有关蛇绿岩研究的一些新进展

本文扼要介绍有关蛇绿岩的形成环境、成因类型划分及有关上地幔岩变形特征方面的新成果。     

Adsorbed silica in stalagmite carbonate and its relationship to past rainfall

Despite considerable work on other trace elements, the incorporation of dissolved silicon from cave waters into speleothems has not been previously investigated. In this study, the controls on dissolved Si in cave waters and on adsorbed Si in resulting speleothems are therefore investigated. Bedrock (dolomite), soil water, dripping water, and cave carbonates were retrieved from Heshang Cave situated in the central Yangtze valley of China and were subjected to analysis of dissolved Si content (plus accompanying Ca and Fe analyses). Soil waters have Si/Ca of 45.5 mmol/mol, compared to only 3.2 mmol/mol in the dolomite bedrock, demonstrating that >80% of the dissolved Si must come from dissolution of silicate minerals in the soil. Drip waters have a dissolved Si concentration of ≈4.2 μg/mL, similar to that in the overlying soil water. Actively growing cave carbonates have a Si/Ca of 0.075 mmol/mol suggesting a partition coefficient for incorporation of dissolved silicon of 0.0014, in good agreement with previous laboratory studies. Extrapolating the results of these laboratory studies to the cave environment suggests that changes in Si/Ca in cave carbonates are likely to be primarily controlled by changes in drip-water Si/Ca. The drip-water Si/Ca will, in turn, be controlled by the rate of wind-blown silicate supply; by soil weathering rates; by rainfall dilution; and by precipitation of calcite. The general expectation is that these effects combine to produce high Si/Ca in speleothems during times of low rainfall. A δ¹⁸O record from a Heshang Cave stalagmite which grew between 20 and 11 thousand years ago allows these controls to be tested. Correlation of high Si/Ca with high δ¹⁸O demonstrates that regional rainfall exerts significant (but not complete) control on speleothem Si/Ca. With further understanding, speleothem Si/Ca may provide a proxy for past rainfall to complement existing proxies such as δ¹⁸O and Mg/Ca.     

浅析渭河断陷地下热水赋存的地质构造背景

渭河断陷赋存丰富的地下热水资源．本文叙述了该区地热分布特征,阐明了区内地质构造、深部地质条件对地下热水赋存和水温、水量变化的控制作用,兼论了西安城郊区及地热赋存的地质构造背景．对指导当前和今后这一地区地热资源的开发利用和管理工作有重要意义。     

高放废物处置库预选场地地学信息库的建立

本文以高放废物处置库预选场地甘肃北山玉门镇地学信息库的建立为例,详细阐述了地理信息系统在高放废物地质处置中的应用,并在此基础上分析了其应用前景,为不同层次的管理、科研人员提供了全新思路;介绍了将地理信息系统技术引入图件和资料管理的优点。     

先锋盆地小龙潭组巨厚煤层煤相特征

通过２９个煤样的显微组分观察和定量分析,结合氯仿沥青“Ａ”族组分分析和饱和烃气相色谱分析,对先锋盆地上第三系中新统小龙潭组（Ｎ１ｘ）巨厚煤层的煤相特征进行了研究。结果表明该厚煤层形成期间泥炭沼泽经历了一次大的由浅变深、又由深变浅的水深变化,总体上属于低位沼泽。该厚煤层具有以陆生高等植物为主、以水生高等植物为辅的混合生源,山间盆地优越的气候水文条件、良好的聚集场所和充足的成煤原始物质最终在中新世早期稳定下沉的泥炭沼泽环境中形成了巨厚煤层     

关于中国煤层瓦斯区域分布的几点认识

据１９９４￣１９９６年连续３年的统计,全国煤矿瓦斯灾害伤亡人数占煤矿伤亡总人数的４０％以上,瓦斯涌出规律、瓦斯涌出量预测、瓦斯突出预测仍是煤矿安全技术的难题,在加强对瓦斯灾害综合治理的同时,把瓦斯作为煤层气资源积极进行开发利用,是当前的研究方向,瓦斯区域分布规律研究可以概括为建立在煤层瓦斯生成条件、保存条件基础上的高斯赋存量,高瓦斯涌出量,低瓦斯赋存量,低瓦斯涌出量区域分布规律研究;建立在高瓦斯赋     

夹皮沟金矿深部成矿预测研究

系统研究了夹皮沟地区二道沟、庙岭、大猪圈、下戏台和东坨腰子等矿床矿体和近矿围岩微量元素、矿石矿物组合和黄铁矿热电系数等的垂直变化特征,认为三者具有相互一致的变化规律,即：与热液金矿床通常的分带性相比,具有逆向分带的现象,这种特征被认为是多层次正常分带上下叠加的产物,反映夹皮沟地区金矿床在垂向上普遍存在着多个富集地段.据此预测二道沟、庙岭、大猪圈、下戏台和东坨腰子等矿床在目前的开采深度下部仍有发现深部矿体的可能.     

Geological, geochemical characteristics and isotope systematics of the Longqiao iron deposit in the Lu-Zong volcano-sedimentary basin, Middle-Lower Yangtze (Changjiang) River Valley, Eastern China

The Middle-Lower Yangtze (Changjiang) River Valley metallogenic belt is located on the northern margin of the Yangtze Craton of eastern China. Most polymetallic deposits in the Changjiang metallogenic belt are clustered in seven districts where magmatism of Mesozoic age (Yanshanian tectono-thermal event) is particularly extensive. From west to east these districts are: E-dong, Jiu-Rui, Anqing-Guichi, Lu-Zong, Tong-Ling, Ning-Wu and Ning-Zhen. World-class iron ore deposits occur in the Lu-Zong and Ning-Wu ore clusters, which are mainly located in continental fault-bound volcanic-sedimentary basins. One of these deposits is the Longqiao iron deposit, discovered in the northern part of the Lu-Zong Basin in 1985. This deposit consists of a single stratabound and stratiform orebody, hosted in sedimentary carbonate rocks of the Triassic Dongma'anshan Formation. A syenite pluton (Longqiao intrusion) is situated below the deposit. The iron ore is massive and disseminated and the ore minerals are mainly magnetite and minor pyrite. Wall rock alteration mostly consists of skarn minerals, such as diopside, garnet, potassic feldspar, quartz, chlorite, phlogopite and anhydrite. Thin sedimentary siderite beds of Triassic age occur as relict laminated ore at the top and the margin of the magnetite orebody. These sideritic laminae are part of Triassic evaporite-bearing carbonate deposits (Dongma'anshan Formation).Sulfur isotopic compositions show that the sulfur in the deposit was derived from a mixture of magmatic hydrothermal fluids and carbonate–evaporite host rocks. Similarly, the C and O isotopic compositions of limestones from the Dongma'anshan Formation indicate that these rocks interacted with magmatic hydrothermal fluids. The O isotopic compositions of the syenitic rocks and minerals from the deposit show that the hydrothermal magnetite and skarn minerals were formed from magmatic fluids. The Pb isotopic compositions of sulfides are similar to those of the Longqiao syenite. Phlogopite coexisting with magnetite in the magnetite ores yielded a plateau age of 130.5 ± 1.1 Ma (2σ), whereas the LA-ICP MS age of the syenite intrusion is 131.1 ± 1.5 Ma, which is slightly older than the age of phlogopite.The Longqiao syenite intrusion may have crystallized from a parental alkaline magma, generated by partial melting of lithospheric mantle, during extensional tectonics. The ore fluids were probably first derived from magma at depth, later emplaced in the sedimentary rocks of the Dongma'anshan Formation, where it interacted with siderite and evaporite-bearing carbonate strata, resulting in the formation of magnetite and skarn minerals. The Longqiao iron deposit is a skarn-type stratabound and stratiform mineral system, genetically and temporally related to the Longqiao syenite intrusion. The Longqiao syenite is part of the widespread Mesozoic intracontinental magmatism (Yanshanian event) in eastern China, which has been linked to lithospheric delamination and asthenospheric upwelling.     

铁锰氧化物对苯酚氧化降解的实验研究

为了考察铁锰氧化物对酚类污染物的氧化降解能力,采用天然以及合成的铁锰氧化物对苯酚的氧化降解进行对比实验研究。土壤中铁锰氧化物样品分别为天然针铁矿及氧化锰,合成铁锰氧化物样品分别为合成针铁矿及软锰矿。结果表明：苯酚与铁锰氧化物发生氧化还原作用时,还可能与土壤中杂质发生吸附等作用;铁锰氧化物还原反应强度随着反应介质pH值的升高而迅速下降;可用零级反应动力学方程拟合铁氧化物还原溶解反应,针铁矿溶解反应的强度与介质的pH值呈负相关关系;天然针铁矿对酚类污染物的氧化降解能力明显高于合成针铁矿,pH值对天然针铁矿溶解反应影响较大;可用一级指数衰减方程拟合锰氧化物还原溶解反应,锰氧化物溶解反应的强度与介质的pH值呈指数衰减关系;pH值对软锰矿还原溶解反应的影响大于对土壤中氧化锰的影响,pH值越小,影响越显著;对比pH值对铁和锰还原作用的影响发现,在pH=6.5时,锰氧化物仍有较强的氧化性能。