微波消解-电感耦合等离子体质谱法测定铁矿石中15个稀土元素

分析地质样品中稀土元素的含量,现有的方法都受到基体干扰和共存元素干扰,电感耦合等离子体质谱(ICP-MS)已在痕量元素分析中得到广泛应用,通过条件优化可准确测定稀土元素。本文建立了ICP-MS同时测定铁矿石中钇镧铈镨钕钐铕钆铽镝钬铒铥镱镥15个稀土元素的方法,样品用盐酸、硝酸和氢氟酸高温密闭消解,消解完全后转移定容,在线加入¹⁰³Rh、¹¹⁵In、¹⁸⁵Re内标液进行测定,方法回收率为95%~104%,精密度(RSD)≤3.5%。对12个国家24个代表性主产区进口的铁矿石样品进行检测,分析其稀土元素的配分模式特征为右倾型轻稀土富集,现阶段的进口铁矿粉多为多产区复合配矿。本方法较其他传统方法大幅降低能耗,提高了分析效率,初步探讨的稀土元素丰度特征可为研究主产区铁矿石的矿床成因、提高我国烧结球团矿的加工工艺提供依据。     

26Al‐26Mg isotope systematics of the first solids in the early solar system

High‐precision bulk aluminum‐magnesium isotope measurements of calcium‐aluminum‐rich inclusions (CAIs) from CV carbonaceous chondrites in several laboratories define a bulk ²⁶Al‐²⁶Mg isochron with an inferred initial ²⁶Al/²⁷Al ratio of approximately 5.25 × 10^?5, named the canonical ratio. Nonigneous CV CAIs yield well‐defined internal ²⁶Al‐²⁶Mg isochrons consistent with the canonical value. These observations indicate that the canonical ²⁶Al/²⁷Al ratio records initial Al/Mg fractionation by evaporation and condensation in the CV CAI‐forming region. The internal isochrons of igneous CV CAIs show a range of inferred initial ²⁶Al/²⁷Al ratios, (4.2–5.2) × 10^?5, indicating that CAI melting continued for at least 0.2 Ma after formation of their precursors. A similar range of initial ²⁶Al/²⁷Al ratios is also obtained from the internal isochrons of many CAIs (igneous and nonigneous) in other groups of carbonaceous chondrites. Some CAIs and refractory grains (corundum and hibonite) from unmetamorphosed or weakly metamorphosed chondrites, including CVs, are significantly depleted in ²⁶Al. At least some of these refractory objects may have formed prior to injection of ²⁶Al into the protosolar molecular cloud and its subsequent homogenization in the protoplanetary disk. Bulk aluminum and magnesium‐isotope measurements of various types of chondrites plot along the bulk CV CAI isochron, suggesting homogeneous distribution of ²⁶Al and magnesium isotopes in the protoplanetary disk after an epoch of CAI formation. The inferred initial ²⁶Al/²⁷Al ratios of chondrules indicate that most chondrules formed 1–3 Ma after CAIs with the canonical ²⁶Al/²⁷Al ratio.     

河北省灵寿县西石门金矿黄铁矿热电性标型及其找矿意义

河北省灵寿县西石门石英脉型金矿位于华北地台太行隆起区之南东部的阜平矿集区,与该区石湖大型金矿受不同断裂控制。黄铁矿是矿床的主要载金矿物,以4个世代产出于黄铁矿-石英阶段(I)、石英-黄铁矿阶段(II)、多金属硫化物阶段(III)和石英-碳酸盐阶段(IV)等4个成矿阶段,其中,石英-碳酸盐阶段的黄铁矿十分稀少。本矿段黄铁矿单晶热电系数变化范围为-328~341μV/℃,从早期到晚期,4个世代的黄铁矿热电系数离散性先增大再减小,石英黄铁矿阶段（II）离散性最大。从黄铁矿-石英阶段(I)至石英-碳酸盐阶段(IV),黄铁矿热电导型的变化规律是P>N(III)→P>>N (IV); P型黄铁矿热电系数均值αP和出现率P%由浅部到深部,总体为逐渐降低,局部呈波状起伏,与矿石金品位呈正相关关系.黄铁矿的热电系数温标计算和投图表明,该矿床的成矿温度集中在168～330℃,为中低温矿床。热电系数在50—200μV/℃之间的黄铁矿是富金矿段的标志。综合分析认为,该矿床290m以下仍有良好的找矿潜力。     

A 352-year record of summer temperature reconstruction in the western Tianshan Mountains,China, as deduced from tree-ring density

Three robust tree-ring density chronologies were developed for the western Tianshan Mountains of northwestern China. The chronologies were significantly correlated and form a regional chronology (GLD). The GLD had significant and positive correlations with temperature of warm seasons. Based on this relationship, the mean minimum temperatures of May to August were reconstructed using the GLD chronology for the period AD 1657 to 2008. The temperature reconstruction exhibited temperature patterns on interannual to centennial timescales, and showed that the end of the 20th century is the warmest period in the past 352 years. The reconstructed temperature variation has a teleconnection with large-scale atmospheric–oceanic variability and captures long- and broad-scale regional climatic variations.     

论“牛岚构造体系”特征及其对蒙阴金伯利岩带的控制

鲁西地区作为华北克拉通的一部分,自古元古代早期（约2400Ma）二长花岗质岩石侵位以后至晚古生代（约250Ma）,一直处于板内稳定地块状态,在这漫长的2150Ma年里仅形成了两期脉岩,即四堡期侵位的基性辉绿岩（牛岚单元）与中晚奥陶世侵位的超基性金伯利岩（常马庄单元）。经对控制辉绿岩侵位的构造特征进行研究发现,该构造体系不仅控制了鲁西辉绿岩的侵位,还控制了金伯利岩的侵位。在此基础上,对蒙阴金伯利岩带的控制规律进行了分析,并对金伯利岩带向南延伸的区域进行了初步的预测。     

沧东断裂山岭子东段地质构造分析

依据钻井、MT测深、地震剖面资料对沧东断裂山岭子东段地质构造进行了研究,认为该段沧东断裂断面形态呈“阶形”,自沧县隆起至北塘凹陷由高、中、低三个台阶组成断阶构造。中生代白垩纪末期,在南东-北西向压扭应力作用下形成褶皱及逆断层,新生代古近纪反转为正断层,断阶带内发育北东及北北西向共轭剪切断层,它们是沟通不同热储层的重要通道。     

Investigation of manganese tolerance and accumulation of two Mn hyperaccumulators Phytolacca americana L. and Polygonum hydropiper L. in the real Mn-contaminated soils near a manganese mine

Up to date, very few studies have examined the phytoextraction ability of hyperaccumulators in the real soils contaminated with heavy metals following the identification of the hyperaccumulators using hydroponics tests. In the present study, amended with a chemical-mobilizing agent of ethylene diamine triacetic acid (EDTA), the manganese accumulation, tolerance and the hyperaccumulating ability of two hyperaccumulators Phytolacca americana L. (Phytolaccaceae) and Polygonum hydropiper L. (Polygonaceae) proved by previous hydroponics tests were examined using pot experiments with paddy soils contaminated with Mn (1,047 ± 53 mg kg^?1) collected from one site in the vicinity of one manganese mine in Xiushan county of Chongqing, China. Results showed that the root and shoot biomass of P. americana and the chlorophyll production of P. hydropiper were significantly inhibited by EDTA treatments while the chlorophyll production of P. americana was oppositely obviously promoted by EDTA. It is noteworthy that, with or without EDTA treatment, the shoot Mn concentrations of both plant species were significantly below the hyperaccumulator threshold, indicating these two plants concealed their hyperaccumulating ability in the studied soils. Thus, further detailed studies need to be conducted to promote the metal hyperaccumulating capacity of these two plant species under comparably low Mn-contaminated soil conditions as shown in this study before the successful application of these Mn hyperaccumulators identified in laboratories to the phytoextraction of lightly or moderately Mn-contaminated agricultural soils.     

螺杆钻具转子表面磨损规律研究

转子是螺杆钻具的核心部件,与定子相配合,决定了螺杆钻具的工作效率和动力性能。主要研究不同泥浆固相含量和添加剂对螺杆钻具转子表面磨损的影响,并设计了专用试验装置以模拟近井下条件工作时螺杆钻具转子的表面磨损情况,对其磨损规律开展研究,探索了转子在不同泥浆条件下的磨损规律,并结合相关磨损机理进行了进一步分析。初步发现了对硬铬镀层损伤较大的因素是泥浆固相与盐类添加剂,进而确定了硬铬镀层磨损的主要形式是腐蚀磨损,从而形成了对转子的制造工艺及使用方法的有益建议。     

地质专业英汉翻译难点与技巧

结合地质专业英语词汇、句法特点,通过大量实例,总结探讨其翻译难点与技巧.供地质工作者参考.