基于土壤-小麦系统的河南黄淮平原As生态安全评价

在研究河南省黄淮平原经济区土壤As对小麦籽实As含量影响的基础上,分析了土壤及籽实As的数据特征,并利用单项污染指数法,对研究区小麦籽实As的安全状况进行了评价,发现研究区小麦籽实中As的含量远远低于不安全标准。还进一步研究了土壤As全量与小麦籽实As含量之间的响应关系,同时根据提供的资料,对小麦籽实的As含量与土壤中As的某些形态的含量建立多元线性回归模型,从而通过食品质量标准推算出土壤中As的安全临界浓度。     

Differences in flood hazard projections in Europe – their causes and consequences for decision making

This paper interprets differences in flood hazard projections over Europe and identifies likely sources of discrepancy. Further, it discusses potential implications of these differences for flood risk reduction and adaptation to climate change. The discrepancy in flood hazard projections raises caution, especially among decision makers in charge of water resources management, flood risk reduction, and climate change adaptation at regional to local scales. Because it is naïve to expect availability of trustworthy quantitative projections of future flood hazard, in order to reduce flood risk one should focus attention on mapping of current and future risks and vulnerability hotspots and improve the situation there. Although an intercomparison of flood hazard projections is done in this paper and differences are identified and interpreted, it does not seems possible to recommend which large-scale studies may be considered most credible in particular areas of Europe.

EDITOR D. Koutsoyiannis

ASSOCIATE EDITOR not assigned     

Groundwater targeting in a hard-rock terrain using fracture-pattern modeling, Niva River basin, Andhra Pradesh, India

In hard-rock terrain, due to the lack of primary porosity in the bedrock, joints, fault zones, and weathered zones are the sources for groundwater occurrence and movement. To study the groundwater potential in the hard-rock terrain and drought-prone area in the Niva River basin, southern Andhra Pradesh state, India, Landsat 5 photographic data were used to prepare an integrated hydrogeomorphology map. Larsson's integrated deformation model was applied to identify the various fracture systems, to pinpoint those younger tensile fracture sets that are the main groundwater reservoirs, and to understand the importance of fracture density in groundwater prospecting. N35°–55°E fractures were identified as tensile and N35°–55°W fractures as both tensile and shear in the study area. Apparently, these fractures are the youngest open fractures. Wherever N35°–55°E and N35°–55°W fracture densities are high, weathered-zone thickness is greater, water-table fluctuations are small, and well yields are high. Groundwater-potential zones were delineated and classified as very good, good to very good, moderate to good, and poor. Electronic Publication     

Lateral migration,thermoluminescence chronology and colour variation of longitudinal dunes near Birdsville in the Simpson Desert,central Australia

The longitudinal dunes of the Simpson Desert, in the vicinity of Birdsville, have been reworked largely during the Holocene from dunes deposited up to 80000 years ago or earlier. The widespread asymmetry of these roughly northward-trending dunes, with steeper eastern faces and more gentle western faces, supports wind-rose data showing sand-transporting winds from the southwest obliquely intersecting the dunes. While this suggests a change in the wind pattern since the dune field was oriented, it does not indicate that the dunes are necessarily shifting leeward (eastward) as a consequence. It is hypothesized that the direction of migration is controlled by the extent to which the dunes are vegetated. Relatively well-vegetated dunes can accrete sand on their gentle stoss slopes and erode on their lee slopes causing them to shift westward and hence obliquely into the wind, a condition that probably prevails in wetter regions and during episodes of relatively humid climate. In contrast, in very dry areas or during arid phases, sand can move unimpeded up a sparsely vegetated stoss face and over the crest to form an avalanche or slip face on the lee side, thereby causing the dunes to shift eastward. Despite evidence that longitudinal dune crests can shift laterally to some extent, the dunes in the western part of the Simpson Desert have not migrated, either westward or eastward, more than 100m or so from their Pleistocene cores. Aeolian transport and partial or complete removal of iron cutans from around quartz grains results in dunes of widely varying colour yet of similar age.     

An algorithm for determination of aerosol opticalthickness from AVHRR imagery over oceans

Summary The uncertainty in aerosol size distributions is a main source of errors in aerosol optical thickness determined from satellite measurements. To reduce the errors resulting from the uncertainty in aerosol size distributions, we have performed sensitivity analyses. It is found the errors resulting from the uncertainty in aerosol size distribution can be considerably reduced by using the Junge power law to approximate the aerosol size distribution in an actual atmosphere, if the exponent value is determined at the same time. An iterative algorithm is then developed for the simultaneous determination of aerosol optical thickness and the exponent of the Junge power law over ocean areas from the upwelling radiances measured in AVHRR visible and near infrared channels. A number of numerical experiments are carried out to investigate the validity of the Junge power law approximation by assuming the aerosol size distributions in an actual atmosphere are bimodal with different mode parameters, and by using the actual aerosol size distributions determined at several places by Kaufman et al. (1994). The results show that the errors in determined aerosol optical thickness resulting from the Junge power law approach are significantly reduced. The iterative algorithm is investigated further by comparing the aerosol optical thickness deduced from satellite measurement with that observed by a sun photometer. Received October 10, 2001 Revised December 28, 2001     

In Situ Determination of Au and Cu in Natural Pyrite by Near‐Infrared Femtosecond Laser Ablation‐Inductively Coupled Plasma‐Quadrupole Mass Spectrometry: No Evidence for Matrix Effects

Gold and copper concentrations were determined in natural pyrite by near‐infrared femtosecond LA‐ICP‐QMS, using both sulfide reference materials (pyrrhotite Po‐726 and in‐house natural chalcopyrite Cpy‐RM) and NIST SRM 610 as external calibrators. Firstly, using NIST SRM 610 as the external calibrator, we calculated the Au concentration in Po‐726 and the Cu concentration in Cpy‐RM. The calculated concentration averages for Au and Cu were similar to the values published for Po‐726 and Cpy‐RM, respectively. Secondly, we calculated Au and Cu concentrations taking NIST SRM 610 as an unknown sample and using Po‐726 and Cpy‐RM as external calibrators. Again, the average values obtained closely reflected the preferred concentrations for NIST SRM 610. Finally, we calculated Au and Cu concentrations in natural pyrite using sulfide and silicate reference materials as external calibrators. In both cases, calculated concentrations were very similar, independent of the external calibrator used. The aforementioned data, plus the fact that we obtained very small differences in relative sensitivity values (percentage differences are between 5% and 17% for ⁵⁷Fe, ⁶³Cu and ¹⁹⁷Au) on analyses of silicate and sulfide RMs, indicate that there were no matrix effects related to the differences in material composition. Thus, it is possible to determine Au and Cu in natural sulfides using NIST silicate glasses as an external calibrator.     

Effects of bottom sediments on the survival of Enterobacter aerogenes in seawater

The survival of the coliform bacterium Enterobacter aerogenes in seawater was greatly affected by the underlying bottom sediments. The presence of sediments which contained higher concentrations of organic nutrients than the overlaying seawater prolonged the survival and even enabled growth of the bacterial cells. Results obtained from chemical analysis indicated that sediments of fine-grained, silt-clay type contained highest amounts of organic nutrients as compared with sediments with larger particle sizes such as silt and sand grains. Thus, nutrient contents of the sediments were found to be inversely proportional to sediment particle size. The degree of prolonged survival of E. aerogenes was also found to be inversely proportional to the size of the sediment particles presented. Release of the bound nutrients which became available to cells of E. aerogenes from sediments by action of waves and human activities can explain, at least in part, why high counts of coliform bacteria are obtained in coastal and beach waters.     

Toxicities of antifouling biocide Irgarol 1051 and its major degraded product to marine primary producers

Irgarol 1051 (2-methythiol-4-tert-butylamino-6-cyclopropylamino-s-triazine) is an algaecide commonly used in antifouling paints. It undergoes photodegradation which yields M1 (2-methylthio-4-tert-butylamino-6-amino-s-triazine) as its major and most stable degradant. Elevated levels of both Irgarol and M1 have been detected in coastal waters worldwide; however, ecotoxicity effects of M1 to various marine autotrophs such as cyanobacteria are still largely unknown. This study firstly examined and compared the 96 h toxicities of Irgarol and M1 to the cyanobacterium Chroococcus minor and two marine diatom species, Skeletonema costatum and Thalassiosira pseudonana. Our results suggested that Irgarol was consistently more toxic to all of the three species than M1 (96 h EC50 values: C. minor, 7.71 microug L(-1) Irgarol vs. > 200 microg L(-1) M1; S. costatum, 0.29 microg L(-1) Irgarol vs. 11.32 microg L(-1)M1; and T. pseudonana, 0.41 microg L(-1) Irgarol vs. 16.50 microg L(-1)M1). Secondly, we conducted a meta-analysis of currently available data on toxicities of Irgarol and M1 to both freshwater and marine primary producers based on species sensitivity distributions (SSDs). Interestingly, freshwater autotrophs are more sensitive to Irgarol than their marine counterparts. For marine autotrophs, microalgae are generally more sensitive to Irgarol than macroalgae and cyanobacteria. With very limited available data on M1 (i.e. five species), M1 might be less toxic than Irgarol; nonetheless this finding warrants further confirmation with additional data on other autotrophic species.