Synthesis of PAMG chelating polymers for the selective flocculation of copper minerals

Experimental techniques for preparation and characterization of polyacrylamide-glyoxal-bis-hydroxyanil (PAMG) selective flocculant are reported. The polymer could be prepared either by direct reaction of glyoxal-bis-hydroxyanil with polyacrylamide and formaldehyde, or by condensation of a diaminiphenol with glyoxal and formaldehyde on polyacrylamide.These reactions were confirmed by various techniques, namely, alcohol precipitation, dialysis, UV and IR spectroscopy. Fractionation of the polymer by membrane filtration and gel chromatography was also reported.     

Major-element petrochemistry of some extrusive rocks from the volcanically active Mariana Islands

Volcanic rocks from six of the currently or recently active volcances of the Mariana Island are show little variation in major element abundances. SiO₂ content averages 51.5 wt.%. The flows are high in Al₂O (mean 17.7 wt.%) and Fe oxides (mean 10.1 wt.% calculated as FeO only), and moderate in MgO content (mean 4.7 wt.%), Na₂O (mean 2.7 wt.%), and K₂O (mean 0.7 wt.%). Only the rocks from Farallon de Pajaros, the northernmost of the Mariana Islands, deviate slightly from the average of the analyses. Three analyses from this island are slightly higher in SiO₂ (about 54 wt.%) and Al₂O₃, and are lower in total Fe oxides and MgO. According to preferred classification, the lavas of the Mariana Islands can be termed mela-andesites, high-alumina basalts, or calc-alkaline (orogenic) basalts. The K₂O values (mean 0.7 wt.%) obtained from lavas of the Mariana Islands are significantly higher than the K₂O values (about 0.33 wt.%) from volcanics of the Izu chain to the north. Inasmuch as the substantial scatter in location of earthquake foci beneath both arcs prevents accurate delineation of the upper boundary of the Benioff zone, it presently cannot be determined whether this discrepancy in K₂O values reflects a difference in depth from the volcanic are to the dipping seismic zone or relates to other phenomena. The older volcanic islands within the Mariana-Bonin island chain apparently defined an island arc system during Eocene to Miocene time. This indicates that the present plane of convergence between the Pacific plate and the Philippine Sea plate has defined the convergence between these plates since Eocene time.     

Ion implantation effects in “cosmic” dust grains

Cosmic dust grains, whatever their origin may be, have probably suffered a complex sequence of events including exposure to high doses of low-energy nuclear particles and cycles of turbulent motions. High-voltage electron microscope observations of micron-sized grains either naturally exposed to space environmental parameters on the lunar surface or artificially subjected to space simulated conditions strongly suggest that such events could drastically modify the mineralogical composition of the grains and considerably ease their aggregation during collisions at low speeds. Furthermore, combined mass spectrometer and ionic analyzer studies show that small carbon compounds can be both synthesized during the implantation of a mixture of low-energy D, C, N ions in various solids and released in space by ion sputtering. The present results have implications concerning the origin of small molecules in interstellar or circumstellar clouds, the “aging” of cosmic dust grains in space, and the “sticking” process in the solar nebula.     

ACMEG‐TS: A constitutive model for unsaturated soils under non‐isothermal conditions

This paper introduces an unconventional constitutive model for soils, which deals with a unified thermo‐mechanical modelling for unsaturated soils. The relevant temperature and suction effects are studied in light of elasto‐plasticity. A generalized effective stress framework is adopted, which includes a number of intrinsic thermo‐hydro‐mechanical connections, to represent the stress state in the soil. Two coupled constitutive aspects are used to fully describe the non‐isothermal behaviour. The mechanical constitutive part is built on the concepts of bounding surface theory and multi‐mechanism plasticity, whereas water retention characteristics are described using elasto‐plasticity to reproduce the hysteretic response and the effect of temperature and dry density on retention properties. The theoretical formulation is supported by comparisons with experimental results on two compacted clays. Copyright © 2008 John Wiley & Sons, Ltd.     

Orbital calibration of the Early Kimmeridgian (southeastern France): implications for geochronology and sequence stratigraphy

Classic stratigraphic methods rarely provide high‐resolution correlations between intrabasinal sedimentary sequences, which are important to understand the origin of sedimentation process and its environmental change. In this study, we investigate high‐resolution cyclostratigraphic correlation from magnetic susceptibility in two Early Kimmeridgian pelagic marl‐limestone successions, at La Méouge and Châteauneuf‐d'Oze, southeastern France. Spectral analysis reveals the complete suite of orbital frequencies (precession, obliquity, and eccentricity) with the marl‐limestone couplets being primarily precession‐driven. Frequencies detected by the spectral analysis are similar between the sections, but their relative amplitudes are somewhat different, linked to the palaeoenvironmental position and the completeness of the sections. High‐resolution correlation reveals two significant hiatuses at Châteauneuf‐d’Oze. Early Kimmeridgian Platynota, Hypselocyclum, and Divisum ammonite zones were orbitally calibrated for an ultra‐high resolution assessment of geological time. Finally, strong 405‐kyr eccentricity cycles are recorded as third‐order depositional sequences.     

Nature of the small main belt Asteroid 3169 Ostro

We present a set of rotational lightcurve measurements of the small main belt Asteroid 3169 Ostro. Our observations reveal an unambiguous, double-peaked rotational lightcurve with a peak-to-peak variation up to 1.2±0.05 mag and a synodic period of 6.509±0.001 h. From the large flux variation and the overall shape of the lightcurves, we suggest that 3169 Ostro could be a tightly bound binary or a contact binary, similar to the Trojan Asteroid 624 Hektor. A shape model of this system is proposed on the assumption that 3169 Ostro is a Roche binary described by a pair of homogeneous elongated bodies, with a size ratio of 0.87, in hydrostatic equilibrium and in circular synchronous motion around each other. The direction of the spin axis is determined modulo 180° by its J2000 ecliptic coordinates λ₀=50±10°, β₀=±54±5°. The binary interpretation and the pole solution adequately fit the earlier photometric observations made in 1986 and 1988. However, additional supporting lightcurves are highly desirable especially in the next mutual events occurrence of 2008 and 2009 in order to remove the pole ambiguity and to confirm unambiguously the binary nature of 3169 Ostro.     

Mode identification of terrestrial ULF waves observed by Cluster: A case study

Using multipoint measurements from the Cluster mission wave identification techniques are applied to observations of ULF waves made in the terrestrial foreshock with the aim of identifying the modes and properties of the waves taking into account the effects of a high beta plasma. The wave properties in the spacecraft and plasma rest frames are experimentally derived using minimum variance analysis. Two waves with periods of 30 and 3 s dominate the dynamic frequency spectrum. The results indicate that these waves propagate in the fast magnetosonic and Alfvén/Ion Cyclotron modes, respectively. Both waves propagate in the upstream direction in the plasma rest frame but are convected downstream in the spacecraft frame. The measured wave properties in the plasma rest frame are in good agreement with those obtained from the theoretical kinetic dispersion relation taking into account the effects of different plasma beta. The dispersion results show a rather significant deviation from fluid model, especially when high beta plasma conditions occur. These experimentally derived foreshock ULF wave properties are in good agreement with previous results but when the effects of a high beta plasma are considered it is not as straight forward to choose the correct wave mode branch.     

Zircon U–Pb age and Hf isotope evidence for contrasting origin of bimodal protoliths for ultrahigh-pressure metamorphic rocks from the Chinese Continental Scientific Drilling project

A combined study of zircon morphology, U–Pb ages and Hf isotopes as well as whole‐rock major and trace elements was carried out for ultrahigh‐pressure (UHP) eclogite and felsic gneiss from the main hole (MH) of the Chinese Continental Scientific Drilling (CCSD) project in the Sulu orogen. The results show contrasting Hf isotope compositions for bimodal UHP metaigneous rocks, pointing to contrasting origins for their protoliths (thus dual‐bimodal compositions). The samples of interest were from two continuous core segments from CCSD MH at depths of 734.21–737.16 m (I) and 929.67–932.86 m (II) respectively. Zircon U–Pb dating for four samples from the two core segments yields two groups of ages at 784 ± 17 and 222 ± 3 Ma, respectively, corresponding to protolith formation during supercontinental rifting and metamorphic growth during continental collision. Although the Triassic UHP metamorphism significantly reset the zircon U–Pb system of UHP rocks, the Hf isotope compositions of igneous zircon can be used to trace their protolith origin. Contrasting types of initial Hf isotope ratios are, respectively, correlated with segments I and II, regardless of their lithochemistry. The first type shows positive ?_Hf(t) values of 7.8 ± 3.1 to 6.0 ± 3.0, with young Hf model age of 1.03 and 1.11 Ga. The second type exhibits negative ?_Hf(t) values of ?6.9 ± 1.6 to ?9.1 ± 1.1, with old Hf model ages of 2.11 and 2.25 Ga. It appears that the UHP rocks from the two segments have protoliths of contrasting origin. Consistent results are also obtained from their trace element compositions suggesting that mid‐Neoproterozoic protoliths of bimodal UHP metaigneous rocks formed during supercontinental rifting at the northern margin of the South China Block. Thus, the first type of bimodal magmatism formed by rapid reworking of juvenile crust, whereas the second type of bimodal magmatism was principally generated by rift anatexis of Paleoproterozoic crust. Melting of orogenic lithosphere has potential to bring about bimodal magmatism with contrasting origins. Because arc–continent collision zones are the best place to accumulate both juvenile and ancient crusts, the contrasting types of bimodal magmatism are proposed to occur in an arc–continent collision orogen during the supercontinental rifting, in response to the attempted breakup of the supercontinent Rodinia at c. 780 Ma.     

The role of social norms in climate adaptation: Mediating risk perception and flood insurance purchase

Flood insurance plays an important role in climate adaptation by recovering insured losses in the event of catastrophic flooding. Voluntary adoption of flood insurance has been seen as a function of risk perception that is shaped by social norms. This paper attempts to clarify the relationship between these factors. It is based on a household survey conducted in the eastern cities of Australia and involving a total of 501 randomly selected residents. Results of a path analysis show that the likelihood of having flood insurance cover was associated with perceived social norms, but not perceived flood risk. In addition, perceived norms and risk were statistically related to each other. It is concluded that social norms played a mediating role between insuring decision and risk perception. Risk perception might influence the insuring decision indirectly through shaping perception of social norms. This implies that adaptive behaviour is not necessarily a function of risk perception, but an outcome of its impacts upon the ways in which the individuals situate themselves in their social circles or the society. There is a feedback process in which individual perceptions of risk manifest as both a cause and effect, shaping and being shaped by the socio-cultural context.