合成斜方辉石系列的红外光谱研究

在30kbar和900℃条件下,用等化学计量氧化物混合物合成了11个斜方辉石系列的样品,并对合成的样品进行了X射线粉晶分析和红外光谱分析。分析结果表明,晶胞参数和红外光谱随化学成分的改变而产生复杂的变化。不仅晶胞参数b和M而且频率ν_(670cm)-1和M之间存在很好的线性相关关系,通过用最小二乘法所拟合的相关方程可容易地测定斜方辉石的成分,但是α和c与M之间只有较差的线性关系,而ν_(450cm)-1和M以及ν_(380cm)-1和M之间并无简单的线性相关关系,这可归因于Fe~(2+)在M_1和M_2位置的有序分布。     

黔中隆起北缘五峰-龙马溪组页岩元素地球化学特征及其地质意义

为探讨黔中隆起北缘五峰-龙马溪组富有机质页岩的沉积环境和物源区背景,对区内两口井的样品进行了有机碳含量、微量元素和稀土元素地球化学测试和分析.结果表明,研究区五峰-龙马溪组页岩在沉积时以贫氧-厌氧环境为主,富氧环境也偶尔存在,且龙马溪组沉积水体还原程度比五峰组高.LaN/YbN值的变化反映沉积速率为:龙马溪组下部<五峰...     

基于三维激光扫描技术的岩质边坡泥化夹层空间分布和几何形态

为了定量研究泥化夹层的空间分布和几何形态,以云南省玉溪市生活垃圾焚烧发电厂高边坡局部开挖剖面为对象,利用徕卡ScanStation C10三维激光扫描仪和瑞典ROMER RA-7520-2六轴关节臂三维测量仪进行扫描,得到了开挖剖面和泥化夹层的原始点云数据;然后采用Cyclone和Geomagic Wrap软件对点云数据进行一系列处理,分析了泥化夹层的三维空间分布、层面产状、间距、层面粗糙度和几何形态。结果表明：大部分泥化夹层横向分布于整个扫描剖面,少数呈局部分布;泥化夹层的平均倾向为196.41°±5.51°,平均倾角为22.27°±2.23°,间距在3.7~49.1 cm之间,平均值为（20.4±12.0）cm;不同层位及同一层位不同横向位置的泥化夹层厚度都不等,最厚约20 mm,最薄小于1 mm;泥化夹层顶面局部典型区域的平面拟合偏差在-22.4~32.5 mm之间,沿夹层倾向的粗糙度系数在5.67~16.77之间,平均值为10.11±3.25;泥化夹层的表面积与体积之比在5.14~5.86 cm^-1之间。运用三维激光扫描技术研究泥化夹层的空间分布和几何形态是可行的。玉溪市生活垃圾焚烧发电厂高边坡的泥化夹层具有宏观整体上相对平直、相互近似平行、非等距分布、间距小、层数多、厚度薄,细观上顶面粗糙底面相对光滑、三维形态复杂的特点。     

Numerical and theoretical research on stress distribution in the loosening zone of the trapdoor problem

The traditional theory of soil arching effect was developed on the assumption that stress distribution in the loosening zone is uniform. However, because of the deflection of principal stress' direction, the stress distribution in the loosening zone is actually ununiform. For the evaluation of principal stress axis deflection and stress redistribution, a discrete element method numerical model of trapdoor problem is established for the simulation of soil arching effect. Based on the numerical results, an arc shape of major principal stress trajectory and uniform horizontal stress distribution at the same depth of the loosening zone are adopted. An analytical model is raised to estimate the average loosening earth pressure acting on the trapdoor and stress distribution in the loosening zone at a limit state. In addition, comparison studies are carried out between the predictions of the proposed solutions and discrete element method numerical results as well as available model test results, thereby validating the accuracy of the proposed theoretical model. Both numerical and theoretical results indicate that the vertical stress distribution in the loosening zone is obviously ununiform. The load acting in the middle of loosening zone is transferred toward two sides so that the vertical stress distribution in loosening zone is concave.     

Hotspots and a clumpy disc: variability of brown dwarfs and stars in the young σ Ori cluster

The properties of accretion discs around stars and brown dwarfs in the σ Ori cluster (age 3 Myr) are studied based on near-infrared (IR) time series photometry supported by mid-IR spectral energy distributions (SEDs). We monitor ∼30 young low-mass sources over eight nights in the J and K band using the duPont telescope at Las Campanas. We find three objects showing variability with J -band amplitudes  ≥0.5 mag  ; five additional objects exhibit low-level variations. All three highly variable sources have been previously identified as highly variable; thus, we establish the long-term nature of their flux changes. The light curves contain periodic components with time-scales of  ∼0.5–8 d  , but have additional irregular variations superimposed – the characteristic behaviour for classical T Tauri stars. Based on the colour variability, we conclude that hotspots are the dominant cause of variations in two objects (#19 and #33), including one likely brown dwarf, with spot temperatures in the range of 6000–7000 K. For the third one (#2), a brown dwarf or very low-mass star, inhomogeneities at the inner edge of the disc are the likely origin of variability. Based on mid-IR data from Spitzer , we confirm that the three highly variable sources are surrounded by circum-(sub)-stellar discs. They show typical SEDs for T Tauri-like objects. Using SED models, we infer an enhanced scaleheight in the disc for the object #2, which favours the detection of disc inhomogeneities in light curves and is thus consistent with the information from variability. In the σ Ori cluster, about every fifth accreting low-mass object shows persistent high-level photometric variability. We demonstrate that estimates for fundamental parameters in such objects can be significantly improved by determining the extent and origin of the variations.     

变异函数在异常空间插值中的应用

针对数据空间架构中异常点对地质数据解译过程的干扰，以协方差数学理论为基础，提出界定空间数据分布方法-变异函数。着重阐述变异函数的求取过程，对新疆贝克滩水系沉积物化探数据处理，预测误差均值为0．1032、平均预测标准差为21．12、标准均方根预测误差为0．9841。预测值与样品实测值误差较小，界定的空间数据分布与实际矿床（点）分布吻合较好。     

气候模式-农业气象模式集成系统的小麦灌溉管理新途径

首次采用区域数值预报模式与农业气象模型结合的技术途径, 构成一个气候模式-土壤水分模式-灌溉模式的系统模型。模型的数值天气预报部分采用大气过程与陆面过程耦合的区域气候模式; 农业气象模型采用适用于冬小麦区的土壤水分和灌溉管理预报模型。研究表明, 本模型较农业气象模型中一般用气候平均作为环境背景场的方法其预测能力有显著提高, 并提供覆盖整个小麦生长期的区域土壤水分定量预报和灌溉管理服务, 具有很好的使用和推广前景。     

鄂尔多斯盆地西南部长8段砂岩沥青地球化学特征及其来源分析

系统采集了鄂尔多斯盆地西南部地区延长组8段沥青砂岩,对砂岩沥青的地球化学特征进行了研究,探讨了沥青的母质特征、形成环境和成熟度。研究结果表明:(1)长8段砂岩沥青中高碳数的正构烷烃优势明显,规则甾烷中C_(29)含量相对较高,萜烷系列中四环萜烷含量较高,C_(24)四环萜烷/(C_(24)四环萜烷+C_(26)三环萜烷)的值为0.26~0.52,C_(23)三环萜烷/(C_(23)三环萜烷+C_(30)藿烷)的值分布范围为0.06~0.41,这些都指示研究区长8段砂岩沥青母质来源为混合型,并且陆源有机质贡献较大;(2)砂岩沥青中Pr/Ph为0.67~1.07,同时,沥青中检测出低丰度的β胡萝卜烷,说明沥青形成环境为弱氧化—弱还原环境,较低丰度的伽马蜡烷与C_(30)+藿烷指示沥青的母质形成于淡水或微咸水湖泊环境;(3)长8段砂岩沥青的C31藿烷22S/(22S+22R)、C_(29)甾烷20S/(20S+20R)、C_(29)甾烷ββ/(αα+ββ)和C_(29)重排甾烷20S/(20S+20R)均接近或已经达到平衡值,反映沥青为成熟沥青。将研究结果与已报道潜在烃源岩的生物标志化合物特征进行对比,显示出研究区长8段砂岩沥青主要来源于延长组7段烃源岩,表明长7段烃源岩是研究区最主要的烃源岩之一。     

Influence of land use on the persistence effect of riverine phosphorus

The persistence effect contribution of legacy nutrients is often cited as a reason for little or no improvement in water quality following extensive implementation of watershed nutrient mitigation actions, yet there is limited knowledge concerning factors influencing this response, often called the “persistence effect.” Here, we adopted detrended fluctuation analysis and Spearman analysis methods to assess the influence of land use on the watershed phosphorus (P) persistence effect, using monthly water quality records during 2010–2016 in 13 catchments within a drinking water reservoir watershed in eastern China. Detrended fluctuation analysis was used to calculate the Hurst exponent α to assess watershed legacy P characteristics (α  ≈ 0.5, α  > 0.5, and α  < 0.5 indicate white noise, persistence, and anti‐persistence, respectively). Results showed weak to strong P persistence (0.60–0.81) in the time series of riverine P in the 13 catchments. The Hurst exponent α had negative relationships with agricultural land (R = ?.47, p = .11) and developed land (R = ?.67, p = .01) and a positive relationship with forest land cover (R = .48, p = .10). The persistence effect of riverine P was mainly determined by retention ability (biogeochemical legacy) and migration efficiency (hydrological legacy). A catchment with strong retention capacity (e.g., biomass uptake/storage and soil PO₄ sorption) and low migration efficiency results in a stronger persistence effect for riverine P. In practice, source control is more effective in catchments with weak persistence, whereas sink control (e.g., riparian buffers and wetlands) is preferred in catchments with strong persistence effects.