Adsorption of Pentachlorophenol onto Oxide and Clay Minerals： Surface Reaction Model and Environmental Implications

The adsorption of pentachlorophenol （PCP） onto quartz, kaolinite, illite, montmorillonite and iron oxides has been investigated by batch equilibrium techniques. The pH-dependent isotherms are curves with peak values, the position of which is at about pH = 5-6 depending on the mineral species. Based on distribution of both speciation of surface hydroxyls on minerals and PCP in solution a surface reaction model involving surface complexation and surface electrostatic attraction is presented to fit the pH-dependent isotherms, and both reaction constants are calculated. The results show that on quartz and phyllosilicate minerals the predominant adsorption reaction is surface complexation, meanwhile both of surface electrostatic attraction and surface complexation are involved on the iron oxide minerals. The reaction constants of surface electrostatic adsorption are usually one to three orders in magnitude, larger than that of surface complexation. The concentration-dependent isotherms can be well fitted by Langmnir equation with the correlation coefficient R〉0.93 for kaolinite and iron oxides. The maximum adsorption is found in the order： hematite 〉 lepidocrocite 〉 goethite 〉 kaolinite 〉 quartz 〉 montmorillonite ≈ illite, which can be interpreted by consideration of both reaction mechanism and surface hydroxyl density. The significant adsorption of PCP onto mineral surfaces suggests that clay and iron oxide minerals will play an important role as HIOCs are adsorbed in laterite or latertoid soil, which is widespread in South China.     

北斗广播电文钟差模型精度评估及改善策略

星载原子钟是北斗卫星导航系统(BDS)的核心设备,其钟差模型是北斗广播电文的重要组成部分,模型精度直接影响BDS的服务性能.本文采用星地双向时频传递(TWSTF)钟差测量为参考,评估了BDS广播电文钟差模型精度,结果表明BDS广播电文钟差模型精度优于2 ns(数据龄期小于12 h).针对BDS广播电文钟差参数解算问题,...     

激光雷达点云树木建模研究进展与展望

三维树木几何模型是数字城市与数字林业工程的重要组成部分.针对点云树木建模,深入分析了基于广义(泛在)激光雷达点云的树木模型重建方法,提出了聚类思想建模、图论方法建模、先验假设建模、拉普拉斯算子建模与轻量化表达建模5类建模体系,归纳总结了不同建模体系在树冠枝干的细节表达、建模算法性能、树木模型的多层次细节表达、建模体系综...     

带保温层管道腐蚀状态的X射线检测方法研究

随着无损检测技术的飞速发展,X射线实时成像技术获得了广泛的应用.本文论述了带保温层管道的X射线实时成像检测方法,重在对管道腐蚀缺陷深度如何定量的实验方法研究,和管道缺陷处厚度与图像灰度的数学模型建立,从而对管道腐蚀厚度进行定量,管道缺陷的定量研究有助于管道安全运行的评价和隐患问题的及时发现.     

基于无人机遥感和面向对象法的简单地物分类研究

近年来,全国各地进行了大范围的土地利用调查,随着无人机遥感技术越来越成熟,无人机影像分析技术已深入应用到土地利用调查中,其中最多的用途是地物分类。本文选择昭通市昭阳区某乡镇区域为研究区,对采集到的无人机影像进行预处理,生成对应的正射影像;基于多种可见光植被指数,计算每3种指数合并得到影像的OIF指数,确定最佳波段组合;采用基于规则和基于样本两种面向对象分类方法,提取房屋、道路、植被等简单地物及背景。分析结果:两种方法的提取精度均达到90%以上,基于规则的面向对象分类方法精度较高,但耗时较长;基于样本的面向对象方法耗时较短,精度相对较低。两种方法相结合的全自动分类提取是下一步研究的目标。     

基于D-InSAR技术的金沙江地区滑坡形变监测与分析

滑坡是发生在我国山区的主要地质灾害类型,金沙江地区由于地势较高、地形复杂、多云多雨的特点,给传统的滑坡监测增加了难度。合成孔径雷达差分干涉测量技术(Differential interferometry synthetic aperture radar,D-InSAR)已在滑坡地面沉降监测中得到了广泛应用。本文选取金沙江上游沿岸作为研究区域,基于2018年8月11日与9月28日的Sentinel-1A影像及SRTM1数据,利用GAMMA软件及D-InSAR技术监测到金沙江地区的地表形变,成功识别出金沙江右岸的一处滑坡灾害。研究结果显示,在此滑坡的坡顶部分出现了约2.5 cm的沉降,而在坡底部分由于崩塌物的累积,地面出现了约3 cm的抬升。从实验结果可以得出,InSAR技术是一种有效的滑坡变形监测手段,利用Sentinel-1A卫星的SAR数据对滑坡区域进行形变监测,可以得到较好的干涉结果。     

基于二三维一体化的智慧警务地理信息平台建设与研究

"智慧警务"是"智慧城市"的重要组成部分,也是社会治安防控体系发展的必然趋势,应提高认识,积极探索和论证建设"智慧警务"的模式和方法。本文阐述了基于二三维一体化的智慧警务地理信息平台建设内容和总体框架,并详细地介绍了警用地理信息系统及智慧警务应用系统建设内容和技术路线。     

Experimental Study and Fatigue Analysis of Vortex-Induced Vibration of Umbilical Cable Considering Internal Friction

In order to investigate the effect of internal friction of umbilical cable on its vortex-induced vibration(VIV)responses, the experimental study on VIV of bond umbilical cable(BUC) and un-bond umbilical cable(UBUC) was carried out in an experimental tank. A current generator in the laboratory simulated the uniform current, and the current velocities were observed in real time by using a Doppler Velocimeter. In addition, different sizes of top tension were applied to the umbilical cable model. The VIV responses of the umbilical cable model were measured by using Fiber Bragg grating(FBG) strain sensors. The displacement responses of umbilical cable model were reconstructed based on the experimental strain data processed by modal superposition method. In this paper, the traveling wave characteristics, the spatial-temporal distribution characteristics of frequency and fatigue damage of the BUC and UBUC under VIV are studied. The experimental results show that there are obvious differences between BUC and UBUC in the response characteristics of VIV. The UBUC appears the traveling wave sooner than BUC, but its standing wave characteristics are more obvious than those of BUC at high velocities. Compared with BUC, the spatial-temporal distribution of UBUC frequencies appears wide-band distribution sooner, but has narrower bandwidth in the "lock-in" state. The level of fatigue damage of BUC was approximately the same as that of UBUC.     

Influence Analysis and Vibration Restraint Solutions Research on the Underwater Acoustic Monitoring System

China Ocean Engineering - In order to reduce the hydrodynamic and structural influences on the detection accuracy especially in the very-low-frequency range, some vibration restraint methods are...     

碟形越浪式波能发电装置的三维数值模拟

基于计算流体力学软件的三维数值模拟技术,分析了碟形越浪式波能发电装置的越浪性能,通过构建基于水气两相VOF(Volume of Fluid)模型的三维数值波浪水槽对该装置进行三维数值模拟研究,数值计算结果与物理试验结果相互对比验证较为吻合,验证了所构建的三维数值波浪水槽的可靠性,通过考察装置的坡度、导流叶片个数、干舷高度对越浪性能的影响确定装置的最优结构参数。结果表明,在装置的斜坡面边缘增加回流板可减少波浪的反射,提高装置的越浪性能。在数值模拟中将装置的斜坡面边缘处安装回流板对碟形越浪式波能发电装置参数进行优化,通过分析回流板的长度对装置越浪性能的影响来探索最优回流板长度。