The effects of clay minerals and organic matter on nanoscale pores in Lower Paleozoic shale gas reservoirs,Guizhou, China

In organic-rich gas shales, clay minerals and organic matter (OM) have significant influences on the origin, preservation, and production of shale gas. Because of the substantial role of nanoscale pores in the generation, storage, and seepage of shale gas, we examined the effects of clay minerals and OM on nanoscale pore distribution characteristics in Lower Paleozoic shale gas reservoirs. Using the Niutitang and Longmaxi shales as examples, we determined the effects of clay minerals and OM on pores through sedimentation experiments. Field emission–scanning electron microscopy combined with low-pressure N₂ adsorption of the samples before and after sedimentation showed significant differences in pore location and pore size distribution between the Niutitang and Longmaxi shales. Nanoscale pores mostly existed in OM in the Longmaxi shale and in clay minerals or OM–clay composites in the Niutitang shale. The distribution differences were attributed largely to variability in thermal evolution and tectonic development and might account for the difference in gas-bearing capacity between the Niutitang and Longmaxi reservoirs. In the nanoscale range, mesopores accounted for 61–76% of total nanoscale pore volume. Considerably developed nanoscale pores in OM were distributed in a broad size range in the Longmaxi shale, which led to good pore connectivity and gas production. Numerous narrow pores (i.e., pores?<?20 nm) in OM–clay composites were found in the Niutitang shale, and might account for this shale’s poor pore connectivity and low gas production efficiency. Enhancing the connectivity of the mesopores (especially pores?<?20 nm and those developed in OM–clay composites) might be the key to improving development of the Niutitang shale. The findings provide new insight into the formation and evolutionary mechanism of nanoscale pores developed in OM and clay minerals.     

Semi-analytical solutions for vertically and laterally loaded piles in multilayered soil deposits

In geotechnical practice, it is of considerable importance to assess the behavior of vertical–lateral coupled loading piles in multilayered soil deposits. This study deals with a semi-analytical formulation for the performance of a pile suffering from combined vertical and lateral loads. The emphasis is on quantifying the mobilization of the subgrade reaction provided by the layered soil stratums. In the proposed method, subgrade reactions, correlated with both the accumulative axial load transfer and side resistances depending upon the pile–soil interaction, are abstracted as a series of nonlinear springs in both vertical and lateral directions. On account of this, an alternative transfer matrix method is applied to characterize the pile reaction along the depth under the identified boundary conditions atop the pile; meanwhile, the condition of static equilibrium, between two specific pile segments located at the border of soil layers, is also essential. On this basis, validation of the solution is conducted by comparing with observations from experiments and predictions obtained from other existing methods. In addition, the influence of properties in shallow soil layer and the vertical load on the lateral response of the pile is also discussed. The results indicate a reduction in the lateral displacement and the maximum bending moment within the pile with the increase in the shallow soil stiffness, but a growth with the increase in vertical load due to the “P-Δ effect.”     

Model Test on Self-Weight Consolidation of the Red Mud Tailings Placed in the Karsts

The management of tailings depends on its consolidation behavior to great extent. The red mud tailings in Pingguo, Guangxi is of high water content and void ratio. The present paper takes the red mud aluminiferous tailings in Pingguo, Guangxi as prototype. Model tests were carried out to study the consolidation behavior of red mud aluminiferous tailings that were landfilled layer by layer. The layered settlement and the water discharge caused by self-weight consolidation were studied. The influence of the latter landfilled layer of red mud on the previous layer was analyzed. The results show that the settlement at the surface with time can be divided into two stages. During the first stage, a thin layer of water appeared and the thickness kept increasing at the top of the mud surface with the particle of red mud sinking. During the second stage, water drained from the mud and settlement developed slowly. Cracks developed at the surface due to evaporation and the red mud near the surface became unsaturated. When the previous landfilled layer consolidated to the degree that the water content was less than 40%, the later landfilled layer of red mud will have little influence on the settlement of previous landfilled layer.     

Zircon U-Pb Geochronology,Geochemistry and Petrogenesis of Early Cretaceous A-type Granites in the Mikengshan Area,Southern Jiangxi ProvinceEI北大核心CSCD

In the Mikengshan-Yanbei area, a special region for the tin mineralization in South China, there are some Yanshanian granites and porphyries and associated porphyry tin deposits (e.g., Yanbei). Although the tin mineralization is closely associated with the granitoids magmatism, the age and petrogenesis of the granites remain controversial. The Mikengshan pluton, which intrudes into the rhyolitic tuff and pyroclastic rocks of the Upper Jurassic Jilongzhang Formation, is the largest one in Mikengshan-Yanbei area and mainly consists of K-feldspar bearing granites. In this study, we report new age and geochemical data for the Mikengshan K-feldspar bearing granites. LA-ICP-MS zircon U-Pb age dating shows that they were generated in the Early Cretaceous (~138 Ma). They have high SiO2 (74.42% to 76.69%), low Al2O3 (12.39% to 13.49%) and Mg# (11 to 19), and negative Eu, Sr and Ba anomalies, and are rich in potassium (most K2O/Na2O=1.37 to 1.94) and high field strength elements (HFSEs), and are weakly peraluminous (A/CNK=1.03 to 1.1) with high 10000×Ga/Al ratios (3.46 to 4.96) and slightly high zircon saturation temperatures (807 ℃ to 817 ℃), showing the characteristics of the typical A-type granites. Moreover, they have high Rb contents 842×10-6 to 1295×10-6, Rb/Sr (90 to 255) ratios and show rare earth elements (REE) tetrad effect, which are similar to those of high fractionated granites. Thus, we suggested that the Mikengshan K-feldspar bearing granites are high fractionated and aluminous A-type granite. Their slightly high εNd(t) values (-3.4 to -4.6) indicate that the mantle components should have played a role during their formation. Taking into account regional igneous rocks and tectonic setting data, we suggest that the Mikengshan K-bearing granites were formed in an extensional setting, which was probably related to the roll-back of the subducted Paleo-Pacific plate. © 2018, Science Press. All right reserved.     

Water Cycle Analysis of Social and Economic System in Tarim River Basin

Water cycle includes natural water circulation and social economic system water cycle. The concept of virtual water provides a new method and means for studying social water circulation. This paper is based on the theory of water circulation in social and economic system, using input-output analysis method quantitatively describes the Tarim River basin of social water cycle paths and analysis of water resources management in Tarim River basin sustainable development process of the key issues. The results show that the main sectors of virtual water export in the Tarim River Basin are agriculture, petroleum, natural gas and food industry. Agricultural water accounts for more than 98% of total water consumption, most of which is transferred to the food and textile industries, and the food industry export water from the agricultural sector. Shandong Province is the largest virtual water transport area in the Tarim River Basin. The main sector of virtual water input in the Tarim River Basin is the metallurgical industry. Finally, in view of the problems arising from the inter-industrial and inter-regional social water circulation in the Tarim River basin, the paper puts forward the ways and strategies of regulating agricultural and industrial water use in the Tarim River Basin.     

The evolution of the terrestrial-terminating Irish Sea glacier during the last glaciation

Here we reconstruct the last advance to maximum limits and retreat of the Irish Sea Glacier (ISG), the only land-terminating ice lobe of the western British Irish Ice Sheet. A series of reverse bedrock slopes rendered proglacial lakes endemic, forming time-transgressive moraine- and bedrock-dammed basins that evolved with ice marginal retreat. Combining, for the first time on glacial sediments, optically stimulated luminescence (OSL) bleaching profiles for cobbles with single grain and small aliquot OSL measurements on sands, has produced a coherent chronology from these heterogeneously bleached samples. This chronology constrains what is globally an early build-up of ice during late Marine Isotope Stage 3 and Greenland Stadial (GS) 5, with ice margins reaching south Lancashire by 30 ± 1.2 ka, followed by a 120-km advance at 28.3 ± 1.4 ka reaching its 26.5 ± 1.1 ka maximum extent during GS-3. Early retreat during GS-3 reflects piracy of ice sources shared with the Irish-Sea Ice Stream (ISIS), starving the ISG. With ISG retreat, an opportunistic readvance of Welsh ice during GS-2 rode over the ISG moraines occupying the space vacated, with ice margins oscillating within a substantial glacial over-deepening. Our geomorphological chronosequence shows a glacial system forced by climate but mediated by piracy of ice sources shared with the ISIS, changing flow regimes and fronting environments.     

额济纳绿洲沙尘暴沉积特征

1 Introduction Oases are unique ecosystems and important residences for our ancestors in arid and semiarid regions of the world, and have deeply been imprinted by human actions, such as Jericho oasis of Jordan Valley, Jarmo oasis of the Euphrates River an…     

汛期短历时强降水过程的闪电特征

对2011年3次短历时强降水天气过程的闪电特征分析结果表明:①3次短时强降水都以负闪为主,负闪占总闪电的比例都在92﹪以上;②小时闪电频数峰值超前降雨峰值1h或同相;③5min闪电频数超前雨量峰值5~60min;④负闪电密集区主要发生在40dBZ以上的回波区,偶尔发生的正闪一般在较弱回波处;闪电大部分发生在回波顶高大于5km以上的区域;多分布在速度不均匀场附近;闪电密集区与VIL大值区对应关系不太好;⑤不同云体,闪电特征不尽相同,闪电频数高峰有的发生在强回波阶段,有的并不是回波最强阶段,而是减弱阶段。强回波前沿出现闪电密集区或前方无回波处发生闪电,预示未来强回波移动的方向;有的云体发展、成熟阶段闪电分布密集,负闪电主要集中在强回波中心附近,云体减弱阶段闪电分散,集中在单体的不同部位。     

基于激光雷达测风数据的复杂地形下风力机尾流特性研究

以张家口某处风电场为实验场地,采用两台多普勒激光雷达(Wind3D 6000和WindMast WP350)分别测量风力机的尾流和来流风速,对全尾流、半尾流和独立尾流3种工况进行研究。结果表明,3种工况下随着尾流发展尾流宽度均不断变大,而尾流深度和速度衰减则不断减小;全尾流和半尾流工况中,上游风力机的存在会增加下游风力机尾流宽度,且全尾流比半尾流的增加量大;全尾流和半尾流工况中,相较于上游风力机,下游风力机尾流深度和速度衰减均较小。     

汾河流域城乡聚落体系发展潜能测度及空间模式探究

以11 188个自然聚落斑块为研究对象,基于场强模型,定量测度汾河流域城乡聚落体系发展潜能,借助GIS技术和地理探测器模型,分析其空间格局特征及驱动因素,进而探讨流域城乡融合发展空间模式。结果表明：① 城乡聚落斑块发展潜能差异显著,且空间分布极不均衡;纵向上中游流域高于下游流域高于上游流域,横向上河谷盆地区高于周边缓丘区高于两侧山丘区。② 聚落斑块发展潜能具有正向空间自相关性,高值斑块聚类显著;具有空间异质性特征且方向性明显,汾河主河道方向联动效应最强,空间联系最紧密;存在局域热点区,并呈现“主核–廊道–次核”的空间结构形态。③ 自然基础、社会经济发展水平和区位条件共同影响着城乡聚落体系发展潜质及空间结构形态;融合发展采取非均衡增长路径,市、县、镇、村全局考虑,构建“强化核心点–培育发展轴–扶持特色区–带动全流域”的逐层推进式空间发展模式。