation rate is much higher for the Ganges. This study also documents a wide range of interannual, seasonal and daily variation in suspended sediment transport and water discharge. Interannual variation in sediment deposition within the basin is also suggested. Copyright © 1999 John Wiley & Sons, Ltd.     

Predicting Soil-Water and Soil-Air Transport Properties and Their Effects on Soil-Vapor Extraction Efficiency

Accurate prediction of water and air Iran sport parameters in variably saturated soil is necessary for modeling of soil-vapor extraction (SVE) at soil sites contaminated with volatile organic chemicals (VOCs). An expression for predicting saturated water permeability (k_l,s) in undisturbed soils from the soil total porosity and the field capacity soil-water content was developed by fitting a tortuous-tube fluid flow model to measured water permeability and gas diffusivity data. The new k_l,s expression gave accurate predictions when tested against independent k_l,s data. The k_l,s expression was implemented in the Campbell relative water permeability model to yield a predictive model for water permeability in variably saturated, undisturbed soil. The water permeability model, together with recently developed predictive equations for gas permeability and gas diffusivity, was used in a two-dimensional numerical SVE model that also included non-equilibrium mass transfer of VOC from a separate phase (nonaqueous phase liquid [NAPL]) to the air phase. SVE: calculations showed that gas permeability is likely the most important factor controlling VOC migration and vapor extraction efficiency. Water permeability and gas diffusivity effects became significant at water contents near and above field capacity. The NAPL-air mass transfer coefficient also had large impacts on simulated vapor extraction efficiency. The calculations suggest that realistic SVE models need to include predictive expressions for both conveciive, diffusive. and phase-partitioning processes in natural, undisturbed soils.     

The Kellwasser events in the Upper Devonian Frasnian to Famennian transition in the Toc Tat Formation,northern Vietnam

Upper Devonian carbonates of the Toc Tat Formation in the Si Phai Pass area of Dong Van District, northern Vietnam were deposited in carbonate platform, slope, and basin environments. These carbonates yield abundant conodonts indicative of the Palmatolepis nasuta, Pa. linguiformis and Pa. triangularis zones, the Frasnian–Famennian stage boundary being identified by the first occurrence of Pa. triangularis. Two positive carbon isotope excursions are recognized, the lower excursion peaking in the interval of the lower to middle Pa. nasuta Zone, whilst the upper excursion peaks just above the local Frasnian–Famennian boundary. Based on the biostratigraphy, these excursions equate to the Lower and Upper Kellwasser events. Locally, tentaculitoid taxa (Nowakia, Styliolina, Homoctenus, and Metastyliolina?) are abundant in the interval of the Pa. nasuta Zone, but show a drastic decline in abundance before the Lower Kellwasser Event, and only two taxa survived into the Famennian.     

Bidirectional shaking table tests of a low-cost friction sliding system with flat-inclined surfaces

A novel low-cost friction sliding system for bidirectional excitation is developed to improve the seismic performance of reinforced concrete (RC) bridge piers. The sliding system is a spherical prototype developed by combining a central flat surface with an inclined spherical segment, characterized by stable oscillation and a large reduction in response accelerations on the flat surface. The inclined part provides a restoring force that limits the residual displacements of the system. Conventional steel and concrete are employed to construct a flat-inclined spherical surface atop an RC pier. The seismic forces are dissipated through the frictions generated during the sliding movements; hence, the seismic resilience of bridges can be ensured with a low-cost design solution. The proposed system is fabricated utilizing a mold created by a three-dimensional printer, which facilitates the use of conventional concrete to construct spherical shapes. The concrete surface is lubricated with a resin material to prevent abrasion from multiple input ground motions. To demonstrate the effectiveness of the system, bidirectional shaking table tests are conducted in the longitudinal and transverse directions of a scaled bridge model. The effect of the inclination angle and the flat surface size is investigated. The results demonstrate a large decrease in response acceleration when the system exhibits circular sliding displacement. Furthermore, the inclination angle that generates the smallest residual displacement is identified experimentally.     

Investigation of ULF Seismo-Magnetic Phenomena in Kanto, Japan During 2000–2010: Case Studies and Statistical Studies

In order to clarify the ultra low frequency (ULF) seismo-magnetic phenomena, a sensitive geomagnetic network has been installed in Kanto, Japan. In this study, we have analyzed geomagnetic data observed during the past decade in Izu and Boso Peninsulas. Energy of ULF geomagnetic signals at the frequency around 0.01 Hz has been investigated by wavelet transform analysis. To identify anomalous changes in ionospheric disturbances, the station Memabutsu has been chosen as a reference station. Case studies of magnitude 6 class earthquakes have demonstrated that there are unusual geomagnetic energy enhancements in the vertical component before the main shocks. Statistical studies by superposed epoch analysis have indicated that, before a sizeable earthquake, there are clearly higher probabilities of ULF anomalies than after the earthquake: statistical results of daily counts were found significant at about 3–4 weeks before, 1 week before, few days before, and 1 day after the event for Seikoshi station in Izu and around 2 weeks before, few days before, and 1 day after the event for Kiyosumi station in Boso, respectively.