Mössbauer studies of iron silicate spinel at high pressure

We have measured in situ Mössbauer transmission spectra of iron silicate spinel (γ-Fe₂SiO₄) in a diamond anvil cell at room temperature and pressures up to 16 GPa. The observed spectra show a doublet characteristic of the paramagnetic state. The isomer shift and quadrupole splitting at atmospheric pressure are 1.10 and 2.63 mm/s, respectively, which are smaller than those of fayalite (α-Fe₂SiO₄). Both the isomer shift and quadrupole splitting decrease linearly with pressure with slope of ?0.003(1) and ?0.020(1) mm/sec · GPa, respectively. This simple linear trend suggests that no electronic or polymorphic transitions occur under 16 GPa except for those due to the small and continuous changes of volume and local symmetry under pressure. On the basis of a crystalline field calculation, the negative pressure derivative of the quadrupole splitting is associated with a trend towards an ideal cubic symmetry of the oxygen sublattice.     

国际古植物学1989年研究进展

古植物学是一个日新月异发展着的学科。每年,都有一些新的方法问世,它们结合地质学和生物学方法来研究地史时期植物的生活。其研究广度可以从1989年7月在美国首都华盛顿召开的第28届国际地质大会上明显看出。古植物学家们报告了他们关于“古气候”、“前寒武纪/寒武纪的过渡”、“泥炭和煤的来源”、“适应辐射”、“埋藏过程”、“特异埋藏”及南极地质等方面的研究成果;关于晚石炭世植物群的生物地理方面的文章也很多。 由Gastaldo(1989)编辑的《植物埋藏学——有机沉积过程》论文专辑是将更多的地质     

Contribution à la surveillance de l'activité de l'Etna à partir de l'étude des zones fumerolliennes

Resume La convection de la vapeur d'eau formée en profondeur dans une zone fumerollienne crée en surface une anomalie hydrique, thermique et électrique, cette dernière pouvant être la plus sensible à une variation de l'activité thermique profonde. L'amplitude des anomalies dépend de la position du site par rapport à la configuration de l'activité magmatique, mais aussi des conditions hydrogéologiques locales. La surveillance spatiale et temporelle des éruptions à partir du phénomène convectif hydrique doit tenir compte de ces conditions.

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The water steam convection existing below a fumarolic area creates hydraulic, thermal and electric anomalies, the electric anomaly being probably the most correlated to a change of the deep thermal activity. The anomaly range depends on the position of the site connected with the configuration of the magmatic activity, but also on the local hydrogeologic conditions. The spatial and temporal surveillance of the eruptions based on these convective data should take into consideration these conditions.

     

Seasonal abundance of brachyuran crab larvae in a tropical estuary: Gulf of Nicoya,Costa Rica,Central America

Brachyuran crab larvae were sampled approximately monthly at four stations in the Gulf of Nicoya, a tropical estuary on the Pacific coast of Costa Rica, Central America. The gulf was divided into two regions based on physical and chemical characteristics. Larvae were identified to five families: Ocypodidae, Pinnotheridae, Portunidae, Majidae, Xanthidae. The abundance and distribution of these taxa were similar to that found in temperature estuaries of North America. Ocypodids, pinnixids, and xanthids were most common in the estuarine upper-gulf region while portunids were more common in the lower gulf. Majids were found in small numbers in the lower gulf. Only the ocypodids showed a consistent pattern in vertical distribution; larvae of this taxon were always more common in surface water. There was no consistent pattern in the seasonal abundance of the various taxa when compared among stations.     

Normalized 87Sr86Sr by multiple collection and comparison to a standard

A system for precisely determining normalized ${}^{87}\text{Sr}{}^{86}\text{Sr}$ by comparing unknown to standard in a solid-source quadruple-collector mass spectrometer is outlined. This is made possible by a mathematical approximation in the data-reduction process.     

Zircon saturation revisited: temperature and composition effects in a variety of crustal magma types

Hydrothermal experiments in the temperature range 750–1020°C have defined the saturation behavior of zircon in crustal anatectic melts as a function of both temperature and composition. The results provide a model of zircon solubility given by: In D_Zr^zircon/melt= ?3.80?[0.85(M?1)]+12900/T where D_Zr^zircon/melt is the concentration ratio of Zr in the stoichiometric zircon to that in the melt, T is the absolute temperature, and M is the cation ratio (Na + K + 2Ca)/(Al · Si). This solubility model is based principally upon experiments at 860°, 930°, and 1020°C, but has also been confirmed at temperatures up to 1500°C for M = 1.3. The lowest temperature experiments (750° and 800°C) yielded relatively imprecise, low solubilities, but the measured values (with assigned errors) are nevertheless in agreement with the predictions of the model.For M = 1.3 (a normal peraluminous granite), these results predict zircon solubilities ranging from ～ 100 ppm dissolved Zr at 750°C to 1330 ppm at 1020°C. Thus, in view of the substantial range of bulk Zr concentrations observed in crustal granitoids (～ 50–350 ppm), it is clear that anatectic magmas can show contrasting behavior toward zircon in the source rock. Those melts containing insufficient Zr for saturation in zircon during melting can have achieved that condition only by consuming all zircon in the source. On the other hand, melts with higher Zr contents (appropriate to saturation in zircon) must be regarded as incapable of dissolving additional zircon, whether it be located in the residual rocks or as crystals entrained in the departing melt fraction. This latter possibility is particularly interesting, inasmuch as the inability of a melt to consume zircon means that critical geochemical “indicators” contained in the undissolved zircon (e.g. heavy rare earths, Hf, U, Th, and radiogenic Pb) can equilibrate with the contacting melt only by solid-state diffusion, which may be slow relative to the time scale of the melting event.