淮南刘庄煤矿地基人工冻融土工程性质与中微观结构之间关系研究

以淮南刘庄煤矿主井地基的人工冻融土为研究对象,以偏光显微镜,扫描电镜（SEM）为主要研究手段,研究分析了人工冻融土与原状土的中微观结构、冻融前后的中微观结构的变化规律及内在原因。此外,还研究分析了人工冻融土冻融前后的中微观结构及其变化与人工冻融土的物理、力学、工程性质之间的关系。研究显示中微观结构对人工冻融土的物理、力学、工程性质有很大的影响,冻融前后中微观结构的变化受到土的种类、埋深、原状土的中微观结构等因素的影响,且冻融前后的中微观结构的变化在一定程度上主导了冻融前后的物理、力学、工程性质的改变。     

土城住宅楼工程锚杆拉力监测及数值模拟分析

支护结构中锚杆的受力在一定程度上反映了作用在支护结构上的土压力大小.对锚杆受力进行原位监测,通过对数据进行研究、分析,可以了解土压力的大小和分布规律,这对于优化深基坑支护结构设计具有重要的实际意义.以某基坑工程为依托,对锚杆在张拉锁定及工作过程中的实际受力情况进行了全程监测,通过FLAC数值模拟分析,研讨了作用于支护结构上的土压力计算问题.     

膜生物反应器中膜污染机理及其防治

通过向一体式膜生物反应器中分别投加聚合铝和粉煤灰改变料液性质,来预防膜污染和提高膜生物反应器对总磷的去除效率,并通过X射线衍射和红外光谱实验分析活性污泥性质的变化,利用扫描电镜分析中空纤维膜表观结构的变化情况,探讨防治膜污染的机理.实验结果表明:聚合铝的投加改变了活性污泥的性质和生物膜的表观结构,可有效地减缓膜污染,且除磷效率达85%以上;而投加粉煤灰并没有明显效果.     

Effect of volatiles erupted from Mesozoic and Cenozoic volcanic activities on paleo-environmental changes in China

Based on the determination of composition of volcanic volatiles and petrologic estimation of the total mass of volatiles erupted, we showed important advances in the study of the impact of Mesozoic and Cenozoic volcanic activities on paleo-environmental changes in China. The volcanic activities include western Liaoning and Zhangjiakou Mesozoic intermediate-acidic explosive eruptions, southern Tibet and Shanwang Cenozoic volcanism, and Mt. Changbai volcanic eruption around one thousand years ago. The paper predominantly discusses the earth’s surface temperature changes, ozone depletion, acidic rain formation and mass mortalities of vertebrate induced by the Mesozoic and Cenozoic volcanism in China. __________ Translated from Bulletin of Mineralogy, Petrology and Geochemistry, 2007, 26(4): 319–322 [译自: 矿物岩石地球化学通报]     

研究“源兆”的若干问题及途径分析

从位场理论的观点讨论了场和源的概念,建议将“场兆”改称为构造前兆,将“源兆”称为震源前兆。文中还分析了震源体与各种前兆观测方法探测的深度,并根据地磁与重力观测方法不同的物理基础和地质基础,指出震磁效应对于研究震源前兆的特殊意义,文中还介绍了１９７６唐山地震观测到震源前兆的部分实际地磁资料。     

Gold Solubility in SiO2—HCl—H2O System at 200℃：a Preliminary Assessment of the Implications of Silicification with Regard to Gold Mineralization

The complexation between gold and silica was experimentally, confirmed and calibrated at 200 °C: $$\begin{gathered} Au^ + + H_3 SiO_4^ - \rightleftharpoons AuH_3 SiO_4^0 \hfill \\ \log K_{(200^\circ C)} = 19.26 \pm 0.4 \hfill \\ \end{gathered} $$ Thermodynamic calculations show that AuH₃SiO ₄ ⁰ would be far more abundant than AuCl ₂ ^? under physicochemical conditions of geological interest, suggesting that silica is much more important than chloride as ligands for gold transport. In systems containing both sulfur and silica, AuH₃SiO ₄ ⁰ would be increasingly more important than Au (HS) ₂ ^? as the proportion of SiO₂ in the system increases. The dissolution of gold in aqueous SiO₂ solutions can be described by the reaction: $$\begin{gathered} Au + 1/4O_2 + H_4 SiO_4^0 \rightleftharpoons AuH_3 SiO_4^0 + 1/2H_2 O \hfill \\ log K_{(200^\circ C)} = 6.23 \hfill \\ \end{gathered} $$ which indicates that SiO₂ precipitation is an effective mechanism governing gold deposition, and thus explains the close association of silicification and gold mineralization.     

Two-dimensional pH distributions and dynamics in bioturbated marine sediments

The seafloor is the site of intense biogeochemical and mineral dissolution-precipitation reactions which generate strong gradients in pH near the sediment-overlying water interface. These gradients are usually measured in one-dimension vertically with depth. Two-dimensional pH distributions in marine sediments were examined at high resolution (65 × 65 μm pixel) and analytical precision over areas of ∼150 to 225 cm² using a newly developed pH planar fluorosensor. Dramatic three-dimensional gradients, complex heterogeneity, and dynamic changes of pH occur in the surficial zone of deposits inhabited by macrofauna. pH can vary by ±2 units horizontally as well as vertically over millimeter scales. pH minima zones often form in association with redoxclines within a few millimeters of inner burrow walls, and become more pronounced with time if burrows remain stable and irrigated for extended periods. Microenvironmental pH minima also form locally around decaying biomass and relict burrow tracks, and dissipate with time (∼5 d). H⁺ concentrations and fluxes in sandy mud show complex acid-base reaction distributions with net H⁺ fluxes around burrows up to ∼12 nmol cm⁻² d⁻¹ and maximum net reaction rates varying between −90 (consumption) to 120 (production) μM d⁻¹ (∼90 nmol cm⁻¹ d⁻¹ burrow length). Acid producing zones that surround irrigated burrows are largely balanced by acid titration zones along inner burrow walls and outer radial boundaries. The geometry and scaling of pH microenvironments are functions of diagenetic reaction rates and three-dimensional transport patterns determined by sediment properties, such as diffusive tortuosity, and by benthic community characteristics such as the abundance, mobility, and size of infauna. Previously, undocumented biogeochemical phenomena such as low pH regions associated with in-filled relict biogenic structures and burrowing tracks are readily demonstrated by two-dimensional and time-dependent images of pH and sedimentary structure.     

邢台矿区山字型构造的发现及其地质意义

邢台山字型构造位于河北省邯邢煤田内，其前弧向ES突出，脊柱呈ES-WN走向。分别分析了山字型构造脊柱及其东、西翼反射弧构造形迹特征，对研究区找矿具有重要意义。