南黄海沉积物中活性铁氧化物对有机碳的保存作用

土壤和沉积物中活性铁对有机质的吸附对有机质具有长期稳定和保存作用,从而在地质时间尺度上缓冲大气CO₂浓度。本文利用连二亚硫酸钠还原性溶解提取活性铁氧化物（FeR）及与之结合的有机碳（Fe-OC）,定量研究了南黄海沉积物中FeR与OC之间的结合方式以及FeR对OC的保存作用,讨论了深度增加对二者相互作用的影响。结果表明,南黄海沉积物中Fe-OC占沉积物总有机碳的份数（f_Fe-OC）为（13.2±7.47）%,即活性铁对OC的年吸附量为0.72 Mt,占全球边缘海沉积物TOC年埋藏通量的0.44%。Fe-OC的平均OC:Fe为4.50±2.61,表明共沉淀作用对有机质的保存起重要作用,且其比值随海源有机质含量增加而增加。Fe-OC稳定碳同位素（δ13C_Fe-OC）结果表明,FeR优先保存活性有机质,但这种选择性随OC:Fe增大而减弱。随深度增加,f_Fe-OC和δ13C_Fe-OC均未表现出显著变化,这与该海域沉积物中有机质活性较低、铁还原作用较弱有关。     

Study on the negative bias temperature instability effect under dynamic stress

This paper studies negative bias temperature instability (NBTI) under alternant and alternating current (AC) stress. Under alternant stress, the degradation smaller than that of single negative stress is obtained. The smaller degradation is resulted from the recovery of positive stress. There are two reasons for the recovery. One is the passivation of H dangling bonds, and another is the detrapping of charges trapped in the oxide. Under different frequencies of AC stress, the parameters all show regular degradation, and also smaller than that of the direct current stress. The higher the frequency is, the smaller the degradation becomes. As the negative stress time is too small under higher frequency, the deeper defects are hard to be filled in. Therefore, the detrapping of oxide charges is easy to occur under positive bias and the degradation is smaller with higher frequency.     

Impact of multiple satellite ocean color samplings in a day on assessing phytoplankton dynamics

Ocean-color imagers on conventional polar-orbiting satellites have a revisit time of ??2 days for most regions, which is further reduced if the area is frequently cloudy. The Geostationary Ocean Color Imager (GOCI), the first ocean-color imager on a geostationary satellite, provides measurements 8 times a day, thus significantly improving the frequency of measurements for studies of ocean environments. Here, we use results derived from GOCI measurements over Taihu Lake to demonstrate that the extra sampling can be used to improve the accuracy of statistically averaged longer-term (daily) measurements. Additionally, using numerical simulations, we demonstrate that the coupling of diurnal variations of both biomass and photosynthetic available radiation can improve the accuracy of daily primary production estimates. These results echo that higher sampling frequency can improve our estimates of longer-term dynamics of biogeochemical processes and highlights the value of ocean color measurements from geostationary satellites.     

Automated multi-scale classification of the terrain units of the Jiaxie Guyots and their mineral resource characteristics

Given the advances in satellite altimetry and multibeam bathymetry, benthic terrain classification based on digital bathymetric models (DBMs) has been widely used for the mapping of benthic topographies. For instance, cobalt-rich crusts (CRCs) are important mineral resources found on seamounts and guyots in the western Pacific Ocean. Thick, plate-like CRCs are known to form on the summit and slopes of seamounts at the 1 000–3 000 m depth, while the relationship between seamount topography and spatial distribution of CRCs remains unclear. The benthic terrain classification of seamounts can solve this problem, thereby, facilitating the rapid exploration of seamount CRCs. Our study used an EM122 multibeam echosounder to retrieve high-resolution bathymetry data in the CRCs contract license area of China, i.e., the Jiaxie Guyots in 2015 and 2016. Based on the DBM construted by bathymetirc data, broad- and fine-scale bathymetric position indices were utilized for quantitative classification of the terrain units of the Jiaxie Guyots on multiple scales. The classification revealed four first-order terrain units (e.g., flat, crest, slope, and depression) and eleven second-order terrain units (e.g., local crests, depressions on crests, gentle slopes, crests on slopes, and local depressions, etc.). Furthermore, the classification of the terrain and geological analysis indicated that the Weijia Guyot has a large flat summit, with local crests at the southern summit, whereas most of the guyot flanks were covered by gentle slopes. “Radial” mountain ridges have developed on the eastern side, while large-scale gravitational landslides have developed on the western and southern flanks. Additionally, landslide masses can be observed at the bottom of these slopes. The coverage of local crests on the seamount is ~1 000 km2, and the local crests on the peak and flanks of the guyots may be the areas where thick and continuous plate-like CRCs are likely to occur.     

Calculation and analysis of negative skin of monopile applied for offshore wind turbine

Monopiles are considered to be as a kind of viable foundation types for offshore wind turbines. The effect of negative skin friction on pile foundation is always an important problem. There are very important theoretical and practical significance to study the distribution law of negative skin friction and the calculation method. Based on the special stratum, the stress and strain of the monopile and soil are simplified, and the improved Kezdi’s double-broken-line model is adopted. The analytical solution of negative skin friction of monopile is deduced according to the degree of skin friction. An engineering case was analyzed by the method, and the calculated results agree well with the measured data. The calculation method proposed can accurately describe the range of the monopile skin frictional distribution and the position of the neutral point, and it is simple and convenient to calculate, that is also a feasible method for calculating the negative skin friction of monopile of offshore wind turbines in practical engineering.     

Spectroscopic ellipsometric study of the optical properties of Ag2O film prepared by direct-current magnetron reactive sputtering

The Ag₂O film, as-deposited by direct-current magnetron reactive sputtering at a substrate temperature of 150 °C, clearly shows a preferential orientation (111), and is capable of lowering the threshold value of the thermal decomposition temperature to about 200 °C, which is helpful to its application in optical and magneto-optical storage. This paper fits its optical constants in terms of a general oscillator model by using measured ellipsometric parameters. The fitted oscillator energy 2.487 eV is close to the optical direct interband transition energy value of the Ag₂O film determined by Tauc equation; whereas, the fitted oscillator energy 4.249 eV is far from the fitted plasma oscillator energy 4.756 eV by single-oscillator energy. The photoluminescence spectrum centred at about 2.31 eV indicates a direct-energy gap photoluminescence mechanism of the Ag₂O film.     

均相沉淀法制备Ni(OH)_2和NiO纳米晶

以ＮｉＳＯ４·６Ｈ２Ｏ 为主要原料、以ＣＯ（ＮＨ２）２ 为沉淀剂,采用均相沉淀法合成了纳米级Ｎｉ（ＯＨ）２ 和ＮｉＯ粉末,用Ｘ射线衍射分析（ＸＲＤ） 、差热分析（ＤＴＡ） 等实验手段对样品的热稳定性、相转变温度、相结构和粒子形状等进行了表征。结果表明所合成的ＮｉＯ粉末的粒径约为６ｎｍ ,且基本成球形。     

DOT2008A海面地形模型在我国邻近海域的精度评估

文中首先介绍了DOT2008A模型建立的原理和方法,利用我国48个长期验潮站19 a连续观测数据验证DOT2008A模型的精度,其均方差为0.118 m,残差的标准偏差为0.086 m;联合多源测高卫星建立的海面地形模型数据验证DOT2008A的精度,均方差为0.106 m,残差的标准偏差为0.099 5 m,且其残差分布图基本符合正态分布。从实验结果来看,DOT2008A模型在我国周边海域精度较高,其建立方法较为合理,转化应用价值较高;同时与多源测高卫星建立的海面地形比较结果来看,验证了自主建立的海面地形模型的正确性,对建立我国高精度海面地形模型具有重要的借鉴意义。     

Status of Macrobenthic Community and Its Relationships to Trace Metals and Natural Sediment Characteristics

Laizhou Bay, located in the northwest of Shandong Peninsula, has complex transitional environments between terrestrial and marine ecosystems. In the present study, a total of 122, 131, and 139 species were collected in spring, summer, and autumn 2011, respectively. Species constitutions of macrobenthos were grouped into four phyla, of which annelida were the most abundant phylum, the average biomass proportion of echinodermata was the lowest, and the proportion of important species for mollusca was the highest. The structure of the macrobenthic community showed significant differences between sites, and greater divergence was observed between the third site (S03) and other stations. The ABC plots showed that the biomass curve lay below the abundance curve, and the W‐statistic value was negative. The result of the BOPA index showed that two stations had moderate ecological status in spring and that there were two heavily polluted sites and one moderately polluted site in summer. The BIO‐ENV analyses indicated that the grain‐size fractions together with trace metals (Hg, Pb, Zn, Cu, and Cr) could be considered as the major environmental variables influencing the macrobenthic patterns. The results together demonstrated that the macrobenthic communities in Laizhou Bay were negatively affected, perhaps by the tremendous impact of heavy metals in the sediments.     

南海北部深水区新生代岩浆岩分布规律及其与海底地质灾害的相关性

前人对南海北部新生代陆缘盆地结构、构造样式和期次等做了大量的研究工作,但对于具体体现内动力过程的岩浆活动关注较少,尤其是北部深水区的研究鲜有涉及。本文基于二维地震剖面的解译分析,将南海北部新生代岩浆岩划分为3个集中分布区:琼东南-西沙区、神狐区和东沙区。各区域岩浆岩的产出状态有所差异,其中琼东南-西沙区岩浆岩的平面展布规律性极强,主要受右行右阶的走滑断裂控制;神狐区岩浆岩位于NW向与NE向断裂的交汇处,侵位空间受先存断裂制约;东沙区岩浆岩的产生与东沙运动期间区域伸展过程有直接关系。作为内动力的表征,岩浆作用对于海底地形地貌具有重要的改造作用,与活动断裂、海底滑坡、浅层气等海底地质灾害也具有成因上的关联。