Geochemical Characteristics and Tectonic Significance of Aoyougou Group Basalts in Western North Qilian

The North Qilian orogenic belt is a typical plate suture zone, which is studded with numerous different sizes of fragments of micro-continental crust consisting of pre-Sinian metamorphic rocks and the North Qilian orogenic belt provides important study carrier for studying the pre-orogenic tectonic process of the North Qilian. The relatively complete volcanic-clastic-carbonate rocks formation of Zhulongguan Group, Changchengian System, Mesoproterozoic are distributed in the Kawa-Qiqing area, Western North Qilian orogenic belt. Geochemical characteristics of the Aoyougou Group basalts in the North Qilian indicated that the contents of major element were relatively stable, high K₂O contents(4.27%~6.07%), TFe₂O₃(10.49%~13.01%),TiO₂(1.96%~2.90%)and middle MgO(5.37%~6.71%,Mg^# 48~51), CaO(2.57%~5.51%)content. Thus, the Aoyougou Group basalts belong to potassium alkaline basalt. The contents of Cr and Ni of the basalts decreased with the decreasing of Mg^#, and there was a positive correlation between CaO and CaO/Al₂O₃, Furthermore, the Eu anomaly of samples was slightly negative, high contents of high field strength elements (HFSE, Nb, Ta, Ti), and the ratios of Gd/Yb(2.5~3.0), Zr/Y(8.6~10.2), Ta/Yb(0.96~1.23), Ti/Yb(5 074~6 021), Zr/Yb(81~97), Ce/Nb(1.87), Zr/Nb(6.41)indicated that the Aoyougou Group basalts had obvious OIB-type magmatic affinity. In combination with the regional geological background, the study results showed that Aoyougou Group alkaline basalt generated from deep enrichment mantle similar to the source of OIB, with fractional crystallization of olivine and monoclinic pyroxene and a certain degree of contamination of continental crust in the process of magmatism, formed in the background of continental rift, might response to the Proterozoic Columbia supercontinent rifting, which further provides important petrological evidences for the relationship between North China Craton rifting events and Columbia supercontinent rifting during Proterozoic.     

GEOCHRONOLOGICAL LIMITATIONS FOR INTERPRETING THE PALEOCLIMATIC HISTORY OF THE TIBETAN PLATEAU

在当前全球变化背景下,青藏高原冰川急剧退缩严重影响着东亚地区水资源.为了有效地规划水资源,需要对高原气候变化及其机制有深入的理解.尽管在青藏高原及周边地区有大量的古气候记录,但是目前对高原气候的时空变化及其机制仍缺乏深入一致的认识.青藏高原冰川、树轮和石笋记录可以提供过去气候变化的框架,但是这些记录的分布局限于一些特定的地理区域.青藏高原上广泛分布的湖泊沉积物是研究高原气候的时空变化及其机制的优良介质.湖泊沉积物岩芯的年龄控制主要依赖于放射性碳同位素定年,但大多数高原湖泊具有碳库效应,为建立沉积岩芯年代控制需要进行碳库年龄校正所带来的年龄误差目前未有深入研究,这在某种程度上制约了利用湖泊沉积物记录研究高原气候时空变化及其机制.本文比较了目前确定高原湖泊碳库年龄的方法并提出建议采用的方法,汇总目前己发表的高原湖泊碳库年龄,讨论湖泊现代碳库年龄的空间分布及其影响因素,讨论湖泊碳库过去变化及其可能造成的岩芯年代控制误差;以青海湖和班公错两个高原湖泊已发表的记录为例讨论过去碳库年龄变化可能造成对记录完全不同的解释;还讨论了由碳库效应校正而带来的湖泊沉积物岩芯年龄控制误差对青藏高原湖泊记录的末次盛冰期终止年代的空间分布及其对变化机制解释的影响.如果考虑碳库效应的过去变化,目前所观测到的高原气候时空变化及其机制需要重新解释.因此,为了更好地理解青藏高原气候时空变化及其机制,我们需要更多有良好定年、高分辨率和定量化的湖泊记录,本文也建议在解释目前湖泊记录时需要应对年龄控制极大重视.     

渤海—鲁西地区白垩-早第三纪裂谷活动——火山岩的地球化学证据

渤海—鲁西地区的白垩早第三纪火山岩在渤海东部主要沿郯庐断裂带呈北北东向分布,在渤海西部和鲁西地区主要沿北西向断裂带分布。白垩纪火山岩以安山岩类为主,早第三纪以玄武岩类为主,玄武岩浆源于富集型地幔,即富集轻稀土和大离子亲石元素,但明显亏损Yb、Ni和Cr等元素。火山岩的Sr和Nd同位素初始比值结果表明白垩纪的火山岩来源于Ⅱ型富集地幔,而早第三纪火山岩来源于接近原始地幔的略富集型地幔。这可能由于早第三纪岩石圈大规模伸展减薄,致使上地幔深部的亏损型物质上涌参与岩浆活动,与富集型地幔混染的结果。     

黔西南白层超基性岩墙锆石SHRIMP U-Pb年龄和Hf同位素组成研究

文章对黔西南白层地区出露的燕山期超基性岩墙进行了单颗粒锆石SHRIMP U-Pb年龄和Hf同位素组成研究,获得A、B两组不同的锆石年龄.A组锆石呈不规则粒状,具不完整的宽大条带,12颗锆石的 SHRIMP U-Pb年龄加权平均值为(84±1)Ma,代表了超基性岩墙的侵位年龄;锆石Hf原位分析表明,176Hf/177Hf从0.282561到0282719,εHf(84 Ma)平均为-3.61,表明岩浆源区主要以富集地幔为主,并受到部分地壳物质的混染.B组锆石晶形完整,具典型的中酸性岩浆型振荡环带,3颗锆石的SHRIMP U-Pb模式年龄为409～450 Ma.176Hf/177Hf从0282379到0282440,εHf(t)平均为-3.77,均低于A组锆石,属于捕获锆石.据此认为84 Ma左右由于华南岩石圈伸展,软流圈地幔上涌,导致岩石圈富集地幔部分熔融,熔体上升过程中与409～450 Ma左右形成的少量地壳岩石发生混染,随后快速侵位冷凝而形成基性-超基性岩墙.白层地区84 Ma的超基性岩浆活动是整个华南西部燕山晚期(80～90 Ma)岩浆活动的一部分.右江褶皱带周缘的燕山晚期岩浆活动主要与大规模的Sn、W、Ag、Cu、Pb、Zn等矿床有关,但右江褶皱带内部的燕山晚期岩浆活动是否与以卡林型金矿为代表的低温热液矿床有成因上的联系,尚需更多矿床年代学资料的证实.     

西天山伊宁地块主褶皱幕鄯善运动的确立及地质意义

地层不整合接触是研究地质发展历史及鉴定地壳运动特征和运动时期的重要依据,主褶皱幕是一造山带多幕构造运动中起决定性作用和最为重要的一次构造运动。天山的构造运动幕次多且因地而异,前人认识多有分歧,也没有确立主褶皱幕。伊宁地块伊什基里克山一带上、下石炭统之间为角度不整合接触关系,在岩石组合、沉积环境、古生物地理区系、构造样式、区域大地构造背景等方面差异最为显著,凸显了鄯善运动对区内构造格架和盆山演化起到决定性的作用,因而是主褶皱幕。鄯善运动记录了西天山沟—弧—盆格局消亡,天山残余小洋盆终结,塔里木板块和准噶尔板块最终拼合在一起,形成了统一大陆的重要演化信息。     

东昆仑东段中更新世以来的成山作用及其动力转换

对东昆仑造山带东段第四纪构造及与地貌关系的分析表明，现代山盆相间的地貌格局成型于中更新世，且在中更新世以来发生了多次构造变形体制的转换。根据布青山北部查干额热格地区第四系剖面的构造、地层时代及地层与构造关系的分析表明，中更新世时期为伸展构造体制，昆仑山内部开始发生了差异隆升，布青山开始崛起。中更新世末应力体制发生急剧变化，由伸展体制转为收缩事件，又急速转为伸展构造体系，短暂的收缩事件造成了中更新世冲洪积层的褶皱，随后的伸展则导致了影响深刻的向北依次断落的阶地状正断层系统。晚更新世应力体系再度发生重大转换，伸展正断层体系被左旋走滑运动体系所代替，并一直延续至今。中更新世以来多次隆升构造变形体制的转换说明东昆仑地区的成山过程受控于多种动力背景，而非单一的挤压抬升。隆升构造变形体系的确定及其时代约束为深入刻划青藏高原东北缘隆升作用的动力过程提供了重要信息。     

Surface analysis of pyrite in the No. 9 coal seam, Wuda Coalfield, Inner Mongolia, China, using high-resolution time-of-flight secondary ion mass-spectrometry

The chemical composition of pyrite in coal can be used to investigate its geological and mineralogical origin. In this paper, high-resolution time-of-flight secondary ion mass spectrometry (TOF-SIMS) was used to study the chemical composition of various pyrite forms in the No. 9 coal seam (S_t,d=3.46%) from the Wuda Coalfield, Inner Mongolia, northern China. These include bacteriogenic, framboidal, massive, cell-filling, fracture-filling, and nodular pyrites. In addition to Fe⁺ (⁵⁴Fe⁺, ⁵⁶Fe⁺, ⁵⁷Fe⁺), other fragment ions were detected in bacteriogenic pyrites, such as ²⁷Al⁺, Si⁺ (²⁸Si⁺, ²⁹Si⁺, ³⁰Si⁺), ⁴⁰Ca⁺, Cu⁺ (⁶³Cu⁺, ⁶⁵Cu⁺), Zn⁺ (⁶⁴Zn⁺, ⁶⁶Zn⁺, ⁶⁷Zn⁺, ⁶⁸Zn⁺), Ni⁺ (⁵⁸Ni⁺, ⁶⁰Ni⁺, ⁶²Ni⁺), and C₃H₇⁺. TOF-SIMS images show bacteriogenic pyrites are relatively rich in Cu, Zn, and Ni, suggesting that bacteria probably play an important role in the enrichment of Cu, Zn, and Ni during their formation. Intense positive secondary ion fragments from framboidal aggregates, such as ²⁷Al⁺, ²⁸Si⁺, ²⁹Si⁺, AlO⁺, CH₂⁺, C₃H₃⁺, C₃H₅⁺, and C₄H₇⁺, indicate that formation of the framboidal aggregates may have occurred together with clay mineral and organic matter, which probably serve as the binding substance. The intense ions of ²⁸Si⁺ and ²⁷Al⁺ from massive pyrites also suggest that their pores incorporated clay minerals during crystallization. Together with the lowest ²⁸Si⁺/²³Na⁺ value, the intense organic positive secondary ion peaks from cell-filling pyrites, such as C₃H₃⁺, C₃H₅⁺, C₃H₇⁺, and C₄H₇⁺, indicate that pyrite formation may have accompanied dissolution or disintegration of the cell. The intense P⁺ peak was observed only in the fracture-filling pyrite and the highest ²⁸Si⁺/²³Na⁺ value of fracture-filling pyrite reflects its epigenetic origin. Together with XRD and REEs data, the stronger ⁴⁰Ca⁺ in nodular pyrite than other pyrite forms shows seawater influence during its formation.     

吉林六批叶沟金矿床绢云母40Ar-39Ar 快中子活化法定年研究

在六批叶沟金矿石中,精选出与金矿物同期生成的绢云母作为样品,采用40Ar-39Ar快中子活化法测年,获得8个一致相连的平坦型绢云母年龄谱,tp=(190.28±0.30) Ma,氩同位素计算得等时线年龄为(189.98±0.58) Ma,两者完全吻合.等时线截距为(296.9±10.0) Ma,与大气氩的该值(295.5 Ma)相比较,两者完全吻合,表明该样品出自未受明显后期热力作用影响的非扰动体系.锁定六批叶沟金矿床主要成矿年龄为190 Ma左右,属早侏罗世的燕山早期.     

安徽峙门口铜—铁—金—硫矿床地球化学特征

峙门口铜—铁—金—硫矿床发育上部层状矿体和下部脉状矿体。上部层状矿石重晶石的δ~(34)S值为+14.10‰～+18.90‰。上部层状矿石黄铁矿和方铅矿的δ~(34)S值为+3.50‰～+5.84‰,下部脉状矿石黄铁矿的δ~(34)S值为+4.80‰～+6.80‰。下部脉状矿石中脉石英的δ~(18)O值为+14.3‰～+1 8.5‰,δ~(30)Si值为-0.3%0～-0.2‰。下部脉状矿石黄铁矿Re/Os比值为78.342～175.540,上(顶)部层状矿石中黄铁矿Re/Os比值为62.298～169.545。从下部脉状矿石到上部层状矿石,δ~(34)S值、Re/Os比值和流体包裹体温度249 ℃→97 ℃逐渐降低,~(206)Pb/~(204)Pb、~(207)Pb/~(204)Pb、~(208)Pb/~(204)Pb平均值和Os_总、Re、~(187)Re等含量逐渐增高。矿石黄铁矿Re-Os同位素等时线年龄303±33 Ma。地质地球化学特征反映峙门口铜—铁—金—硫矿床为海底热水喷流沉积成因。     

青海湖沉积物生物硅的环境意义初步研究

湖泊沉积物中生物硅含量的变化已经被广泛应用于评价湖泊生产力和古气候变化研究,但大型湖泊不同位置生物硅含量的时空变化及其与环境要素之间的关系仍缺乏详细的现代过程研究。通过对青海湖不同位置表层沉积样品的生物硅含量测定,建立其空间分布模式及最近数百年生物硅含量的时间序列。结果表明,青海湖表层沉积物生物硅含量变化范围是1.75 ％ ~2.98 ％ ,平均值为2.25 ％ 。与世界其他湖泊相比,青海湖生物硅含量处于相对较低水平,可能与其特殊的地理位置和气候条件有关。青海湖生物硅含量的空间分布规律与沉积物质量堆积速率以及陆源组分含量(如SiO2)相反,而与化学/生物沉积组分(如CaCO3)含量的空间分布规律大体一致,说明生物硅的空间分布受到陆源碎屑物质的"稀释效应"影响。时间序列上,生物硅含量与SiO2含量呈相反变化趋势,与指示降雨量变化的 C/N 比值也是反相变化,说明生物硅含量在时间序列上也受与气候条件密切相关的陆源输入的影响。青海湖湖心低沉积速率区域的生物硅指标具有指示古气候变化的潜力。