Numerical Study of Failure Mechanism of Serial and Parallel Rock Pillars

Using a numerical modelling code, rock failure process analysis, 2D, the progressive failure process and associated acoustic emission behaviour of serial and parallel rock samples were simulated. Both serial- and parallel sample models are presented for investigating the mechanism of rock pillar failure. As expected, the numerical results show that not only the stiffness, but also the uniaxial compressive strength of the rock plays an important role in pillar instability. For serial pillars, the elastic rebound of a rock pillar with higher uniaxial compressive strength can lead to the sudden failure of an adjacent rock pillar with lower uniaxial compressive strength. The failure zone forms and develops in the pillar with lower uniaxial compressive strength; however, the failure zone does not pass across the interface of the two pillars. In comparison, when two pillars have the same uniaxial compressive strengths but different elastic moduli, both serial pillars fail, and the failure zone in the two pillars can interact, passing across the interface and entering the other pillar. For parallel pillars, damage always develops in the pillar having the lower uniaxial compressive strength or lower elastic modulus. Furthermore, in accordance with the Kaiser effect, the stress-induced damage in a rock pillar is irreversible, and only when the previous stress state in the failed rock pillar is exceeded or the subsequent applied energy is larger than the energy released by the external loading will further damage continue to occur. In addition, the homogeneity index of rock also can affect the failure modes of parallel pillars, even though the uniaxial compressive strength and stiffness of each pillar are the same.     

Iron isotopic systematics of UHP eclogites respond to oxidizing fluid during exhumation

The iron stable isotope compositions (δ⁵⁶Fe) and iron valence states of ultrahigh‐pressure eclogites from Bixiling in the Dabie orogen belt, China, were measured to trace the changes of geochemical conditions during vertical transportation of earth materials, for example, oxygen fugacity. The bulk Fe³⁺/ΣFe ratios of retrograde eclogites, determined by Mössbauer spectroscopy, are consistently higher than those of fresh eclogites, suggesting oxidation during retrograde metamorphism and fluid infiltration. The studied eclogites (five samples) display limited mid‐ocean ridge basalts (MORB)‐like (~0.10‰) δ⁵⁶Fe values, which are indistinguishable from their protoliths, that is, gabbro cumulates formed through differentiation of mantle‐derived basaltic magma. This suggests that Fe isotope fractionation during continental subduction is limited. Garnet separates display limited δ⁵⁶Fe variation ranging from ?0.08 ± 0.07 ‰ to 0.02 ± 0.07‰, whereas coexisting omphacite displays a large variation of δ⁵⁶Fe values from 0.15 ± 0.07‰ to 0.47 ± 0.07‰. Omphacite also has highly variable Fe³⁺/ΣFe ratios from 0.367 ± 0.025 to 0.598 ± 0.024, indicating modification after peak metamorphism. Omphacite from retrograde eclogites has elevated Fe³⁺/ΣFe ratios (0.54–0.60) compared to that from fresh eclogites (~0.37), whereas garnet displays a narrow range of ferric iron content with Fe³⁺/ΣFe ratios from 0.039 ± 0.013 to 0.065 ± 0.022. The homogenous δ⁵⁶Fe values and Fe³⁺/ΣFe ratios of garnet suggest that it survived the retrograde metamorphism and preserved its Fe‐isotopic features and ferric contents of peak metamorphism. Because of similar diffusion rates of Fe and Mg in garnet and omphacite, and constant Δ²⁶Mg_{omphacite‐garnet} values (1.14 ± 0.04‰), equilibrium iron isotope fractionation between garnet and omphacite was probably achieved during peak metamorphism. Elevated Fe³⁺/ΣFe ratios of omphacite from retrograde eclogites and variant Δ⁵⁶Fe_{omphacite‐garnet} values of the studied eclogites (0.13 ± 0.10‰ to 0.48 ± 0.10‰) indicate that oxidized geofluid infiltration resulted in the elevation of δ⁵⁶Fe values of omphacite during retrograde metamorphism.     

Mechanical characteristics of dip basement effects on dump stability in the Shengli open pit mine in Inner Mongolia,China

For waste dump slopes that form basements, landslides can be prevented by determining a stability evolving law of dynamic development. Keeping this issue in mind, the relationship between the mechanical structure and stability of waste dumps with basements is studied. Three key factors that influence waste dump stability are presented, and judgment criteria for self-locking and unlocking states of dump basements are provided. From the friction coefficient of waste dump basement stability analyses of the Shengli open pit mine, the results indicate that waste dump basements on the right side of fault F8 and on the left side of fault F61 are subjected to self-locking. However, between faults F61 and F8, the basement is subjected to unlocking. Regarding the residual thrusting of unlocking areas, structure and stability optimization schemes for waste dumps in the Shengli open pit mine are provided through a mechanics analysis. Reducing the slopes and basement angles of waste dumps can enhance their stability by increasing basement roughness levels.     

Preparation of iron phosphate from sludge sourced from the electrocoagulation treatment of source-separated urine

In order to prepare iron phosphate by waste sludge, we report a method for effective utilization of the sludge obtained from the electrocoagulation treatment of source-separated urine. The sludge was dissolved with hydrochloric acid and pretreated with H₂O₂ and Na₃PO₄; finally, NaOH was added to precipitate iron phosphate from the solution. Thermal treatment of the precipitate at 750 °C in air yielded crystalline quartz-like anhydrous FePO₄. The precipitate was characterized by a number of thermal techniques such as thermogravimetry/differential thermal analysis, scanning electron microscopy, and X-ray powder diffraction.     

The kinetic studies of the cobalt ion removal from aqueous solutions by dolomite-based sorbent

The kinetics of Co(II) ions adsorption on thermally activated dolomite was studied with respect to the calcination temperature of natural dolomite. The sorption of Co(II) onto all samples is reasonably fast: The first 30–35 min accounts for approximately 70–80 % of Co(II) removal from feed solutions. In order to select the main rate-determining step in the overall uptake mechanism, a series of experiments were performed and data obtained were interpreted in terms of film diffusion control, intraparticle diffusion, pseudo-first-order and pseudo-second-order models. From the modeling of kinetic data, it can be concluded that adsorption of Co(II) ions from aqueous solution by heat-treated dolomite is a complex phenomenon and occurs in a mixed diffusion mode—the kinetic data are well described by the pseudo-second-order equation. The possible multistage sorption mechanism involving film diffusion and intraparticle diffusion control steps as well as chemical interaction between Co(II) ions and calcined dolomite is proposed.     

Slope stability evaluation using Back Propagation Neural Networks

The Yudonghe landslide, located in western Hubei Province of China, consists of eastern and western subunits as well as a main landslide mass with upper and lower slip surfaces. As an important landslide close to Shuibuya Dam on the Qing River, its stability is crucial, as the slide might reactivate because of a change in ground-water level caused by filling of the Shuibuya Reservoir. Existing weakness zones, growth of ruptures, the downslope attitude of geologic strata, and water infiltration, which reduced the strength of rocks and soils, have been found to be the most important factors contributing to the Yudonghe landslide. With regard to the landslide processes, it can be noted that the original large-scale slide activity was due to erosion by the Qing River, the second sliding resulted from the fall of blocks from the head scarp, and the final activity was the growth of the eastern and western secondary slides. A base failure was the main type of slope movement, however, it was obvious that more than one sliding event occurred, as inferred from striations and fractures detected by microstructure analysis of soils along the failure surfaces. Slope instability was evaluated by the method of Back Propagation Neural Networks (BPNN), in which a four-layer BPNN model with five input nodes, two hidden layers, and two output nodes was constructed using a training data set of landslide samples throughout the Qing River area. The predicted results of this analysis showed that the factor of safety was 1.10, which indicates that the Yudonghe landslide is currently in a marginally stable condition.     

Characteristics of Ore-controlling Structures and Ore Emplacement Mechanism in the Shihu Gold Deposit,Hebei Province - A Case Study of the No.101 VeinEI北大核心CSCD

The Shihu gold deposit lies in the middle-northern Taihang Mountains and is strictly controlled by faults. The ore-controlling structures in the mining district are not well-documented. Detailed field observation and laboratory investigation of the No.101 vein indicated that the ore-controlling structures of the Shihu gold deposit are the pre-Mesozoic shear joints with SN and NW strike that reactivated during the Yanshanian emerged from. The NNW-SSE left-strike-slip stresses during the main mineralization stage led to the dilation of the NW-strike structural segments along the roof and footwall of the early quartz diorite porphyrite veins, which contributed to the extensive wall-rock alteration, intensive gold mineralization and occur as quartz-vein type ores, and consequently the formation of rich ore pillars. On the contrary, the SN-strike compressive structures correspond to the weak wall-rock alteration and gold mineralization and occur as altered-rock type ores. All the rich ore pillars laterally distributed with high-angle (70°±), and wholly pitched southward with 40° angle. According to the structural ore-controlling regularities, the location between the No.47 and the No.61 exploratory line with elevation below 150 m is an excellent ore-prospecting area. Our prospecting proposal based on the ore-controlling structural analyses in the study area has been proven by the underground works in the Shihu gold deposit. © 2017, Science Press. All right reserved.     

Coexistence of garnet blueschist and eclogite in South Tianshan,NW China: dependence of P–T evolution and bulk‐rock composition

Coexisting garnet blueschist and eclogite from the Chinese South Tianshan high‐pressure (HP)–ultrahigh‐pressure (UHP) belt consist of similar mineral assemblages involving garnet, omphacite, glaucophane, epidote, phengite, rutile/sphene, quartz and hornblendic amphibole with or without paragonite. Eclogite assemblages generally contain omphacite >50 vol.% and a small amount of glaucophane (<5 vol.%), whereas blueschist assemblages have glaucophane over 30 vol.% with a small amount of omphacite which is even absent in the matrix. The coexisting blueschist and eclogite show dramatic differences in the bulk‐rock compositions with higher X(CaO) [=CaO/(CaO + MgO + FeO_total + MnO + Na₂O)] (0.33–0.48) and lower A/CNK [=Al₂O₃/(CaO + Na₂O + K₂O)] (0.35–0.56) in eclogite, but with lower X(CaO) (0.09–0.30) and higher A/CNK (0.65–1.28) in garnet blueschist. Garnet in both types of rocks has similar compositions and exhibits core–rim zoning with increasing grossular and pyrope contents. Petrographic observations and phase equilibria modelling with pseudosections calculated using thermocalc in the NCKMnFMASHO system for the coexisting garnet blueschist and eclogite samples suggest that the two rock types share similar P–T evolutional histories involving a decompression with heating from the P_max to the T_max stage and a post‐T_max decompression with slightly cooling stage, and similar P–T conditions at the T_max stage. The post‐T_max decompression is responsible for lawsonite decomposition, which results in epidote growth, glaucophane increase and omphacite decrease in the blueschist, or in an overprinting of the eclogitic assemblage by a blueschist assemblage. Calculated P–X(CaO), P–A/CNK and P–X(CO₂) pseudosections indicate that blueschist assemblages are favoured in rocks with lower X(CaO) (<0.28) and higher A/CNK (>0.75) or fluid composition with higher X(CO₂) (>0.15), but eclogite assemblages preferentially occur in rocks with higher X(CaO) and lower A/CNK or fluid composition with lower X(CO₂). Moreover, phase modelling suggests that the coexistence of blueschist and eclogite depends substantially on P–T conditions, which would commonly occur in medium temperatures of 500–590 °C under pressures of ~17–22 kbar. The modelling results are in good accordance with the measured bulk‐rock compositions and modelled temperature results of the coexisting garnet blueschist and eclogite from the South Tianshan HP–UHP belt.     

Determination of perchlorate and iodide concentrations in edible seaweeds

Perchlorate and iodide concentrations were determined in brown (Undaria pinnatifida and Laminaria japonica) and red (Porphyra sp.) edible seaweeds, which are commonly consumed by Korean people, with the use of ion chromatography, coupled with a tandem mass spectrometer. Seaweeds (i.e., good sources of iodine) are among the most important plant life in the ocean and commonly consumed as food and nutritional supplement in South Korea. All seaweed samples were purchased from different regions in South Korea. The detected concentrations of perchlorate were as follows: 19.7–620.7 μg kg^?1 dry weight (n = 11, mean concentration = 149.2 μg kg^?1 dry weight) for L. japonica and 7.3–21.7 μg kg^?1 dry weight (mean concentration = 10.6 μg kg^?1 dry weight) for U. pinnatifida. Of the 11 samples of Porphyra sp., only 1 sample showed 6.7 μg kg^?1 dry weight perchlorate. The concentrations of iodide in all seaweed samples varied from 0.44 to 6,800 mg kg^?1 dry weight. L. japonica samples (n = 11) had significantly higher iodide concentrations, with a mean of 5,261 mg kg^?1 dry weight. The bioconcentration factor values for perchlorate and iodide in the three different seaweeds varied widely and showed similar variation trends. The trend for perchlorate and iodide was Porphyra sp. < U. pinnatifida < L. japonica. The results have provided growing evidence that perchlorate frequently occurs in food products.     

Evaluation of adsorption potential of bamboo biochar for metal-complex dye: equilibrium,kinetics and artificial neural network modeling

Metal-complex dyes are widely used in textile industry, but harmful to the environment and human health due to aromatic structure and heavy metal ions. The objective of this work was to evaluate the adsorption potential of bamboo biochar for the removal of metal-complex dye acid black 172 from solutions. Freundlich model was more suitable for the adsorption process of bamboo biochar than Langmuir isotherm, indicating multilayer adsorption of acid black 172 on a heterogeneous bamboo biochar surface. Adsorption kinetics analysis of pseudo-second-order and Weber–Morris models revealed that intraparticle transport was not the only rate-limiting step. The bamboo biochar exhibited a good adsorption performance even at high ionic strength. Analysis based on the artificial neural network indicated that the temperature with a relative importance of 29 % appeared to be the most influential parameter in the adsorption process for dye removal, followed by time, ionic strength, pH and dye concentration.