压实红黏土的持水性能与机制分析

了解压实红黏土的持水性能是预防路基土体开裂和失稳的基础。首先,利用15 bar压力板仪研究了4种干密度压实试样脱湿路径下的土体持水特征曲线。发现持水曲线随着干密度减小,曲线中间部分呈现水平台阶状,且干密度越小水平台阶的长度越长。然后,结合相同干密度试样的孔隙分布特征曲线,从微观结构的角度分析了压实土体不同持水性能的原因。最后,通过数据拟合的方法建立了不同压实度土体的持水特征曲线方程     

公路隧道中系统锚杆的功效研究

系统锚杆是锚喷支护的重要组成部分,目前广泛应用到公路隧道的初期支护中。然而,系统锚杆到底对隧道结构的稳定起到多少作用一直没有有效的定量计算方法。以某高速公路隧道为例,用有限元强度折减法计算了不同地质条件下锚杆对隧道安全系数大小的影响。结合有限元数值模拟,通过对锚杆各种效应的分析后得到如下结论：在很多地质条件下锚杆对公路隧道稳定性影响不大,建议在有条件的情况下可以逐步开展取消系统锚杆的工程试验验证,为公路隧道不设置系统锚杆提供更多的工程依据     

Removal of Ni(II) from Aqueous Solutions by Nanoscale Magnetite

Magnetite nanoparticles were applied to remove Ni(II) from aqueous solutions as a function of pH, contact time, supporting electrolyte concentration, and analytical initial Ni(II) concentration. The highly crystalline nature of the magnetite structure with diameter of around 10 nm was characterized with transmission electron microscopy (TEM) and X‐ray diffractometry (XRD). The surface area was determined to be 115.3 m²/g. Surface chemical properties of magnetite at 25°C in aqueous suspensions were investigated. The point of zero charge (pHzpc) was found to be 7.33 and the intrinsic acidity constants (${\rm p}K_{{\rm a}1}^{{\rm s}} $ and ${\rm p}K_{{\rm a}2}^{{\rm s}} $ ) were found to be 9.3 and 5.9, respectively. The surface functional groups were investigated with Fourier transform‐infrared spectroscopy (FTIR) as well. Batch experiments were carried out to determine the adsorption kinetics and mechanism of Ni(II) by these magnetite nanoparticles. The adsorption process was found to be pH dependent. In NaCl solutions, Ni(II) adsorption increased with increasing ionic strength while in NaClO₄ solutions, Ni(II) adsorption exhibited little dependence on the ionic strength of the solution. The adsorption process better followed the pseudo‐second order equation and Freundlich isotherm.     

基于背景噪声的宁夏及邻区瑞利波层析成像

In this article,the vertical components of the continuous waveform data of 90 seismic stations in Ningxia and its adjacent regions recorded from January 2012 to December 2013 are used to obtain the Rayleigh surface wave group velocity dispersion images in the study area( 101°- 112°E,31°-42°N) according to the method of noise imaging,with period between 6s - 50s and resolution of 0.5°. The Yinchuan basin in the 6s - 26 s period obviously shows a low velocity anomaly,which is not uniform and has a tendency to gradually weaken; the Guanzhong Basin in 6 s-22s shows a strip of low velocity anomaly and demonstrates a transverse inhomogeneity,where velocity in the southeast is slightly faster than that in the northwest. In the 30s - 50s period it shows that in the Yinchuan graben basin and its southern area,there is a large low velocity anomaly area,which moves from northeast to southwest. It shows that between the main active tectonic zones,like mountains and basins,there are obvious geomorphologic boundaries. For example,the deep fault near Liupan Mountain is the dividing line between two large tectonic units of eastern and western of China. The inversion results have good correlation with the geological structure and the stratigraphic landform. The results are consistent with the results of artificial seismic section tomography across the basin. It provides an important basis for the dynamics of active tectonic zones and the mechanism of earthquake occurrence in this area.     

井下视电阻率观测影响系数分析

采用水平层状均匀介质中点电流源位于任意深度时电位解析表达式,分析了井下对称四极视电阻率观测时影响系数随深度和极距的变化。结果表明对于固定的观测极距,影响系数与电极埋深之间关系复杂;对于某些电性结构和在一定深度范围内,井下观测对表层干扰具有放大作用。对于固定的电极埋深,小极距观测主要体现观测装置所在处的介质层信息,深部介质的影响系数随着极距的加大而增加,浅层影响系数一般先上升后下降;观测极距足够大时,井下观测影响系数逐渐接近于地表观测的影响系数,井下观测的优势得不到体现。本文以天水台为例讨论了实施井下观测时影响系数在选择供电极距和电极埋深过程中的应用。分析结果对在不同电性结构中实施井下地电观测时具有一定的参考意义。     

Dispersion function of Rayleigh waves in porous layered half-space system

Rayleigh wave exploration is based on an elastic layered half-space model. If practical formations contain porous layers, these layers need to be simplified as an elastic medium. We studied the effects of this simplification on the results of Rayleigh wave exploration. Using a half-space model with coexisting porous and elastic layers, we derived the dispersion functions of Rayleigh waves in a porous layered half-space system with porous layers at different depths, and the problem of transferring variables to matrices of different orders is solved. To solve the significant digit overflow in the multiplication of transfer matrices, we propose a simple, effective method. Results suggest that dispersion curves differ in a lowfrequency region when a porous layer is at the surface; otherwise, the difference is small.     

Newmark design spectra considering earthquake magnitudes and site categories

Newmark design spectra have been implemented in many building codes, especially in building codes for critical structures. Previous studies show that Newmark design spectra exhibit lower amplitudes at high frequencies and larger amplitudes at low frequencies in comparison with spectra developed by statistical methods. To resolve this problem, this study considers three suites of ground motions recorded at three types of sites. Using these ground motions, influences of the shear-wave velocity, earthquake magnitudes, source-to-site distances on the ratios of ground motion parameters are studied, and spectrum amplification factors are statistically calculated. Spectral bounds for combinations of three site categories and two cases of earthquake magnitudes are estimated. Site design spectrum coefficients for the three site categories considering earthquake magnitudes are established. The problems of Newmark design spectra could be resolved by using the site design spectrum coefficients to modify the spectral values of Newmark design spectra in the acceleration sensitive, velocity sensitive, and displacement sensitive regions.     

利用断层滑动资料反演郯庐断裂带山东段第四纪构造应力场

郯庐断裂带(即郯城-庐江断裂带)是纵贯中国东部大陆边缘的一条巨型断裂带,整体为北北东走向。它的形成和演化对中国东部中生代以来的地质演化有明显控制作用,同时又是一条现今地震活动较为活跃的地震带,因此对郯庐断裂带周边构造应力场的研究具有重要的意义。采用野外观测取得的10个测点共206条活断层擦痕数据,利用断层滑动资料反演构造应力张量的方法,计算获得了研究区现代构造应力场主要特征:郯庐断裂及其周边地区现代构造应力场以北东-东西向挤压、北西-近南北向拉张为特征,其最大主压应力(σ1)方向为64°一106°,平均倾角23%最小主压应力(σ3)方向为332°~14°,平均倾角14°;中间主应力(σ2)倾角较陡,近垂直,应力结构为走滑型。     

Effect of tidal stress on fault nucleation and failure of the 2007 Ms6.4 Ning’er earthquake

Based on calculations of the tidal Coulomb failure stress and investigations of the correlation between the Earth tide and the Ning’er earthquake sequence, the processes of fault nucleation and failure were simulated. In these simulations we consider the influence of tidal stresses using the rate- and state-dependent friction laws. Furthermore, the effects on tidal triggering due to the stress amplitude and periodic oscillation properties were investigated, and the triggering effects between the tidal normal and tidal shear stresses were compared. The results showed that the Ning’er earthquake sequence was a physical consequence of tidal effects. A transition period T₀ exists between the nucleation and failure processes of a seismic fault. When the period T of stress is equal to or becomes larger than T₀, the fault response becomes dependent on the periodic features of the loading stress; however, for T < T₀, the response of the fault is nearly independent of the period. Both the tidal normal and tidal shear stresses have similar effect in the nucleation and failure processes; the clock changes generally increase with the maximum amplitudes of the tidal stresses. Tidal normal and tidal shear stresses with positive amplitudes mainly induce earthquake triggering; however, the triggering effects induced by negative tidal stresses are smaller and faults are not sensitive to negative tidal stresses. Our results primarily reveal the physical mechanisms of tidal stress triggering.     

含钙铝铁水解聚合产物的矿物学研究Ⅱ:热分解特性

分别以NaOH和Ca(OH)2作为碱化剂,合成了聚合氯化铝铁(PAFCNa,PAFCCa),比较样聚合氯化铝(PACNa,PACCa)、聚合氯化铁(PFCNa,PFCCa),制成低温干燥样进行热分解检测.热重分析证明,PAFCCa中的含水量高,主要是配位水与结晶水.当n(Al)/n(Fe)>5:5后,PAFCCa的含水量平均为42.3%.按Ca6Al2(SO4)3(OH)12·26H2O分子式计算,钙矾石的结构水(含OH水)含量为43.06%,两者含水量相当接近.TG-DTG热分析结果支持XRD对PAFCCa中存在含Ca3Al2(OH)12柱体的类钙矾石结构体的认定.PAFC-Ca根据其DTG曲线上的125℃和180℃两个脱水速率(肩)峰可以判别其中有无钙矾石结构体,以及相对量的多少.