江西永平铜矿区古构造应力场与构造演化

利用多重反演方法(Multiple Inverse Method,MIM)恢复永平铜矿多期古构造应力场,该方法可以划分形成断层擦痕的多个古构造应力期次.研究表明,永平矿区印支期以来至少受到3期古构造应力场作用,进而探讨了永平铜矿构造演化历史.第一期构造应力场为EW方向的近水平挤压,形成轴向近SN的褶皱,以及走向近南北的逆断层;第二期构造应力场为NW-SE方向近水平挤压,伴随着岩体的侵入,导致层间破碎带的矽卡岩化和矿体形成;第三期构造应力场为EW方向的再次挤压作用,造成控矿断层推覆距离加大,混合岩和矽卡岩破碎带向西逆冲推覆到晚古生代地层之上.     

Hydromechanical behavior of unsaturated soil with different initial densities over a wide suction range

Acta Geotechnica - Many civil engineering projects are related to hydromechanical behavior of unsaturated soils over a wide suction range, which was investigated by imposing suctions on clayey silt...     

CCSD在线流体监测捕获的气体地球化学异常与2004年9．3级苏门答腊地震可能的超远程关系

中国大陆科学钻探工程在线流体地球化学监测在2004年12月10至2005年1月10日之间捕获到一段重要的气体地球化学异常。该异常从2004年12月24日晚上11点半开始到12月29日晚上7点半结束,其中在12月26日早上7点半到29日晚7点半这段异常非常特殊,表现出流体地球化学的剧烈变化。具体表现为流体组分从基本上不含Ar、He及N2跳跃到富含Ar、但亏损He和N2。该异常发生在2004年9.3级苏门答腊地震前1个半小时。由于CCSD现场离苏门答腊地震震中距离大于4170公里,大于该地震破裂长度1200公理的3倍,该地震在CCSD现场产生的静态应力变化微乎其微,不足以导致CCSD现场深部岩石或封闭破裂的岩石物理性质剧烈变化,因而可以排除静态激发效应的作用。在我国的云南和广东等地所观测到的地震异常和地下水位变化等表明2004年苏门答腊地震的动态激发效应主要沿东北方向,这和大地震的动态激发具有方向性一致。而CCSD现场就位于该方向上。我们推测2004年苏门答腊地震所产生的面波在CCSD现场激发的动态效应,导致库仑型失稳,增进深部岩石或破裂带的渗透率,释放富含Ar但亏损He和N2的流体,产生CCSD所观测到的气体异常。     

Relationship Between Permeability and Strain of Sandstone During the Process of Deformation and Failure

The permeability of the rock specimen during the process of deformation and failure is a dynamic evolution, and it relates with the growth and coalesces of micro-cracks within the rock. Although extensive researches have been conducted on the relationship between the stress–strain and the permeability, the deformation of the specimen should be taken into account for the evaluation of the permeability. In this study, experiments on the hydro-mechanical coupling of sandstone are carried out. Change of the permeability with the axial, lateral and volumetric strains is investigated. The experimental results show that the change of the permeability during the process of deformation and failure has apparent phases, and the evolution of the permeability is closely correlated with the strain. According to the experimental data, two kinds of empirical equations are fitted to better describe the relationship between the permeability and the strain. One is the polynomial equation used to simulate the phase of compression of rock specimens, the other is exponential equation used to simulate the rest of deformation phases. The obtained equations are just the empirical ones for the sandstone and are not for the universal application.     

Dissolution kinetics of calcite at 50-70 °C: An atomic force microscopic study under near-equilibrium conditions

Direct measurements of calcite faces were performed using in situ atomic force microscopy (AFM) to reveal the dissolution processes as a function of solution saturation state and temperature. Time-sequential AFM images demonstrated that step velocities at constant temperature increased with increasing undersaturation. The anisotropy of obtuse and acute step velocities appeared to become more significant as solutions approached equilibrium and temperature increased. At saturation state Ω > 0.02, a curvilinear boundary was formed at the intersection of two acute steps and the initially rhombohedral etch pit exhibited a nearly triangular shape. This suggests that the and steps may not belong to the calcite-aqueous solution equilibrium system. Further increase in the saturation state (Ω ? 0.3) led to a lack of etch pit formation and dissolution primarily occurred at existing steps, in accordance with Teng (2004). Analysis of step kinetics at different temperatures yielded activation energies of 25 ± 6 kJ/mol and 14 ± 13 kJ/mol for obtuse and acute steps, respectively. The inconsistencies in etch pit morphology, step anisotropy, and step activation energies from the present study with those of studies far-from-equilibrium can be explained by increased influence of the backward reaction, or growth, near-equilibrium. We propose that the backward reaction occurs preferentially at the acute-acute kink sites. The kinetics and effective activation energies of near-equilibrium calcite dissolution presented in this work provide accurate experimental data under likely CO₂ sequestration conditions, and thus are crucial to the development of robust geochemical models that predict the long-term performance of mineral-trapped CO₂.     

平庄盆地六家立井地区找铀目标层岩石学特征及其找矿意义

六家立井地区位于平庄盆地北缘,白垩系下统阜新组上段是该区砂岩型铀矿床目标层位,具有较好找铀前景。为深入了解该区砂体的岩石学特征,通过野外钻探工作、岩心编录、样品采集及岩矿测试方法,详细研究了目标层碎屑岩类型、碎屑岩成分、结构构造等岩石学方面特征。结果表明目标层碎屑岩成分成熟度和结构成熟度均较低,具有搬运距离短、沉积速度快的特点,其物源较单一,初步判断物源来自盆地东北部和西北部隆起带酸性花岗岩,同时也为铀成矿提供了良好的铀源。     

分形几何用于岩石损伤扩展过程的研究

通过对岩石损伤扩展机理的研究，运用分形几何理论，建立了岩石损伤变量ω与分形维数之间关系。     

Leaching of manganese residue for the preparation of trimanganese tetroxide with a high surface area

The accumulation of electrolytic manganese residue (EMR) has become a serious problem and its recycling will be of great benefit to protect the environment and assist sustainable development. The reusing method was conducted by leaching EMR with sulfuric acid and the optimal leaching condition was 1:3 (g/g) as the ratio of solid to liquid with 20% (g/g) H2SO4 , heating at 90 ℃ for 3 hours, which aims at extracting Mn in a sulfuric acid medium. The produced MnSO4 solution was precipitated by adding alkali and oxidized in aqueous phase. The oxidized products were characterized by various techniques, including X-ray powder diffraction (XRD), Fourier transform infrared (IR) spectrometry, vibrating sample magnetometry (VSM), with Brunauer-Emmett-Teller (BET) specific surface area instrument and laser particle size analyzer. The final products were confirmed to be a single-phase Mn3O4 .     

Ultramafic Blocks in Sumdo Region, Lhasa Block, Eastern Tibet Plateau: An Ophiolite Unit

Recently, an over 100 kin long MORB-type eclogite belt of Permian was discovered in the Sumdo (松多) region of the Lhasa block, Tibet. A critical question thus is: what is the tectonic setting of the eclogite belt and is it related to an unrecognized suture in the region? Further investigations show that there are some mafic and ultramafic rocks spatially associated with the eclogite belt in the region. Three ultramafic massifs were recognized in the Sumdo region, and called the Luomaling (罗马岭),Gongbupala (贡布爬拉) and Qiazhasumdo (卡扎松多) massifs. All the massifs are fault-contacted with greenschist (Chasagang (岔萨岗) Formation) or muscovite-quartz schist (Mabuku (马布库) Formation), and individuals are about 100 m×50 m in size extending in EW as the regional structure. All the ultramafic rocks have been entirely serpentinized, and the Gongbupala massif has been selected for study in geochemistry. Eleven chemical analyses of the rocks from the Gongbupala massif show a narrow range in contents: SiO2(35.97-40.63) wt.%, MgO (37.02-38.60) wt.%, TiO2(0.01-0.08) wt.%, Al2O3 (0.80-1.64) wt.%, (Na2O+K2O) less than 0.1 wt.%, with high volatile contents (H2O+CO2) (11.24-14.91) wt.%. After recalculation without H2O+CO2, the mean values are SiO2 45.24 wt.%, MgO 43.54 wt.%, FeOT(7.45-9.97) wt.% (8.55 wt.% in average), (MgO+FeOT) 52.09 wt.%, Mg# (100×Mg/(Mg+Fe*), where Fe* represents total Fe)=89.42-90.08, (m+f)/Si ((atomicity Mg+atomicity Fe) /atomicity Si)=1.53-1.75 (1.59 in average), respectively. The mean M/F (atomicity Mg/atomicity Fe) ratio of the rocks is 9.05, which is classified as magnesium enriched-type of ultramafic rocks. The compositional features, depleted in K, Na, Ca, Al and Ti and enriched in Mg#, indicate the characteristics of peridotite originated from a depleted mantle. The rocks have low ∑ REE with (1.60-2.68)×10-6 similar to those of the primitive mantle. The chondrite-normalized REE patterns of all samples show slightly enrichment in LREE, with (Ce/Yb)N 1.03-2.46, but a little depleted in HREE. Most samples show a slight negative anomaly in Eu, a feature In REE from a relic mantle and common features In highly serpentinized ultramafic rocks in the Yarlung-Zangbo (雅鲁藏布) ophiolite and the Bangong (班公)-Nnjiang (怒江)ophiolite in Tibet. The primitive mantle-normalized spiderdiagram of trace elements for Gongbupala ultramafic rocks yields uniform distributed pattern. They are relatively enriched in Rb, Ba, La, P element (LHSE) and depleted in Sin, Ti, Y, Yb element (HFSE), a feature of metasomatic mantle peridotite. The geochemical features of the rocks suggest that the protofith of Gongbupala serpentinite in Sumdo region is harzburgite, a typical depleted mantle rock, and may represent a dismembered ophiolite unit in the region.