黑潮延伸体海域典型涡旋的次中尺度特征分析

本文基于卫星遥感资料和高分辨率ROMS(Regional Ocean Modeling System)数值模拟结果, 对黑潮延伸体海域典型中尺度涡旋的次中尺度特征进行了探讨。卫星观测和模拟结果显示, 黑潮延伸体涡旋海域伴随着活跃的次中尺度现象。涡旋演变与多尺度能量分析结果表明, 涡旋海域次中尺度动能的强弱与涡旋海域地转流动能有着密切联系, 锋生可能是涡旋边缘次中尺度动能增强的重要机制。次中尺度现象在中尺度涡旋海域具有沿地转流方向的复杂涡丝状结构特征, 意味着涡旋边缘较强的水平浮力梯度和地转流侧向剪切为次中尺度过程形成与发展提供了有利条件。此外, 垂向结构分析表明, 次中尺度过程能引起较大的垂向速度, 最大可达100m·day^-1, 该垂向速度可以影响至混合层下200m深度处, 对海洋内部的垂向物质能量交换、海—气相互作用等有着重要的影响。     

基于PPT战略的广东省乐昌市生态旅游扶贫模式探讨

以贫困人口受益为出发点,基于有利于贫困人口发展的旅游(Pro-Poor Tourism,PPT)战略,以广东省乐昌市为例,开展适用于中国南方林区生态旅游扶贫开发的发展模式和旅游扶贫产业的发展路径研究.结果表明:1)政府部门、旅游企业、乡村社区和非营利社会组织都应在提升贫困人口参与度、减轻贫困和生态保护方面承担责任,具体...     

1959-2003年青海省干湿变化分析

利用青海省1959-2003年气象资料,计算了修正的Palmer干旱指数,并对其进行了分析。结果表明：在青海省旱涝监测中,PDSI指数反映旱涝程度更为客观;青海省的干旱主要以轻旱为主;夏秋季年际干湿交替较冬春季频繁,变化振幅也较大;秋季青海省干旱化倾向最为严重,冬春季出现轻旱几率最大。另外,春季干旱总面积在减小;夏季轻旱面积增加,而中旱、重旱面积在减小;秋冬季重旱面积在增加。     

青海东昆仑哈陇休玛钼多金属矿床成矿流体特征及成矿模式

哈陇休玛钼多金属矿床是东昆仑成矿带东段目前仅有的中型斑岩型矿床。为了查明其成矿流体性质及成矿物质来源,构建矿床成矿模式,本文进行了详细的流体包裹体和H-O-S同位素研究。流体包裹体显微测温显示,哈陇休玛矿床发育气液两相和含CO₂三相两种类型包裹体,成矿流体呈现中高温(集中于280～340℃)、高盐度(w(NaCl),集中于6.00%～18.00%)和中等密度(集中于0.64～0.92 g/cm³)特点,成矿深度为2.4～4.1 km,形成于中浅成环境。H-O同位素显示,成矿流体具有岩浆水和大气降水混合的特征,但主体以岩浆水为主;S同位素显示,成矿物质主要来自于深部岩浆。结合区域构造演化认为,哈陇休玛矿床成矿模式为印支晚期东昆仑地区发生强烈壳幔混合作用,形成富含成矿元素的混合岩浆,含矿流体在随混合岩浆上升的过程中发生流体沸腾,并与大气降水混合冷却,导致成矿物理化学条件发生变化,促使成矿物质沉淀成矿。     

应用KDD技术分析气象地质灾害与降水的关系

应用人工智能技术——数据库中知识发现(KDD)技术,分析研究发生在云南省境内造成重大损失的气象地质灾害的发生与当日及前期降水的关系。结果表明,绝大多数气象地质灾害都是由强降水诱发的,云南气象地质灾害与发生当日及前期降水的关系主要有3种类型,即暴雨诱发型、多日中大雨诱发型和连阴雨诱发型。所得到的云南气象地质灾害与当日及前期降水的定量关系,为云南地质灾害的气象监测、预报模式的建立提供了依据。     

Cs and Cl NMR spectroscopy and molecular dynamics modeling of Cs and Cl complexation with natural organic matter

Interaction of dissolved aqueous species with natural organic matter (NOM) is thought to be important in sequestering some species and enhancing the transport of others, but little is known about these interactions on a molecular scale. This paper describes a combined experimental ¹³³Cs and ³⁵Cl nuclear magnetic resonance (NMR) and computational molecular dynamics (MD) modeling study of the interaction of Cs⁺ and Cl⁻ with Suwannee River NOM. The results provide a detailed picture of the molecular-scale structure and dynamics of these interactions. Individual NOM molecules are typically hundreds to thousands of Daltons in weight, and on the molecular scale their interaction with small dissolved species can be investigated in ways similar to those used to study the interaction of dissolved aqueous species with mineral surfaces. As for such surface interactions, understanding both the structural environments and the dynamics over a wide range of frequencies is essential. The NMR results show that Cs⁺ is associated with NOM at pH values from 3.4 ± 0.5 (unbuffered Suwannee River NOM solution) to 9.0 ± 0.5. The extent of interaction increases with decreasing CsCl concentration at constant pH. It also decreases with increasing pH at constant CsCl concentration due to pH-dependent negative structural charge development on the NOM caused by progressive deprotonation of carboxylic and phenolic groups. The presence of NOM has little effect on the ¹³³Cs chemical shifts, demonstrating that its local coordination environment does not change significantly due to interaction with the NOM. Narrow, solution-like line widths indicate rapid exchange of Cs⁺ between the NOM and bulk solution at frequencies of >10² Hz. The MD simulations support these results and show that Cs⁺ is associated with the NOM principally as outer sphere complexes and that this interaction does not reduce the Cs⁺ diffusion coefficient sufficiently to cause NMR line broadening. The ³⁵Cl NMR data and the MD results are consistent in demonstrating that there is no significant complexation between Cl⁻ and NOM in the pH range investigated, consistent with negative structural charge on the NOM.     

二异氰酸酯与壳聚糖交联产物对金属离子的吸附性能

研究了二异氰酸酯与壳聚糖的交联反应,其产物与壳聚糖相比,酸溶解度由82.04％降到58.08％。DSC曲线表明,交联产物的热稳定性明显提高,对低价重金属离子(Hg     

潜水的降雨入渗补给模型研究

根据土水势能原理,在试验、监测资料基础上,建立活塞武、扩散式两种入渗补给模型和单一入渗、单一蒸发及入渗蒸发三个子模型,与此相应地建立了积水模型法,表面通量法,毛细带上缘通量法和零通量面法的数学模型,描述入渗补给的时、空变化过程,计算降雨入渗补给量,从土水势能观点提出降雨入渗补给的物理机制,并在实际应用中得到了证实。     

Helium and argon isotope geochemistry of natural gases in China’s petroliferous basins

The age-accumulation effect of 40Ar in hydrocarbon source rocks was discussed in accordance with the decay law of radioactive elements. In terms of the mean values of 40Ar/36Ar, the old Sinian gas reservoirs (mean values of 40Ar/36Ar: 7009) were definitely distinguished from the Permian gas reservoirs (mean values of 40Ar/36Ar: 1017) in Weiyuan, Sichuan Province, and the gas source of the Permian gas reservoir (mean values of 40Ar/36Ar: 5222) in well Wei-7 with the Weiyuan structure is defined as the Sinian system. Based on the values of 40Ar/36Ar, the coal-type gases (The source rocks are of the C-P system; mean values of 40Ar/36Ar: 1125) are definitely distinguished from the oil-type gases (The source rocks are of the Tertiary system; mean values of 40Ar/36Ar: 590) in the Tertiary reservoirs of the Zhongyuan Oilfield. Besides, 40Ar/36Ar values also have a positive effect on the oil-source correlation of oil reservoirs in ancient hidden mountains. According to the crust-mantle interchange information reflected by 3He/4He values, petroliferous provinces in China can be divided into three major tectonic regions. (1) The eastern active region: The crust-mantle volatile matter exchanges actively, and the 3He/4He values are mainly around 10-6, partly around 10-7. (2) The central stable region: The 3He/4He values are all around 10-8. (3) The western sub-stable region: The 3He/4He values are mainly around 10-8, and around 10-7 on the edges of the basins. Helium contents of some gas wells in China’s eastern petroliferous region reach the industrial abundance (He≈0.05%–0.1%), the 3He/4He values reach 10-6, and the equivalent values for the mantle-source components in helium gas can reach 30%–50%. As viewed from this, a new type of crust-mantle composite helium resources has been proposed. Geneses of some CO2 gas reservoirs in the east of China and some issues concerning mantle-source methane were discussed in the light of the helium and carbon isotopes of CO2 and CH4 in natural gases. In the discussion on helium isotopic characteristics of inclusions in the reservoirs, it was discovered that the 3He/4He values are close to those in natural gases. That is to say, this phenomenon is related to regional tectonism. The 3He/4He, CO2/3He and CH4/3He data were used to discuss the tectonic activities of fault zones in a certain number of regions in China.     

Heavy metals pollution on the sediments in lakes Dianchi, Erhai and Poyanghu and historical records

In this paper²¹⁰ Pb and ¹³⁷Cs dating methods were used to determine sedimentation rates of lakes Dianchi, Erhai and Poyanghu, and to establish the time scale of the sediments. Also based on geochemical records in the sediment column, the historical variation in heavy metal content over the past one hundred years was determined. Some element concentration increased rapidly after the 1970s, such as Cu, Zn and Mn in the sediments of northern Lake Dianchi, Cd and Mn in southern Lake Erhai and in the west central parts of Lake Poyanghu, Our investigations indicate that the increase in element concentration is caused by human activities. In order to understand the extent of the effect caused by human activities, we have calculated the flux of Zn, Cd and Mn. Results show that the flux caused by human activities is seven times greater than the natural one and the ratio is about 2 times in Lake Erhai and Lake Poyanghu.