山西辛安岩溶泉形成条件及随机模型

本文详细分析了山西辛安岩溶泉的水文地质条件,并通过对泉域岩溶水的补给、径流、排泄条件的分析,将辛安泉域概化为单输入单输出线性时不变集中参数随机系统的概念模型。利用24年的水文序列资料进行基流分割,获得泉多年月平均流量过程曲线,求得泉年平均流量和年平均补给量。在此基础上,应用滑动平均模型（MA）,自回归—滑动平均模型（AR-MA）及泉流量调和分析—残差自回归等三个模型,对泉域地下水进行模拟,获得了满意的结果,不仅揭示了泉水动态特征,而且对泉流量动态进行了预报,为晋东南区域经济规划提供了有益资料。     

Red clay deposits on the Chinese Loess Plateau during 11.0–2.6?Ma and its implications for long-term evolution of East Asian monsoon

Loess and red clay on the Chinese Loess Plateau have produced a detailed history of the East Asia monsoon for the past eight million years. Recently, a well-conserved red clay sequence was discovered at Shilou on the eastern edge of Chinese Loess Plateau, extending the monsoon history back to approximately 11 Ma. By comparing lithologic features, particle size distribution, magnetic susceptibility and deposition rate of Shilou red clay sequence, the paleomonsoon evolution from 11 to 2.6 Ma can be divided into four stages: largely fluctuated stage (11.0–8.0 Ma), relatively strengthened period (8.0–6.5 Ma), extremely changed stage (6.5–4.9 Ma) and further intensified period (4.9–2.6 Ma). The new evidence indicates that variation of paleomonsoon has close relationship with uplifting of the Tibetan Plateau and ongoing global cooling and the consequent expansion of ice sheets during 11.0–2.6 Ma.     

胶东焦家断裂带与金矿的成生关系

文中着重阐述了控矿断裂活动与焦家金矿Ⅱ、Ⅰ、Ⅲ号矿体之间的成生关系。指出:焦家金矿Ⅱ号矿体与控矿断裂第一期活动有关,Ⅰ号矿体与第二期活动有关,Ⅲ号矿体与第三期活动有关。控矿断裂第一、二期活动显压扭性,第三期活动则显张扭性特征,Ⅰ、Ⅱ号矿体的矿化类型为破碎蚀变岩型,Ⅲ号矿体为多金属硫化物脉型。      

Deep root of a continent-continent collision belt: Evidence from the Chinese Continental Scientific Drilling (CCSD) deep borehole in the Sulu ultrahigh-pressure (HP-UHP) metamorphic terrane, China

The Chinese Continental Scientific Drilling (CCSD) deep borehole, which reached a depth of 5158 m in the Sulu ultrahigh-pressure (UHP) metamorphic terrane, provides a new window into the deep root of a continent-continent collision belt, and the tectonic processes by which supracrustal material is recycled into the mantle by subduction and then uplifted to the surface. Major research themes of the CCSD project were to: (1) determine the three-dimensional composition, structure and geophysical character of the deep root of this orogenic belt; (2) investigate the nature and timing of the UHP metamorphism; (3) investigate the processes of crust-mantle interaction involved in the formation and exhumation of the UHP rocks; (4) study the process of fluid circulation and mineralization during subduction and exhumation; (5) study the rheological properties of the various rocks during subduction and exhumation; (6) develop and refine dynamic models for deep subduction and exhumation of crustal rocks, and (7) establish a long-term, natural laboratory for the study of present-day crustal dynamics (e.g., stress, strain, fluid activity). The CCSD has developed precise oriented profiles of the main borehole in terms of lithology, geochemistry, oxygen isotopes, zircon SHRIMP U-Pb ages, ⁴⁰Ar-³⁹Ar ages, deformation, rheology, mineralization, physical properties of the rocks, petrophysical logs, seismic reflections and underground fluids. The present paper summarizes the integrated research results of this project, especially the new findings concerning the deep root of a continent-continent collision.     

海南岛几个重大基础地质问题的探讨

海南岛有无泥盆纪地层？有无加里东运动？有无加里东期花岗岩？历来是大家关注和争论的焦点问题。在１：５万昌江县幅和邦溪幅地质调查研究中,笔者对上述问题进行了探讨,并取得了一些重要进展：首次在海南岛发现珊瑚化石Ｃｙｓｔｏｐｈｒｅｎｔｉｓ ｋａｌａｏｈｏｅｎｓｉｓ Ｙｕ,结合旋回地层学研究主为,在昌江县鸡心－鸡实一带南好组（Ｃ１ｎ）中下部可能存在中晚泥盆世地层;首次发现并圈定了加里东期花岗岩体,时代为３６     

包气带的水分分布特征及给水度的探讨

文中用不等径的葫芦状毛管网络模型讨论了均质土的重力释水机制,认为重力释水与变动后的潜水位以上原饱水带及与其相联系的支持毛细水带有关;据此定义了给水度。 均质土给水度的大小与重力释水前后包气带的水分分布特征有关。由模型的分析说明,蒸发条件下的初始水分分布特征曲线偏低,造成均质土的重力释水减量,使给水度变小。     

Rare—Earth Element Geochemistry of Elogites from the Ultra—High Pressure Metamorphic Belt in Central China

Based on their REE contents and REE patterns,eclogites from the ultra-high pressure metamorphic belt in central China may be roughly divided into xis types including LREE-rich.LREE-rich positive Eu anomaly,LREE-rich negative Eu anomaly,REE pattern-smooth,MREE-rich and HREE-rich.The LREE_rich,LREE-rich positive Eu anomaly and LREE-rich negative Eu anomaly types of eclogites are dominant .REE types of eclogites in different areas can be compared and the REE feactures of the same REE type of eclogites in different areas are similar.The results of reconstruction of the primary rocks show that the primary rocks of eclogites possibly are dominated by continental tholeiites which are the product of partial melting of relatively fertile mantle and the rocks of tholeiite crystallization-differentiation.There is perfect evolution relationship among the primary rocks of the LREE-rich, LREE-rich positive Eu anomaly and LREE-rich negative Eu anomaly types of eclogites and among those of the REE pattern smooth and MREE-rich types of eclogites,the former three types were deried from continental settings and the latter two from nearly oceanic settings.Meanwhile,it is concluded that the mantle sources of primary rocks of the eclogites are inhomogeneous and the primary rocks of eclogites in this area appear to have undergone varying degree of crustal contamination.     

东秦岭造山带两类元古宙地壳基底及其地壳增生

通过研究南秦岭地区陡岭群、武当群和北秦岭地区秦岭群的变质基性岩等的铅同位素和微量元素组成，揭示出东秦岭造山带分布有两种性质及不同归属的元古宙地壳，指出中、古元古代时可能一个统一的地壳基底；南秦岭的中、古元古代地壳是在扬子陆地基底上通过岛弧的侧向加积形成和，北秦岭元古宙地壳则可能垂向增生于一个富入射性成因铅同位素组成的、具古洋壳幔性质的微地块之上，研究还表明陡岭群不是北秦岭地区的秦岭群，而应属于南秦     

二异氰酸酯与壳聚糖交联产物对金属离子的吸附性能

研究了二异氰酸酯与壳聚糖的交联反应,其产物与壳聚糖相比,酸溶解度由82.04％降到58.08％。DSC曲线表明,交联产物的热稳定性明显提高,对低价重金属离子(Hg     

Cs and Cl NMR spectroscopy and molecular dynamics modeling of Cs and Cl complexation with natural organic matter

Interaction of dissolved aqueous species with natural organic matter (NOM) is thought to be important in sequestering some species and enhancing the transport of others, but little is known about these interactions on a molecular scale. This paper describes a combined experimental ¹³³Cs and ³⁵Cl nuclear magnetic resonance (NMR) and computational molecular dynamics (MD) modeling study of the interaction of Cs⁺ and Cl⁻ with Suwannee River NOM. The results provide a detailed picture of the molecular-scale structure and dynamics of these interactions. Individual NOM molecules are typically hundreds to thousands of Daltons in weight, and on the molecular scale their interaction with small dissolved species can be investigated in ways similar to those used to study the interaction of dissolved aqueous species with mineral surfaces. As for such surface interactions, understanding both the structural environments and the dynamics over a wide range of frequencies is essential. The NMR results show that Cs⁺ is associated with NOM at pH values from 3.4 ± 0.5 (unbuffered Suwannee River NOM solution) to 9.0 ± 0.5. The extent of interaction increases with decreasing CsCl concentration at constant pH. It also decreases with increasing pH at constant CsCl concentration due to pH-dependent negative structural charge development on the NOM caused by progressive deprotonation of carboxylic and phenolic groups. The presence of NOM has little effect on the ¹³³Cs chemical shifts, demonstrating that its local coordination environment does not change significantly due to interaction with the NOM. Narrow, solution-like line widths indicate rapid exchange of Cs⁺ between the NOM and bulk solution at frequencies of >10² Hz. The MD simulations support these results and show that Cs⁺ is associated with the NOM principally as outer sphere complexes and that this interaction does not reduce the Cs⁺ diffusion coefficient sufficiently to cause NMR line broadening. The ³⁵Cl NMR data and the MD results are consistent in demonstrating that there is no significant complexation between Cl⁻ and NOM in the pH range investigated, consistent with negative structural charge on the NOM.