Radon variations in a Hungarian village

 A steady radon exhalation is assumed in most publications. In a village of North-East Hungary, however, high radon concentrations have been measured, differing strongly in neighbouring houses and varying in time, due to the interplay of geochemical phenomena. Received: 20 November 1995 · Accepted: 18 June 1996     

Measurement of stress effects (scope for growth) and contaminant levels in mussels (Mytilus edulis) collected from the Irish Sea

The objective of this research was to quantify the impact of pollution along the coastlines of the Irish Sea. Pollution assessment was based on the combined measurement of scope for growth (SFG), and chemical contaminants in the tissues of mussels (Mytilus edulis) collected from 38 coastal sites around the Irish Sea during June-July in 1996 and 1997. On the UK mainland coast, the SFG showed a general trend with a significant decline in water quality in the Liverpool and Morecambe Bay region. High water quality was recorded along the west coast of Wales, as well as southwest England and northwest Scotland (clean reference sites outside the Irish Sea). Along the coast of Ireland there was a similar trend with reduced SFG within the Irish Sea region. SFG was generally low north of Duncannon and then improved north of Belfast. The poor water quality on both sides of the Irish Sea is consistent with the prevailing hydrodynamics and the spatial distribution of contaminants associated with urban/ industrial development. The decline in SFG of mussels on both sides of the Irish Sea was associated with a general increase in contaminant levels in the mussels. Certain contaminants, including PAHs, TBT, sigmaDDT, Dieldrin, gamma-HCH, PCBs, and a few of the metals (Cd, Se, Ag, Pb), showed elevated concentrations. Many of these contaminants were particularly elevated in the coastal margins of Liverpool Bay, Morecambe Bay and Dublin Bay. A quantitative toxicological interpretation (QTI) of the combined tissue residue chemistry and SFG measurements indicated that at the majority of coastal sites, c. 50 to > 80% of the observed decline in SFG was due to PAHs as a result of fossil fuel combustion and oil spills. TBT levels were highest at major ports and harbours, but these concentrations only made a minor contribution to the overall reduction in SFG. At no sites were individual metals accumulated to concentrations that could cause a significant effect on SFG. The study identified many sites where the observed reduction in SFG was far greater than predicted from the limited number of chemical contaminants analysed, thus indicating the presence of additional 'unknown toxicants'. Sewage (containing domestic, agricultural and industrial components) appears to be an important contributor to reduced SFG and linear alkylbenzenes (LABs) and As may provide suitable 'sewage markers'. There was a highly significant positive correlation between SFG and As (P < 0.001). This relationship may be due to reduced As uptake by algal food material and mussels at sites with elevated P04 concentrations (e.g. at sites with sewage inputs). Phosphate is a known competitive inhibitor of As accumulation, at least in algae. The results highlight that further research is required on 'sewage markers' in mussels. The SFG approach therefore provides a rapid, cost-effective and quantitative measure of pollution impact, as well as a means of identifying the causes through a QTI of tissue contaminants levels. It also serves to identify the presence of unidentified toxicants and areas that require further study.     

Contamination of organotin compounds and imposex in molluscs from Vancouver,Canada

Gastropods and bivalves were collected at 15 sites at Vancouver and Victoria, Canada between 24 May and 7 June, 1999, to establish tissue concentrations of butyltin and phenyltin compounds, to record imposex symptoms in gastropods, and to assess the present status of organotin contamination around Vancouver. No neogastropods (such as Nucella lima) were found around Vancouver. Neogastropod populations could have been extirpated by severe TBT contamination in Vancouver, as relatively high concentrations of TBT were detected in tissues of Mytilus trossulus from Vancouver, and the neogastropods distributed in Vancouver might be sensitive to TBT. Recovery from imposex, however, was observed in neogastropod populations from three sites at Victoria and Mission Point. TBT contamination has continued around Vancouver, arising from continuous use of TBT in antifouling paints for vessels larger than 25 m in length; however, TBT has decreased around Victoria and Mission Point. Different patterns of TBT accumulation in tissue were observed among the bivalve species from Vancouver. The highest TBT concentration detected in Tresus capax suggested some possible adverse effects. TBT was the most predominant butyltin component in almost all bivalve specimens surveyed, suggesting a low rate of TBT metabolism. Phenyltin compounds were not detected in any molluscan specimens in this study.     

Sedimentology of a subtidal,tide-dominated sand body in the Yellow Sea,southwest Korea

Odanam Satoe, a subtidal, tide-dominated sand body in the Yellow Sea, Korea, is linear in plan and asymmetrical in cross-section. It consists of fine- to medium-grained, well-sorted subangular sand. Bedforms consist of high-amplitude (1–2 m) sandwaves on the lower flanks of the gentler-sloping bar surface, and medium-amplitude (0.5-1 m) sandwaves on the sand body trough adjoining the steeper face, the bar crest and shallower parts of the gently sloping bar surface. Bedforms are absent on the relatively steeper bar surface, which is characterized by 2° slopes. Bedform orientation on the gentler slope is oblique by 30° to the bar crest, parallel to the sand-body crest on the crest itself, and opposite to the steeper sand-body face in the trough below the steeper slope of the bar.Bottom current velocity data show that tidal currents are semi-rotary with a flood time—velocity asymmetry over the gentler slope, and ebb time—velocity asymmetry over the steeper slope during most of the tidal cycle. Tidal-current flow parallels bar elongation over the steeper slope, whereas over the gentler slope, tidal-current flow is directed at 30° to the bar crest and changes to normal to the crest one hour prior to low tide. Bedform orientation mapped with side-scan sonar shows agreement with these flow directions.Sand dispersal around the sand body is controlled by time—velocity asymmetry and partial rotary flow directions of tidal currents. This circulation causes not only a trapezoidal mode of grain dispersal, but also westerly migration of the sand body documented from comparative bathymetric surveys in 1964 and 1980.     

Algorithm for non-hydrostatic dynamics in the Regional Oceanic Modeling System

A non-hydrostatic algorithm for the Regional Oceanic Modeling System (ROMS) is proposed. It is based on a decomposition technique for hydrostatic and non-hydrostatic pressure. The algorithm has a pressure-correction scheme with split-explicit time-stepping for baroclinic and barotropic vertical modes with a free surface. The algorithm implementation requires solving a Poisson equation for a non-hydrostatic pressure that has a non-symmetric matrix in discrete form. The efficiency of a different class of solvers and preconditioners were tested. The algorithm is successfully implemented with several examples where non-hydrostatic effects are important. These include standing external gravity waves; strongly nonlinear internal wave generation and transformation; stratified shear instability and its associated mixing; and nonlinear internal tidal generation over a ridge. The corresponding changes in the pre-processing and post-processing infrastructure in the existing hydrostatic ROMS code were performed to implement parallel elliptic solvers and a new set of dynamical equations.     

碘－钒盐催化下合成的四溴邻苯二甲酸酐

报道一种新的有效催化剂－碘－钒盐和在一定条件下合成四溴邻苯二甲酸酐的方法。探讨催化剂的组成配比、用量、温度及废酸循环使用等因素对合成方法的影响。该催化剂的催化效果和常用的碘、碘－铁催化剂相同，适用于四溴邻苯二甲酸酐的合成。