Geochemical characteristics of heavy metals in coastal sediments from the northern Beibu Gulf (SW China): the background levels and recent contamination

Four sediment cores and one hundred surface sediments were collected from the intertidal zone of the northern Beibu Gulf (SW China). In order to detect the intensity of metal contamination recently, the background levels were successfully established for Pb, Zn, Cd and Cr, based on the linear regression of deeper sediments (pre-industrial). Aluminum is a better geochemical normalizer than Fe and it is commonly used to describe the natural metal variability of the coastal sediments. The evident enrichment of Zn and Cd is recorded in the surface sediments of the eastern side of the Guangxi coast and the central part of the Qinzhou Bay, but it does not exceed the effects range-low values, due to a low percentage of fine-grained sediments in the region. Although the Pb and Cr concentrations are mainly of natural origin, 3 and 6% sites exceed the effects range-low values, respectively; indicating the potential for adverse ecological effects of metals on the benthic communities.     

Brittle-plastic deformation in initially dry rocks at fluid-present conditions: transient behaviour of feldspar at mid-crustal levels

We present detailed microstructural and chemical analyses from an initially dry anorthositic rock deformed during wet amphibolite facies conditions. Three different domains representing the microstructural variation of the deformed samples are investigated in detail in terms of fracture morphology and mode, grain characteristics and chemistry of present phases. Results show transient deformational behaviour where a close interaction between brittle, plastic and fluid-assisted deformation mechanisms can be observed. Our analysis allows us to describe the succession, interrelationships and effects of active mechanisms with progressively increasing strain in three so-called stages. In Stage 1, initial fracturing along cleavage planes promoted fluid influx that caused fragmentation and chemical reactions, producing fine-grained mineral assemblages in the fractures. Deformation twins and dislocations developed in clast pieces due to stress relaxation. Passive rotation of conjugate fracture sets and interconnection of intracrystalline fractures formed micro-shear-zones, constituting Stage 2. Microstructures and grain relationships indicate the activity and fluctuation between fracturing, dissolution-precipitation creep, grain boundary sliding and locally dislocation creep, reflecting the transient behaviour of brittle and plastic deformation mechanisms. Further rotation and widening of fractures into overall foliation parallel shear-bands (Stage 3) promoted strain partitioning into these areas through increased fluid influx, influence of fluid-assisted grain boundary sliding, phase mixing and presence of weak phases such as white mica. We suggest that local differences in fluid availability, volume fraction of weak phases produced by fluid present metamorphic reactions coupled with volume increase and local variations in stress concentration induced transient brittle-plastic behaviour. The studied shear-zone represents an example of the transformation of a rigid dry rock to a soft wet rock during deformation through syntectonic fracturing.     

The early Miocene (~25 Ma) volcanism in the northern Kyushu-Palau Ridge,enriched mantle source injection during rifting prior to the Shikoku backarc basin opening

The northern Kyushu-Palau Ridge (KPR), remnant conjugate arc of the Izu-Ogasawara (Bonin)-Mariana (IBM) active arc, is dominated by basalt-andesite except for the Komahashi-Daini Seamount where acidic plutonic rocks of 38 Ma were recovered. These mafic to intermediate volcanics are produced by the rifting volcanism in the proto-IBM arc associated with spreading of the Shikoku Basin. The HFSE and HREE contents and ratios of these volcanics indicate enriched source mantle composition compared to recent volcanic front. The LILE ratios exhibit similar characteristics to reararc volcanism of the recent Izu arc, and some enriched volcanics exhibit high abundance of sediment melt inputs. Based on these observations and compilations of the published data set, the replacement event of the wedge mantle under the IBM arc occurred two times. The first event occurred between 45 and 38 Ma, with Pacific type mantle being replaced by depleted Indian type mantle. The second event occurred between 36 and 25 Ma, enriched mantle flowed from reararc side. The slab component during the proto-IBM arc rifting was a similar characteristic to recent reararc volcanism of the Izu arc, and sediment melt added in a local area.     

Early Triassic potassic volcanism in the Afyon Zone of the Anatolides/Turkey: implications for the rifting of the Neo-Tethys

Afyon Zone, which was derived from the Anatolide–Tauride platform during closure of the Neo-Tethys, is made up of pre-Mesozoic basement and unconformably overlying Triassic–Early Tertiary cover series. The Afyon Zone contains widespread metavolcanic rocks, which are dominated by rhyolite, dacite, and trachyandesite. They form a distinct volcanic succession, which is separated from the underlying Silurian–Lower Carboniferous metacarbonates and meta-siliciclastics by a regional unconformity. Trachyandesitic metavolcanics are made up of massive lava flows, pyroclastics and epiclastics, less frequently, domes and dikes, which were developed on a deeply eroded subaerial landmass. U/Pb and Pb/Pb zircon geochronology yielded Lower Triassic (~250 Ma) ages, which are interpreted as extrusion age of trachyandesitic volcanics. Based on the stratigraphic, geochronological, and geochemical data, we suggest that these Lower Triassic magmatic rocks represent an extensional tectonic setting on the northern active margin of the Gondwana, which led to the development of the northern branch of the Neo-Tethys.     

Permian continental basins in the Southern Alps (Italy) and peri-mediterranean correlations

The Late Carboniferous to Permian continental successions of the Southern Alps can be subdivided into two main tectono-sedimentary Cycles, separated by a marked unconformity sealing a Middle Permian time gap, generally estimated at over 10 Ma. The lower cycle (1), between the Variscan crystalline basement and the Early Permian, is mainly characterised by fluvio-lacustrine and volcanic deposits of calc-alkaline acidic-to-intermediate composition, which range up to a maximum thickness of more than 2,000 m. The upper cycle (2), which is devoid of volcanics, is mostly dominated through the Mid?–Late Permian by alluvial sedimentation which covered the previous basins and the surrounding highs, giving rise to the subaerial Verrucano Lombardo-Val Gardena (Gröden) red-beds, up to about 800 m thick. The palaeontological record from the terrigenous deposits of both the above cycles consists mainly of macro- and microfloras and tetrapod footprints. The age of the continental deposits is widely discussed because of the poor chronological significance of a large number of fossils which do not allow reliable datings; however, some sections are also controlled by radiometric calibrations. The comparison with some selected continental successions in southern Europe allows to determine their evolution and set up correlations. A marked stratigraphic gap shows everywhere between the above-mentioned Cycles 1 and 2. As in the Southern Alps, the gap reaches the greatest extent during the Mid-Permian, near the Illawarra Reversal geomagnetic event (265 Ma). In western Europe, however, such as in Provence and Sardinia, the discussed gap persists upwardly to Late Permian and Early Triassic or slightly younger times, i.e. to the onset of the “Alpine sedimentary Cycle”, even though in northeastern Spain (Iberian Ranges, Balearic Islands) this gap results clearly interrupted by late Guadalupian–Lopingian deposits. The above two major tectonosedimentary cycles reflect, in our view, two main geodynamic events that affected the southern Europe after the Variscan orogenesis: the Late Carboniferous–Early Permian transformation of the Gondwana–Eurasia collisional margin into a diffuse dextral transform margin and the Middle–Late Permian opening of the Neotethys Ocean, with the onset of a generalised extensional tectonic regime and the progressive westward marine ingression.     

Driftwood deposition from debris flows at slit-check dams and fans

Experience shows that debris flows containing large woody debris (driftwood) can be more damaging than debris flows without driftwood. In this study, the deposition process of debris flows carrying driftwood was investigated using numerical simulations and flume experiments. Debris-flow trapping due to driftwood jamming in a slit-check dam was also investigated. A numerical model was developed with an interacting combination of Eulerian expression of the debris flow and Lagrangian expression of the driftwood, in which the fluctuating coordinates and rotation of the driftwood were treated stochastically. The calculated shapes and thicknesses of a debris-flow fan and the positions and orientations of the deposited driftwood on a debris-flow fan were consistent with experimental flume results. The jamming of driftwood in a slit-check dam was evaluated based on geometry and probability. The simulated results of outflow discharge and the proportion of driftwood passed through the slit-check dam also agreed with the experimental results.     

A macro-scale flood risk model for Jamaica with impact of climate variability

Floods account for more than half of the global hydrometeorological risks. Severe floods cause significant economic shocks and loss of lives, particularly for developing countries such as Jamaica. There is need for more information on the present and projected flood risks to justify macro-scale planning for climate change adaptation and facilitate the decision-making processes. In this study, a catalogue of 198 flood events occurring between 1678 and 2010 is compiled for Jamaica and used to examine the climatology, occurrence, trends, causes and duration of the island’s severe events. The annual flood risk is estimated to be a loss of life rate of 4 persons and estimated annual damage of USD96.3 million per annum in 2010 values and approximately 0.84 % of GDP per annum. Macro-scale models for flood risks (deaths and damages) are also developed using data from the flood catalogue and maximum precipitation at the town and parish level. The models examine the relationship between flood risks (death and damages) and extreme rainfall depths and intensities. Future climate risks of loss of lives and damages are predicted to increase 11 and 9 %, respectively, to 4.4 persons and USD105.2 million per annum.     

High-dimensional geostatistical history matching

Hydrocarbon reservoir modelling and characterisation is a challenging subject within the oil and gas industry due to the lack of well data and the natural heterogeneities of the Earth’s subsurface. Integrating historical production data into the geo-modelling workflow, commonly designated by history matching, allows better reservoir characterisation and the possibility of predicting the reservoir behaviour. We present herein a geostatistical-based multi-objective history matching methodology. It starts with the generation of an initial ensemble of the subsurface petrophysical property of interest through stochastic sequential simulation. Each model is then ranked according the match between its dynamic response, after fluid flow simulation, and the observed available historical production data. This enables building regionalised Pareto fronts and the definition of a large ensemble of optimal subsurface Earth models that fit all the observed production data without compromising the exploration of the uncertainty space. The proposed geostatistical multi-objective history matching technique is successfully implemented in a benchmark synthetic reservoir dataset, the PUNQ-S3, where 12 objectives are targeted.     

Constraint energy minimizing generalized multiscale finite element method in the mixed formulation

This paper presents a novel mass-conservative mixed multiscale method for solving flow equations in heterogeneous porous media. The media properties (the permeability) contain multiple scales and high contrast. The proposed method solves the flow equation in a mixed formulation on a coarse grid by constructing multiscale basis functions. The resulting velocity field is mass-conservative on the fine grid. Our main goal is to obtain first-order convergence in terms of the mesh size which is independent of local contrast. This is achieved, first, by constructing some auxiliary spaces, which contain global information that cannot be localized, in general. This is built on our previous work on the generalized multiscale finite element method (GMsFEM). In the auxiliary space, multiscale basis functions corresponding to small (contrast-dependent) eigenvalues are selected. These basis functions represent the high-conductivity channels (which connect the boundaries of a coarse block). Next, we solve local problems to construct multiscale basis functions for the velocity field. These local problems are formulated in the oversampled domain, taking into account some constraints with respect to auxiliary spaces. The latter allows fast spatial decay of local solutions and, thus, allows taking smaller oversampled regions. The number of basis functions depends on small eigenvalues of the local spectral problems. Moreover, multiscale pressure basis functions are needed in constructing the velocity space. Our multiscale spaces have a minimal dimension, which is needed to avoid contrast dependence in the convergence. The method’s convergence requires an oversampling of several layers. We present an analysis of our approach. Our numerical results confirm that the convergence rate is first order with respect to the mesh size and independent of the contrast.