Adsorption of copper, nickel and lead ions from synthetic semiconductor industrial wastewater by palm shell activated carbon

Granular activated carbon produced from palm kernel shell was used as adsorbent to remove copper, nickel and lead ions from a synthesized industrial wastewater.Laboratory experimental investigation was carried out to identify the effect of pH and contact time on adsorption of lead, copper and nickel from the mixed metals solution. Equilibrium adsorption experiments at ambient room temperature were carried out and fitted to Langmuir and Freundlich models. Results showed that pH 5 was the most suitable, while the maximum adsorbent capacity was at a dosage of 1 g/L, recording a sorption capacity of 1.337 mg/g for lead, 1.581 mg/g for copper and 0.130 mg/g for nickel. The percentage metal removal approached equilibrium within 30 min for lead, 75 min for copper and nickel, with lead recording 100 %, copper 97 % and nickel 55 % removal, having a trend of Pb²⁺ > Cu²⁺ > Ni²⁺. Langmuir model had higher R² values of 0.977, 0.817 and 0.978 for copper, nickel and lead respectively, which fitted the equilibrium adsorption process more than Freundlich model for the three metals.     

Synoptic circulation and stream discharge in the Great Lakes basin, USA

Impacts on water resources caused by human activity, natural climate variation and long-term climate change are unclear in the US Great Lakes region. Improved understanding of the impact of atmospheric circulation on stream discharge variability into the Lakes is thus important. In this analysis, monthly surface and mid-tropospheric circulation patterns suggest that surface pressure variations over Missouri and Illinois are most strongly correlated to discharge. The mid-tropospheric patterns most directly related to discharge place the Great Lakes in a trough-to-ridge flow pattern. The analysis confirms that at this scale, lee shore advection resulting in ‘lake-effect’ precipitation is not very important to regional discharge, and neither are variations in the Pacific–North American teleconnection.     

Variations of the aerosol concentration and chemical composition over the arid steppe zone of Southern Russia in summer

Variations in the surface aerosol over the arid steppe zone of Southern Russia have been measured. The parameters of atmospheric aerosol (mass concentration, both dispersed and elemental compositions) and meteorological parameters were measured in Tsimlaynsk raion (Rostov oblast). The chemical composition of aerosol particles in the atmospheric surface layer has been determined, and the coefficients of enrichment of elements with respect to clarkes in the Earth’s crust have been calculated. It is shown that, in summer, arid aerosols are transported from both alkaline and sandy soils of Kalmykia to the air basin over the observation zone. Aerosol particles in the surface air layer over this region have been found to contain the products of combustion of oil, coal, and ethylized fuel. These combustion products make a small contribution to the total mass concentration of atmospheric aerosol; however, they are most hazardous to the health of people because of their sizes and heavy-metal contents. A high concentration of submicron sulfur-containing aerosol particles of chemocondensation nature has been recorded. Sources of aerosol of both natural and anthropogenic origins in southern Russia are discussed.     

Circulation and currents in the southwestern East/Japan Sea: Overview and review

A review is made of circulation and currents in the southwestern East/Japan Sea (the Ulleung Basin), and the Korea/Tsushima Strait which is a unique conduit for surface inflow into the Ulleung Basin. The review particularly concentrates on describing some preliminary results from recent extensive measurements made after 1996. Mean flow patterns are different in the upstream and downstream regions of the Korea/Tsushima Strait. A high velocity core occurs in the mid-section in the upstream region, and splits into two cores hugging the coasts of Korea and Japan, the downstream region, after passing around Tsushima Island located in the middle of the strait. Four-year mean transport into the East/Japan Sea through the Korea/Tsushima Strait based on submarine cable data calibrated by direct observations is 2.4 Sv (1 Sv = 10⁶ m³ s⁻¹). A wide range of variability occurs for the subtidal transport variation from subinertial (2–10 days) to interannual scales. While the subinertial variability is shown to arise from the atmospheric pressure disturbances, the longer period variation has been poorly understood.Mean upper circulation of the Ulleung Basin is characterized by the northward flowing East Korean Warm Current along the east coast of Korea and its meander eastward after the separation from the coast, the Offshore Branch along the coast of Japan, and the anticyclonic Ulleung Warm Eddy that forms from a meander of the East Korean Warm Current. Continuous acoustic travel-time measurements between June 1999 and June 2001 suggest five quasi-stable upper circulation patterns that persist for about 3–5 months with transitions between successive patterns occurring in a few months or days. Disappearance of the East Korean Warm Current is triggered by merging the Dok Cold Eddy, originating from the pinching-off of the meander trough, with the coastal cold water carried Southward by the North Korean Cold Current. The Ulleung Warm Eddy persisted for about 20 months in the middle of the Ulleung Basin with changes in its position and spatial scale associated with strengthening and weakening of the transport through the Korea/Tsushima Strait. The variability of upper circulation is partly related to the transport variation through the Korea/Tsushima Strait. Movements of the coastal cold water and the instability of the polar front also appear to be important factors affecting the variability.Deep circulation in the Ulleung Basin is primarily cyclonic and commonly consists of one or more cyclonic cells, and an anticyclonic cell centered near Ulleung Island. The cyclonic circulation is conjectured to be driven by a net inflow through the Ulleung Interplain Gap, which serves as a conduit for the exchange of deep waters between the Japan Basin in the northern East Sea and the Ulleung Basin. Deep currents are characterized by a short correlation scale and the predominance of mesoscale variability with periods of 20–40 days. Seasonality of deep currents is indistinct, and the coupling of upper and deep circulation has not been clarified yet.     

A Measure of Magnetic Field Discontinuity

In this paper we introduce a measure of magnetic field discontinuity, MAD, defined as Maximum Angular Difference between two adjacent magnetic field vectors. To examine the characteristics of the MAD, we have considered several active region models having a quadrupolar field configuration and computed MADs over these active regions by approximating the 3-D magnetic fields as an ensemble of charge potential fields or linear force-free fields. The computed MAD fields are studied in comparison with other flare activity indicators such as separators. It is found that (1) the region of high level MAD corresponds well with the separator, or practically the intersection of the separator with the plane of measurement, (2) it singles out local discontinuities of magnetic fields, and (3) the MAD can also be a measure of the evolutionary status of an active region.An observational test has been made for 2-D MADs, using the Yohkoh SXT observation of a flare in AR 6919 and the vector magnetogram taken at the Mees Solar Observatory during this flare activity. The high level contours of 2-D MAD are found to trace well the observed soft X-ray bright points, which indicates that the MAD could serve as a good flare activity indicator.     

Estimating the Probable Maximum Precipitation by Physical Methods Using Satellite and Radiolocation Observation Data: Case Study of the Middle Urals

Water Resources - The study considers the methods for evaluating the maximal possible daily storm rainfall (MPR) in the Middle Ural based on a combination of ground, aerological, satellite, and...     

Carbonaceous chondrites as analogs for the composition and alteration of Ceres

The mineralogy and geochemistry of Ceres, as constrained by Dawn's instruments, are broadly consistent with a carbonaceous chondrite (CM/CI) bulk composition. Differences explainable by Ceres’s more advanced alteration include the formation of Mg‐rich serpentine and ammoniated clay; a greater proportion of carbonate and lesser organic matter; amounts of magnetite, sulfide, and carbon that could act as spectral darkening agents; and partial fractionation of water ice and silicates in the interior and regolith. Ceres is not spectrally unique, but is similar to a few other C‐class asteroids, which may also have suffered extensive alteration. All these bodies are among the largest carbonaceous chondrite asteroids, and they orbit in the same part of the Main Belt. Thus, the degree of alteration is apparently related to the size of the body. Although the ammonia now incorporated into clay likely condensed in the outer nebula, we cannot presently determine whether Ceres itself formed in the outer solar system and migrated inward or was assembled within the Main Belt, along with other carbonaceous chondrite bodies.     

Problems with biogenic silica measurement in marginal seas

Surface sediment samples from the Bohai, Yellow Sea, and the Pacific were used to assess biogenic silica (BSi) content and to study uncertainties in BSi measurements. The contents of BSi in the Bohai and Yellow Sea are all less than 1%. The dissolution of BSi in sediments from the Bohai and Yellow Sea is very important to maintain high levels of silicate in the water column. The non-biogenic silica from clay minerals has an obvious effect on BSi of sediment samples in the Bohai and Yellow Sea with low BSi and high clay minerals. The solid to solution ratio was found to have a great influence on BSi measurement, which can induce uncertainties up to 75%. The effect of loss by sorption and centrifugation is negligible. Interlaboratory comparison of techniques for BSi measurement by the wet alkaline extraction technique of Mortlock and Froelich [Deep-Sea Res. 36 (1989) 1415-1426] with clay correction was suggested to give no significant differences. However, differences in sediment compositions and reagent to sample ratio may limit the application of the wet alkaline extraction method.     

A new approach to rapid,desktop-level,environmental flow assessments for rivers in South Africa

Abstract

An approach is presented for desktop-level environmental flow requirement (EFR) determination that is aligned with the Habitat Flow–Stressor Response (HFSR) method which evolved in South Africa over recent years. The HFSR method integrates hydrological, hydraulic and ecological habitat data, involves ecological and hydraulic specialists and is data-intensive and time-consuming. The revised desktop method integrates hydrological information with estimates of channel hydraulic cross-sectional characteristics to generate habitat-type frequencies under changing flow conditions. This information is used with the expected natural habitat requirements to determine acceptable habitat availability under different levels of ecological protection, which is then used with the hydraulic data to define flow regime characteristics that meet the ecological objectives. The paper describes the model components, discusses the assumptions, data requirements and limitations and presents some example results. The revised desktop approach uses approaches that are aligned with the more complex methods and generates results that are similar.

Editor D. Koutsoyiannis; Guest editor M. Acreman

Citation Hughes, D.A., Desai, A.Y., Birkhead, A.L., and Louw, D., 2014. A new approach to rapid, desktop-level, environmental flow assessments for rivers in South Africa. Hydrological Sciences Journal, 59 (3–4), 673–687.     

普洱市宜居气候适宜性分析

气候舒适的程度及持续时间的长短,是影响旅游发展和人类居住环境适应性的重要因素。基于1981 2010年普洱市10个县区气象站的日平均气温、相对湿度及风速等常规气象观测资料,对季节划分、气温极值和平均气温空间分布进行了分析,计算舒适度指数(包括温湿指数、风寒指数、人体舒适度指数),研究了普洱市的宜居气候舒适性。结果表明:普洱市夏季90%的区域平均气温为20~24℃,仅有东部和中部少数河谷地带超过24℃;冬季90%的区域平均气温均在10℃以上。冬半年全市最低气温低于0℃的年平均日数不足1天,夏半年全市最高气温高于35.0℃的年平均日数不足4天。因此普洱市"冬无严寒、夏无酷暑",全年有6~9个月的春秋宜人气候,是典型的全年"人体感觉舒适"的宜居气候区,尤以夏半年最为舒适。近10年普洱市快速增长的旅游总人数和完成的GDP进一步说明普洱市的宜居和旅游的气候适宜性。