Late Paleozoic adakites and Nb-enriched basalts from northern Xinjiang, northwest China: Evidence for the southward subduction of the Paleo-Asian Oceanic Plate

Abstract   Volcanic rocks consisting of adakite and Nb-enriched basalt are found in the early Devonian Tuoranggekuduke Group in the northern margin of the Kazakhstan-Junggar Plate, northern Xinjiang, northwest China. The geochemical characteristics of the andesitic and dacitic rocks in this area resemble that of adakites. The relatively high Al₂O₃, Na₂O and MgO content and Mg^♯ values indicate that the adakites were generated in relation to oceanic slab subduction rather than the partial melting of basaltic crust. A slightly higher SrI and a lower ɛ _Nd( t  = 375 Ma) compared to adakites of mid-oceanic ridge basalt (MORB) imply that slab sediments were incorporated into these adakites during slab melting. The Nb-enriched basalt lavas, which are intercalated in adakite lava suite, are silica saturated and are distinguished from the typical arc basalts by their higher Nb and Ti content (high field strength element enrichment). They are derived from the partial melting of the slab melt-metasomatized mantle wedge peridotite. Apparently, positive Sr anomalies and a slightly higher heavy rare earth element content in these adakites compared to their Cenozoic counterparts indicate that the geothermal gradient in the Paleo-Asian Oceanic subduction zone and the depth of the Paleo-Asian Oceanic slab melting are between those of their Archean and Cenozoic counterparts. The distribution of the adakites and Nb-enriched basalts in the northern margin of the Kazakhstan-Junggar Plate, northern Xinjiang, indicates that the Paleo-Asian Oceanic Plate subducted southward beneath the Kazakhstan-Junggar Plate in the early Devonian period.     

大别山北部榴辉岩的Pb同位素特征

大别山北部榴辉岩的全岩 Pb同位素研究结果表明 ,Pb同位素比值 N(2 0 6 Pb) /N (2 0 4 Pb) =16 .773～ 18.339,N (2 0 7Pb) /N (2 0 4 Pb) =15 .346～ 15 .5 16 ,N (2 0 8Pb) /N (2 0 4 Pb) =37.133～ 38.346 ,平均值分别为 17.6 5 ,15 .4 5和 37.81)明显接近于下地壳成分 N(2 0 6 Pb) /N(2 0 4 Pb) ,N(2 0 7Pb) /N(2 0 4 Pb) ,N(2 0 8Pb) /N(2 0 4 Pb)值分别为 17.6 2 ,15 .35和 38.75 ) ,同时 ,北部榴辉岩的 U /Pb比 (0 .0 0 2～ 0 .0 0 9)及 U质量分数 (0 .0 4× 10 - 6 ～ 0 .2 3× 10 - 6 )稍低于下地壳平均值 ,而 Pb质量分数 (6 .72× 10 - 6～ 2 6 .6 4× 10 - 6 )则接近于或略高于地壳平均值 ,但是 ,U/Pb比则明显偏离上地壳平均值、也不同于大别山南部榴辉岩及有关岩石 (较低的 Pb质量分数和较高的 U/Pb比 )。此外 ,考虑到研究区榴辉岩的岩石地球化学及 Sr,Nd同位素年代学方面研究已证明它们大多数为印支期扬子陆壳俯冲变质成因。由此进一步表明 ,大别山北部榴辉岩的原岩大多数应来自于扬子大陆下地壳。这对正确认识大别山碰撞造山带的构造格局和演化具有重要意义。     

EXPERIMENTAL STUDY ON THE COHERENT STRUCTURE OF THE TURBULENT BOUNDARY LAYER IN OPEN-CHANNEL FLOW

1 INTRODUCTION The coherent structure of turbulence is the most important discovery of turbulence studies in the last several decades. The coherent structure is a joint spatial state (Liang, 1999). In this space, there exist all kinds of motions that are organized and related. Namely, strip structures, large vortical structures, and other organizing flows are present. In 1932, researchers found that turbulence wasn抰 a fully random phenomenon and came to realize that the repeated emergen…     

AN IMPROVED SEMI-IMPLICIT TIME DIFFERENCE SCHEME OF SPECTRAL MODEL AND NUMERICAL APPLICATIONS

In fact,the popular semi-implicit time difference scheme of spectral model still includes someimportant linear terms using time explicit difference scheme,and the major terms are directlyrelated to fast internal-and external-gravity waves in the atmospheric forecasting equation.Additionally,due to using time difference on two terms at different time.the popular schemeartificially introduces unbalance between pressure gradient force and Coriolis force terms whilenumerically computing their small difference between large quantities.According to thecomputational stability analysis conducted to the linear term time difference scheme in simpleharmonic motion equation,one improved semi-implicit time difference scheme is also designed inour study.By adopting a kind of revised time-explicit-difference scheme to these linear terms thatstill included in spectral model governing equations,the defect of spectral model which only partlyusing semi-implicit integrating scheme can be overcome effectively.Moreover,besides all spectralcoefficients of prognostic equations,especially of Helmholtz divergence equation,can be workedout without any numerical iteration,the time-step (computation stability) can also be enlarged(enhanced) by properly introducing an adjustable coefficient.     

Surface complexation modelling of Cd(II), Cu(II), Ni(II), Pb(II) and Zn(II) adsorption onto kaolinite

Proton binding constants for the edge and basal surface sites of kaolinite were determined by batch titration experiments at 25 °C in the presence of 0.1 M, 0.01 M and 0.001 M solutions of NaNO₃ and in the pH range 3-9. By optimizing the results of the titration experiments, the ratio of the edge sites to the basal surface sites was found to be 6:1. The adsorption of Cd(II), Cu(II), Ni(II), Zn(II) and Pb(II) onto kaolinite suspensions was investigated using batch adsorption experiments and results suggested that in the lower pH range the metallic cations were bound through non-specific ion exchange reactions on the permanently charged basal surface sites (X⁻). Adsorption on these sites was greatly affected by ionic strength. With increasing pH, the variable charged edge sites (SOH) became the major adsorption sites and inner-sphere specifically adsorbed monodentate complexes were believed to be formed. The effect of ionic strength on the extent of adsorption of the metals on the variable charged edge sites was much less than those on the permanently charged sites. Two binding constants, log K_(X2Me) and log K_(SOMe), were calculated by optimizing these constants in the computer program FITEQL. A model combining non-specific ion exchange reactions and inner-sphere specific surface complexations was developed to predict the adsorption of heavy metals onto kaolinite in the studied pH range. Linear free energy relationships were found between the edge site binding constants and the first hydrolysis constants of the metals.     

近55年来云南区域性干旱事件的分布特征和变化趋势研究

本文利用一种简化的区域性干旱事件识别方法,对近55年来云南区域性干旱事件进行了识别,在此基础上,选取区域性干旱事件的持续天数、影响站点数、平均强度、累积强度和极端最大强度这5个单一事件评价指标,构建了云南区域性干旱的综合评估模型,确定干旱等级划分标准。进一步分析表明,云南区域性干旱的发生频次、累积强度和累积影响站次均呈现上升趋势;云南在12、1和3月干旱发生最多,7、8月干旱发生最少;干旱持续天数集中在15～45 d,最长的可达222d;云南多发全省性的干旱且旱情偏重。云南中部区域干旱偏多、偏重发生;在严重的干旱事件中,中部型发生频次最多。     

城市小区建筑物和屋顶绿化对小区气象环境影响的数值模拟研究

为了研究城市小区建筑物和屋顶绿化对小区气象环境影响,利用USDSM(城市小区气象与污染扩散数值模式)对杭州市一临钱塘江小区进行敏感性试验。结果表明:(1)小区建筑物的拖曳、阻尼和摩擦作用造成敏感小区内10 m高度平均水平风速减小0.56 m·s-1;对风速的影响范围:迎风向为500 m,背风向为500~600 m,侧风向为200 m,影响高度达到建筑物群平均高度的两倍以上。(2)小区建筑物存在导致低层污染扩散能力减弱,平均污染物浓度达到初始浓度0.01的时间延迟7.6 min。(3)100%的屋顶绿化面积可造成敏感小区平均地表温度下降0.56℃;5 m高度平均气温下降0.70℃;小区平均建筑物高度处气温下降0.94℃。敏感小区内10 m高度平均水平风速增加0.14 m·s-1;小区建筑物下游水平风速显著减小,影响范围达到了600~800 m。     

线状要素移位的研究

制图综合常要求将地形图要素从其正确的图面位置偏移一点。本文就线状要素的移位问题进行讨论。首先提出移位场的概念,这对于由于移位所产生的“连锁反应”能较好地解决;然后,提出一种栅格探测——矢量计算方祛,加快移位计算的速度。     

Types of Organic Fades and Source Rock Assessment of the Coal-Measure Mudstone in the Turpan-Hami Basin

This paper discusses the enviromental characteristics of carbonaceous mudstone and mudstone (coal-measure mudstone in short) of the Early and Middle Jurassic in the Turpan-Hami basin, which were formed in swamps. Through the organic facies study of the coal-measure mudstone in this area, the authors clarify that the flowing-water swamp is the most advanced organic facies belt. Furthermore, according to the practical materials of coal-measure mudstone in the area and with the evaluation criteria of lacustrine mudstone in the past, the authors have established the integrated symbol systems from the abundance of organic matter and the type of organic matter, which can be used in the source rock evaluation of the coal-measure mudstone.     

东营凹陷广饶海相灰岩油藏的勘探与成因机制探讨

山东东营凹陷南部的广饶油藏为一奥陶系灰岩残丘山整带含稠油的大潜山油藏,其埋藏深度为６３４．４￣１５７５．０ｍ,现已探明含油面积３０．７ｋｍ＾２。１９９０年发现一个山头含油,１９９１￣１９９３年发现多个山头含油,１９９６￣１９９７年在各山头之间的部位钻探,结果探明潜山带南部整带含油。地质和地球化学资料分析证实,该油藏不仅是今生储潜山油藏,还是烃类经基岩风化壳运移、聚集而形成的稠油油藏。形成稠油的主要