Concentration,composition and sources of PAHs in the coastal sediments of the exclusive economic zone (EEZ) of Qatar,Arabian Gulf

Surface sediments were collected from sixteen locations in order to assess levels and sources of polycyclic aromatic hydrocarbons (PAHs) in sediments of Qatar exclusive economic zone (EEZ). Samples were analyzed for 16 parent PAHs, 18 alkyl homologs and for dibenzothiophenes. Total PAHs concentration (∑PAHs) ranged from 2.6 ng g⁻¹ to 1025 ng g⁻¹. The highest PAHs concentrations were in sediments in and adjacent to harbors. Alkylated PAHs predominated most of the sampling locations reaching up to 80% in offshore locations. Parent PAHs and parent high molecular weight PAHs dominated location adjacent to industrial activities and urban areas. The origin of PAHs sources to the sediments was elucidated using ternary plot, indices, and molecular ratios of specific compounds such as (Ant/Phe + Ant), (Flt/Flt + Pyr). PAHs inputs to most coastal sites consisted of mixture of petroleum and combustion derived sources. However, inputs to the offshore sediments were mainly of petroleum origin.     

2004年2月11日Cluster卫星和CUTLASS雷达同时观测的磁通量传输事件

本文分析了2004年2月11日11:00～11:40 UT期间Cluster卫星簇的磁通门磁力计FGM）、等离子体电子及电流试验仪（PEACE）和CUTLASS 芬兰雷达对多个磁通量传输事件(FTEs)的同时观测. 在此期间,Cluster卫星簇位于北半球外极隙区附近,并于11:18 UT左右穿出磁层顶进入磁鞘,四颗卫星同时观测到了多个FTEs, 其出现具有准周期性,周期约为130 s. 利用Cluster四颗卫星的多点同时观测数据,采用最小方向微分法和时空微分方法,我们推断这些FTEs是尺度大小约为(0.87～1.81)RE的准二维结构,其运动方向为东北方向,与Cooling模型预测方向基本一致. CUTLASS芬兰雷达在相应的电离层区域观测到了明显的“极向运动雷达极光”结构,这些结构与Cluster卫星簇观测的FTEs有着很好的对应关系,它们是FTEs的雷达观测特征.     

Atmosphere–ionosphere vertical electric coupling above thunderstorms of different intensity

The most important features of the quasi-electrostatic fields (QSFs) and currents, generated in the region between a thunderstorm (TS) and the ionosphere between lightning discharges, are theoretically investigated. They depend on different factors having large variability, related to the TS and to the atmospheric conductivity. These features are studied in order to understand better the conditions when QSFs cause modifications of the parameters and chemical balance in the lower ionosphere over TSs due to electron heating, as well as the generation of red sprites. For this purpose, an analytical model based on Maxwell's equations under conditions of curl-free electric fields is presented. The temporal and spatial behaviour of the QSFs is studied as a function of the parameters of lightning discharges and of atmospheric conductivity. The dependence of the QSF, mainly its peak values, on the charge moment change, the discharge time, and the horizontal extent of the discharged region, on the one hand, and of the conductivity profile, on the other, is studied. It is shown that the profile of the QSF time peak changes its scale height at the altitudes where the relaxation time becomes equal to the discharge time, and where the conductivity scale height is diminished; below these altitudes the peak QSFs decrease with time much slower than above them. Also, the QSF peak increases almost linearly with the charge height and depends little on the size of the discharged region. The total Maxwell and conduction currents, which flow from the TS to the ionosphere, are also studied. The peak current is proportional to the charge moment change, and actually does not depend on the frequency of lightning discharges.     

Seasonal oscillations in mesospheric temperatures at low-latitudes

Using 3 years of high-quality temperature measurements (2002–2004) recorded from Maui, HI (20.8°N), we have investigated the characteristics of mesospheric seasonal oscillations at low-latitudes. Measurements of the near-infrared OH (6,2) and O₂ (0,1) nightglow emission layers (centered at 87 and 94 km) independently reveal a distinct semi-annual oscillation (SAO) and annual oscillation (AO) with amplitudes of 3.8 and 2.0 K, respectively. An observed asymmetry in the seasonal variation of the nocturnal mean, previously reported by Taylor et al. [2005. Characterization of the semi-annual-oscillation in mesospheric temperatures at low-latitudes. Advances in Space Research 35, doi:10.1016/j.asr.2005.05.111] from this site is shown to be due to a superposed AO of amplitude 50% of the SAO signature. Detailed investigations of the local-time variation of the SAO amplitude and phase combined with TIME-GCM simulations of the seasonal variation of the diurnal tide strongly suggest a large local-time dependence of the amplitude (but not phase) of the observed SAO. These data indicate that the true mean temperature SAO amplitude could be as high as 7 K at this latitude.     

Spatio-temporal changes of marine macrobenthic community in sub-tropical waters upon recovery from eutrophication. I. Sediment quality and community structure

A two-year study was conducted in the vicinity of a harbour in sub-tropical Hong Kong, to examine the progress of improvement in sediment quality and recovery of macrobenthic community upon cessation of organic pollution caused by sewage discharge. Median sediment particle diameter (Mdphi) and levels of total organic carbon (TOC), total Kjeldahl nitrogen (TKN), ammonia-nitrogen (NH(3)-N) and total phosphorus (TP), as well as macrobenthic species composition and abundance were determined bi-monthly at three inside-harbour and two outside-harbour locations. At the two inside-harbour locations, significantly higher levels of TOC, TKN, NH(3)-N and TP in sediments were observed than the outside-harbour locations. However, no significant temporal change of nutrient levels was detected at all sampling locations during the two-year study, except a significant decrease in TKN and NH(3)-N levels at one outside-harbour location and a decline in NH(3)-N content at another outside-harbour location. Spatially, the highest in mean total species number, individual number, species diversity H' and lowest evenness J was found at one outside-harbour location, whereas the other four locations had relatively similar values. H' was negatively correlated with TOC, TKN, NH(3)-N and TP content in sediments while J was positively correlated with MDphi. Across the study period, the patterns of macrobenthic community were significantly different among all samplings and that the spatial difference of benthic community was best correlated with MDphi, TOC, TKN and water depth. A weak sign of recovery in macrobenthic community structure was detected at inside-harbour locations, with replacement of opportunistic by ubiquitous species over the two-year study. The slow recovery of macrobenthic community was related to sediment characteristics. Results of a larval settlement bioassay using the polychaete Capitella sp. I also demonstrated that the inside-harbour sediments were still unfavourable for colonization and larval settlement of species sensitive to pollution. The slow biodegradation of the organic pollutants and continuous presence of heavy metals in the sediment may hinder settlement and colonization of benthic animals. However, increases of H' and J were observed in a longer time scale when comparing the present data with those obtained four years ago. This suggested that a detectable recovery of benthic community in the harbour may take at least three years and a complete recovery may even take longer duration.     

东昆仑活动断裂带西大滩段断层气(Rn,CO2)的释放特征

通过在东昆仑活动断裂带西大滩段进行断层气测试,首次获取了该断裂带中Rn和CO2的释放量。在2004年开挖的2～3m深的探槽内,氡浓度可达20732Bq.m-3,氡发射率可达433mBq.m-2.s-1,远高于在地表的氡浓度505～2380Bq.m-3与氡发射率7～28.19mBq.m-2.s-1(地表氡发射率均值为14.7mBq.m-2.s-1,与世界平均值相当)。从而我们推断该断裂具有从上部第四系覆盖物到深部花岗岩之间的良好连通性。在地表CO2的析出率平均值为18.9g.m-2.d-1,与通常的背景值相当,在探槽中和距离断层1km的地方没有明显的空间变化,但是在断层北侧3km处的一个近乎直立的千枚岩小山上,CO2的析出率却很高,为421g.m-2.d-1,同时该处氡的发射率也高,达503mBq.m-2.s-1,因此,有必要在该断裂附近进行长期监测     

An Experiment Using the High Resolution Eta and WRF Models to Forecast Heavy Precipitation over India

In the present study using the Weather Research and Forecasting (WRF) and Eta models, recent heavy rainfall events that occurred (i) over parts of Maharastra during 26 to 27 July, 2005, (ii) over coastal Tamilnadu and south coastal Andhra Pradesh during 24 to 28 October, 2005, and (iii) the tropical cyclone of 30 September to 3 October, 2004/Monsoon Depression of 2 to 5 October 2004, that developed during the withdrawal phase of the southwest monsoon season of 2004 have been investigated. Also sensitivity experiments have been conducted with the WRF model to test the impact of microphysical and cumulus parameterization schemes in capturing the extreme weather events. The results show that the WRF model with the microphysical process and cumulus parameterization schemes of Ferrier et al. and Betts-Miller-Janjic was able to capture the heavy rainfall events better than the other schemes. It is also observed that the WRF model was able to predict mesoscale rainfall more realistically in comparison to the Eta model of the same resolution.     

SPECIFIC DEGRADATION OF WATERSHEDS

An extensive database of reservoir sedimentation surveys throughout continental United States is compiled and analyzed to determine specific degradation SD relationships as function of mean annual rainfall R, drainage area A, and watershed slope S. The database contains 1463 field measurements and specific degradation relationships are defined as function of A, R and S. Weak trends and significant variability in the data are noticeable. Specific degradation measurements are log normally distributed with respect to R, A, and S and 95% confidence intervals are determined accordingly. The accuracy of the predictions does not significantly increase as more independent variables are added to the regression analyses.