云南羊拉铜矿矽卡岩形成时代与矿床成因：来自石榴子石和磁铁矿组分的约束

羊拉铜矿是金沙江缝合带中部已发现的规模最大的印支期铜矿床,矿体以层状—似层状产出于花岗闪长岩外围、变质砂岩与碳酸盐岩地层的层间破碎带中。该矿床在成因类型上存在喷流-沉积成因、复合成因、矽卡岩成因等多种观点。本文以矽卡岩矿石中石榴子石、磁铁矿为研究对象,利用LA-ICP-MS原位微区分析技术开展了石榴子石U-Pb年代学和石榴子石、磁铁矿成分测试分析,以进一步限定该矿床成矿时代和成因类型。分析结果显示,石榴子石中U、Th、Pb的含量分别为1.18×10^-6～6.69×10^-6、0.04×10^-6～1.43×10^-6、0.11×10^-6～1.16×10^-6,获得Tera-Wasserburg下交点年龄为231.0±5.3 Ma(2σ,n=32,MSWD=2.1),与矿区花岗闪长岩形成时代高度一致。结合磁铁矿微量元素组成与全球矽卡岩型矿床可类比等特征,明确羊拉铜矿床属于典型矽卡岩型铜矿床。石榴子石以钙铁榴石组分为主,具轻稀土富集、重稀土亏损的配分模式,这可能受晶体...     

再力花/菖蒲生物湿地床去除河水中氮磷的试验

采用再力花和菖蒲构建湿地床,以考察其对污染河水的净化效果。6个月的连续试验表明:在水力负荷为0.24 m3/(m2.d)、植物种植密度大于158株/m2的条件下,2种植物存活率均大于93%,说明植物能适应低污染负荷、高种植密度的无土培养环境;再力花和菖蒲湿地床月均去除率分别为:总氮(TN),48.22%～78.53%和43.23%～72.42%;总磷(TP),77.62%～85.67%和58.07%～80.77%。再力花湿地床对TN、TP的净化效果好于菖蒲湿地床;2种植物吸收N、P含量分别占去除总量的比例:N为44.14%、37.75%,P为73.43%、62.05%。湿地床技术可有效去除来水中的TN、TP,通过植物吸收作用累积N、P含量较高,不同种类的植物构建湿地床对污染河水中N、P去除效果存在显著差异,且硝化反硝化和植物吸收是去除N的主要途径,而植物吸收是去除P的有效手段。     

Machine learning reveals the influences of grain morphology on grain crushing strength

Acta Geotechnica - Grain morphology has significant impacts on the mechanical behaviors of granular materials. However, its influences on grain breakage are still poorly understood due to the...     

Environmental magnetic studies of sediment cores from Gonghai Lake: implications for monsoon evolution in North China during the late glacial and Holocene

Environmental magnetic studies were conducted on a 9.42-m-long sediment core from Gonghai Lake, North China. Radiocarbon dating indicates that the record spans the last 15,000 cal year BP. The principal magnetic mineral in the sediments is pseudo-single domain magnetite of detrital origin with minimal post-depositional alteration. Although the variations in the concentration of detrital magnetic minerals and their grain size throughout the core reflect inputs from both soil erosion and eolian dust, it is shown that their climatic and environmental significance changes with time. In the lowermost part of the core, ~15,000–11,500 cal year BP, the magnetic minerals were supplied mainly by bedrock erosion, soil erosion and dust input when climate ameliorated after the cold and dusty last glacial maximum. The increasing magnetic susceptibility (χ) in this interval may indicate a combination of changes in the lake environment together with catchment-surface stabilization and a decreasing proportion of dust input. In the central part of the core, ~11,500–1,000 cal year BP, the detrital magnetic minerals mainly originated from dust inputs from outside the catchment when the lake catchment was covered by forest, and catchment-derived sediment supply (and thus the lake sediment accumulation rate) were minimal. The generally low concentration of magnetic minerals in this part of the core reflects the highest degree of soil stability and the strongest summer monsoon during the Holocene. In the uppermost part of the core, the last ~1,000 years, detrital magnetic minerals mainly originated from erosion of catchment soils when the vegetation cover was sparse and the sediment accumulation rates were high. Within this part of the core the high magnetic susceptibility reflects strong pedogenesis in the lake catchment, and thus a strong summer monsoon. This scenario is similar to that recorded in loess profiles. Overall, the results document three main stages of summer monsoon history with abrupt shifts from one stage to another: an increasing and variable summer monsoon during the last deglacial, a generally strong summer monsoon in the early and middle Holocene and a weak summer monsoon in the late Holocene. The results also suggest that different interpretational models may need to be applied to lake sediment magnetic mineral assemblages corresponding to different stages of environmental evolution.     

Response spectral amplification ratios from 1- and 2-dimensional nonlinear soil site models

In order to determine the effect of geometry on the ground response of 2-dimensional (2-D) basins filled with soils that can develop nonlinear response, we use three basin models with width/depth ratios 3, 6 and 10. The three basins are subjected to a suite of rock site records with various magnitudes and source distances. We compute response spectral amplification ratios at four locations on the surface of the 2-D basins, and determine the average variation of the amplification ratios with respect to excitation spectra, for peak ground acceleration (PGA) and 3 spectral periods of 0.2, 0.5, 1 s. Similarly, we compute the average response spectral amplification ratios for two 1-dimensional (1-D) nonlinear models, one having the soil profile at the basin centre and the other having a soil profile at half the depth of the basin. From the relationship between the average amplification ratios and excitation spectra, we determine the cross-over point in terms of excitation spectral values that separate the amplification range from the deamplification range. Our results show that the cross-over point varies significantly from one location to another on the ground surface and from one basin to another, in a range of 0.3–1.1g for PGA. The effects of basin geometry are very strong at weak and moderate excitation, but decrease with increasing excitation spectra in a significant portion around the basin centre. Our results provide some justification for using 1-D models for 2-D basins with a width/depth ratio ?6 if the soil site is subjected to strong ground shaking.     

青岛冷水团的消亡机理研究

本文基于多年月平均水温资料,分析了青岛冷水团的长消过程,并利用气候态月平均大气数据和数值模拟结果,探讨了青岛冷水团的消亡机理。结果表明,青岛冷水团3月出现,4月成型,5月最盛,6月减弱,7月消失;南黄海6-7月间偏南风的增强和温跃层以下反气旋涡的减弱是青岛冷水团消亡的动力机制,而海面净热通量的下传和水平热量的输入则是青岛冷水团消亡的热力机制。     

应用北太平洋表层水温及环流场进行海冰预报

渤海及黄海北部处在中纬度地带,每年冬季都有不同程度的结冰现象。以辽东湾结冰时间最长,全部结冰日数平均为100多天,约占全年的三分之一。从全海区看,建国后冰情较重的有1957、1968、1969、1977年的1、2月份,尤其是1969年,渤海海面发生了该海区历史上罕见的冰封,整个海面几乎全部被海冰所覆盖,严重阻碍了海上的航运交通及海上石油开采工作,从而给国民经济带来很大损失。     

1958-2016年呼伦贝尔草原新巴尔虎右旗气温和降水变化特征

气候变化是影响草原区植被与环境状况的重要因素。利用呼伦贝尔草原新巴尔虎右旗1958-2016年的气温和降水数据资料,采用线性倾向估计法、累积距平分析法、M-K检验法和Morlet小波分析等方法,从不同时间序列上,对该地区近59年的气候变化趋势、极端气候以及突变现象进行分析。结果表明：年平均气温以0.354℃/10a的速率上升,上升趋势显著;四季平均气温均呈现增温趋势,其中春季增温趋势最大;1985-1986年发生了由低温到高温的突变;研究区年平均气温存在11 a的强显著周期。研究区年降水量整体以8.68 mm/10a的速率呈下降趋势,变化趋势不显著;降水集中在夏季（6-8月）,占全年降水量的72.9%,7月降水量最大,有效降水日数最多;1961-1962年和1981-1982年降水发生突变;极端降水指标中日最大降水量、连续5 d最大降水量、强降水量、极强降水量、强降水比率、连续无雨日数、零降水量日数均呈现递减趋势,仅降水强度呈递增趋势,变化趋势均不显著;Morlet小波分析表明研究区年降水量存在52 a的强显著周期。新巴尔虎右旗近59 a气候总体呈现干旱化趋势。     

Comparative studies on compounds occluded inside asphaltenes hierarchically released by increasing amounts of H2O2/CH3COOH

Being the heaviest fraction of crude oils, asphaltenes are liable to aggregate, and other molecules in the oils can be steadily adsorbed onto, and even occluded inside the macromolecular structures of the asphaltenes. These occluded compounds inside the asphaltenes can survive over geological time in oil reservoirs owing to effective protection by the macromolecular structures of the asphaltenes. The asphaltenes of a crude oil (ZG31) from the central Tarim Basin, NW China, were hierarchically degraded by increasing the amount of H₂O₂/CH₃COOH to release the occluded compounds. Besides the common components, series of even numbered n-alk-1-enes and 3-ethylalkanes were detected among the occluded compounds. Comparison of the biomarker distributions and the compound-specific C isotopic results between the compounds from the maltenes and those from the occluded fraction, the ZG31 reservoir was suggested to have been charged multiple times, with different charges being derived from different strata of source rocks.     

山东济宁高硫煤与低硫煤煤层剖面地球化学特征研究

运用电感耦合等离子质谱（ICP-MS）、X射线荧光光谱（XRF）、离子选择电极（ISE）、显微镜光度计和煤化学等方法,对山东济宁矿区的高硫煤（太原组16号煤层）与低硫煤（山西组3上煤层）剖面的煤岩、煤质和煤地球化学特征进行研究。高硫煤中微量元素在垂向上呈现显著的变化规律：（1）Sr含量从煤层底板到顶板呈增高趋势,而Ba含量则相反;因而Sr/Ba比值从下向上呈逐渐变大趋势（0.04～47.7）;（2）Th/U比值从下向上也呈逐渐变大趋势（0.2～37.1）;（3）As含量在煤层顶板石灰岩（26.1μg/g）、透镜状黄铁矿夹层（14.7～19.3μg/g）中较高;（4）V、Cr、Co、Ni、Cu、Pb、Zn等元素在煤层底部和顶部分层中含量较高,而在煤层中部分层中含量较低;（5）Nb、Ta、Zr、Hf、Ga等元素从煤层的底部到顶部呈逐渐降低趋势;（6）煤中稀土元素总量（REE）,除透镜状黄铁矿夹层（第2、4、11分层）外,其它分层（第1、3、5、6、7、8、9、10分层）显示从上往下逐渐增高之规律性。低硫煤中微量元素的分布和垂向变化与高硫煤明显不同：As含量在14个煤分层中都较低（1.03～3.37μg/g）,Sr/Ba比值从下向上变化不大（0.4～2.2）,各个煤分层中稀土元素总量（REE）呈现随灰份含量增高而增高的变化趋势,低硫煤与高硫煤的稀土元素分布模式差别很大。上述研究结果表明济宁矿区高硫煤与低硫煤在地球化学特征上的差别,反映了上石炭统太原组与下二叠统山西组沉积环境和聚煤条件的差别,具有指相意义;太原组16号煤层中富集的硫及有害微量元素,对环境具有潜在危害。