Petrology and geochemistry of eclogite xenoliths from the Rietfontein kimberlite,Northern Cape,South Africa

Petrographic and geochemical features of a suite of eclogite xenoliths from the Rietfontein kimberlite that erupted through probable Proterozoic crust west of the Kaapvaal Craton in the far Northern Cape region of South Africa, are described. Group II eclogites dominate the suite both texturally and chemically, but can be subdivided into bimineralic, opx-bearing and kyanite-bearing groups. Temperature estimates from different geothermometers range from 700 to 1,000°C, indicating derivation from relatively shallow mantle depths. Orthopyroxene-bearing eclogites are inferred to originate from depths of 85 to 115 km and lie close to the average cratonic thermal profile for southern Africa. These uppermost mantle temperatures during the late Cretaceous provide evidence for equilibration of the off-craton lithosphere to craton-like thermal conditions following Namaqua-Natal orogenesis. The kyanite eclogites are distinct from the remaining eclogites in terms of both major and trace element compositions and their lesser degree of alteration. Garnets are richer in Ca, and are Cr-depleted relative to garnets from the bimineralic and opx-bearing eclogites, which tend to be more magnesian. Clinopyroxenes from the kyanite eclogites are more sodic, with higher Al₂O₃ and lower MgO contents than the bimineralic and opx-bearing eclogites. LREE-depletion, positive Sr and Eu anomalies, and the Al-rich, Si-poor bulk composition suggest a plagioclase-rich, probably troctolitic protolith for the kyanite eclogites. In contrast, the major and trace element bulk compositions of the high-MgO bimineralic and orthopyroxene-bearing eclogites are consistent with gabbroic or pyroxenitic precursors, or high-pressure cumulates, rather than mafic to ultramafic lavas. δ¹⁸O values for garnets do not deviate significantly from typical mantle values. The observations reported do not discriminate unambiguously between continental and oceanic origins for the various eclogite components in the mantle lithosphere of this region.     

Environmental impact assessment of risk associated with groundwater overdraft remediation in cone of depression,Jining, China

In this paper, a simple scenario and probabilistic approach is used to assess the potential groundwater risk due to proposed overdraft remedial actions in cone of depression, Jining City, China. Focusing on the concentrations of Chloride ions (Cl⁻) and total hardness (TH), the impact of artificial recharge and reduced pumping on groundwater quality and quantity is analysed by using the three-dimensional finite difference groundwater flow and transport model, Visual MODFLOW, to simulate groundwater flow and transport within the study area based on scenarios, and utilizes SURFER software to map risk levels. Although 5, 10 or 15% reduced pumping with artificial recharge leads to more decrease in Cl⁻ and TH concentrations than the 25%, less volume increase is achieved for the remediation of land subsidence and other environmental problems in the cone of depression. The Cl⁻ concentrations in recovered groundwater are within the desired concentration of 200 mg/l; however, TH in some cases are above the maximum permissible limit of 500 mg/l, with an exceedence probability of about 0.67 for recharge and recharge with reduced pumping at 25%. The presence of fractures and hydrogeological complexity greatly determines impacts of remediation, and the 22% reduced pumping with artificial recharge offers an optimum strategy for overdraft remediation in the Jining cone of depression.     

Lamproitic Rocks from a Continental Collision Zone: Evidence for Recycling of Subducted Tethyan Oceanic Sediments in the Mantle Beneath Southern Tibet

Major and trace element, Sr–Nd–Pb isotope and mineralchemical data are presented for newly discovered ultrapotassiclavas in the Tangra Yumco–Xuruco graben in southern Tibet.The ultrapotassic lavas are characterized by high MgO, K₂O andTiO₂, low Al₂O₃ and Na₂O contents, and also have high molarK₂O/Al₂O₃, molar (K₂O + Na₂O)/Al₂O₃ and K₂O/Na₂O ratios. Theirhigh abundances of incompatible trace elements such as largeion lithophile elements (LILE) and light rare earth elements(LREE) reach the extreme levels typical of lamproites. The lamproitesshow highly radiogenic ⁸⁷Sr/⁸⁶Sr (0· 7166–0·7363) and unradiogenic ¹⁴³Nd/¹⁴⁴Nd (0· 511796–0·511962), low ²⁰⁶Pb/²⁰⁴Pb (18· 459–18· 931),and elevated radiogenic ²⁰⁷Pb/²⁰⁴Pb (15· 6732–15·841) and ²⁰⁸Pb/²⁰⁴Pb (39· 557–40· 058) ratios.On the basis of their geochemical and isotopic systematics,the lamproites in south Tibet have a distinct magma source thatcan be differentiated from the sources of potassic lavas inthe east Lhasa and Qiangtang blocks. Their high Nb/Ta ratios(17· 10–19· 84), extremely high Th/U ratios(5· 70–13· 74) and distinctive isotope compositionsare compatible with a veined mantle source consisting of partialmelts of subducted Tethyan oceanic sediments and sub-continentallithospheric depleted mantle. Identification of the lamproitesand the delineation of their mantle source provide new evidencerelevant for models of the uplift and extension of the Tibetanplateau following the Indo-Asia collision. Metasomatism by partialmelts from isotopically evolved, old sediment subducted on theyoung Tethyan slab is an alternative explanation for PrecambrianNd and Pb model ages. In this model, differences in isotopiccomposition along-strike are attributed to differences in thetype of sediment being subducted, thus obviating the need formultiple metasomatic events over hundreds of million years.The distribution of lamproites, restricted within a north–south-trendinggraben, indicates that the initiation of east–west extensionin south Tibet started at 25 Ma. KEY WORDS: lamproites; subducted oceanic sediment; Tibetan active continental collision belt     

Pedotransfer functions to estimate soil water content at field capacity and permanent wilting point in hot Arid Western India

Characterization of soil water retention, e.g., water content at field capacity (FC) and permanent wilting point (PWP) over a landscape plays a key role in efficient utilization of available scarce water resources in dry land agriculture; however, direct measurement thereof for multiple locations in the field is not always feasible. Therefore, pedotransfer functions (PTFs) were developed to estimate soil water retention at FC and PWP for dryland soils of India. A soil database available for Arid Western India (N=370) was used to develop PTFs. The developed PTFs were tested in two independent datasets from arid regions of India (N=36) and an arid region of USA (N=1789). While testing these PTFs using independent data from India, root mean square error (RMSE) was found to be 2.65 and 1.08 for FC and PWP, respectively, whereas for most of the tested ‘established’ PTFs, the RMSE was >3.41 and >1.15, respectively. Performance of the developed PTFs from the independent dataset from USA was comparable with estimates derived from ‘established’ PTFs. For wide applicability of the developed PTFs, a user-friendly soil moisture calculator was developed. The PTFs developed in this study may be quite useful to farmers for scheduling irrigation water as per soil type.     

湖北赤壁二叠纪一三叠纪之交古海洋沉积环境演化

晚二叠世时,湖北赤壁位于扬子台地与北部硅质岩盆地的过渡地带.特殊的古地理位置,使该地区发育一套独特的地层 沉积序列.沉积微相、古生物化石和草莓状黄铁矿的综合研究表明,晚二叠世长兴期至早三叠世早期,赤壁剖面沉积环境演化 可分为6个阶段:近氧化的深水台缘硅质岩沉积、含氧量正常的台缘缓坡沉积、火山活动加剧而含氧量正常的台缘缓坡沉积、 大灭绝后严重缺氧环境的沉积、大灭绝后贫氧环境下的沉积、大灭绝后氧化环境的沉积.由于赤壁剖面处在远离陆地的台缘缓 坡环境,陆源剥蚀的影响可能比较有限,因此火山作用带来的营养物质可能是引起大灭绝后海洋缺氧的主要原因.      

Hybridization of the probability perturbation method with gradient information

Geostatistically based history-matching methods make it possible to devise history-matching strategies that will honor geologic knowledge about the reservoir. However, the performance of these methods is known to be impeded by slow convergence rates resulting from the stochastic nature of the algorithm. It is the purpose of this paper to introduce a method that integrates qualitative gradient information into the probability perturbation method to improve convergence. The potential of the proposed method is demonstrated on a synthetic history-matching example. The results indicate that inclusion of qualitative gradient information improves the performance of the probability perturbation method.     

A coupling of mixed and continuous Galerkin finite element methods for poroelasticity II: the discrete-in-time case

In this paper, we formulate a finite element procedure for approximating the coupled fluid and mechanics in Biot’s consolidation model of poroelasticity. Here, we approximate the pressure by a mixed finite element method and the displacements by a Galerkin method. Theoretical convergence error estimates are derived in a discrete-in-time setting. Of particular interest is the case when the lowest-order Raviart–Thomas approximating space or cell-centered finite differences are used in the mixed formulation and continuous piecewise linear approximations are used for displacements. This approach appears to be the one most frequently applied to existing reservoir engineering simulators.     

Irrigated area determination: a case study in the Province of San Juan,Argentina

Much of the central-western region of Argentina, where San Juan Province is located, experiences arid to semi-arid climatic conditions with low average annual rainfall accompanied by substantial evapotranspiration. Consequently, a viable crop industry depends to a large extent upon irrigation from major river systems. Increasing demand for water in the lower basin of the San Juan River is emphasizing the need for more accurate estimates of water used for irrigation. Since the water demand for a particular crop is very closely related to crop area, monitoring the area of crop under irrigation is considered a proxy for the amount of water used. Landsat 5 imagery for the growing season, field data and aerial photographs were used to evaluate crop area.     

Speciation and potential remobilization of heavy metals in sediments of the Taihu Lake, China

The species of Cu, Pb, Zn, Cd and Cr in sediments of the Taihu Lake, China, have been analyzed using the sequential chemical extraction method. Variations in the chemical fractions of these metals and their geographic distributions have also been studied. For all five metals, the residual fraction is highest but the exchangeable fraction is lowest among all the fractions. Compared to other metals, Cd has the highest percentage in the exchangeable fraction, and Cr is associated mainly with the residual fraction. Cu in the organic fraction and Pb in the Fe-Mn fraction are the important species, whereas the lowest percentages are found for Cd in the organic fraction, Cu in the Fe-Mn oxide fraction and Pb in the carbonate fraction. With respect to spatial differences, the total contents in the non-residual fractions of the metals in bay sediments are found to be higher than those in other sediments. The fractions of Cd, Cu and Cr showed significant variations in different regions. The fractions of Pb and Zn, however, did not show significant variations in spatial distribution, suggesting different amounts and different paths of anthropogenic input for the metals. Comparisons of the metal speciation indicated that Cd might be the most bioavailable metal, followed by Pb.     

吉林省永吉县倒木河地区地球化学特征及找矿前景

对永吉县倒木河地区的1∶ 1万土壤地球化学测量成果进行了研究.结合成矿地质背景,圈定化探综合异常32处.通过地表揭露,在Ht-23、Ht-26、Ht-30三个异常中发现了 2条金矿化体,3条砷金矿(化)体,预示了工作区良好的找矿前景.