Lead isotope geochemical characteristics of Pb-Zn-Cu deposits on the southwestern margin of Tarim, and their significance

The polymetallic(Pb,Zn,Cu,etc) ore belt on the southwestern margin of Tarim is one of the major regions with the greatest prospecting potential in Xinjiang.Reported in this paper are the lead isotope data for 66 sulfide samples(including 50 galena samples,15 chalcopyrite samples and 1 pyrite sample) collected from such representative deposits as Tamu,Tiekelike,Kalangu,Abalieke,etc.in this ore belt.The Pb isotopic ratios of 206 Pb/204 Pb,207 Pb/204 Pb and 208 Pb/204 Pb in the galena samples range from 17.931 to 18.176,15.609 to 15.818 and 38.197 to 38.944,with the average values of 18.017,15.684 and 38.462,respectively.Those in the chalcopyrite samples range from 17.926 to 18.144,15.598 to 15.628 and 38.171 to 38.583,with the average values of 18.020,15.606 and 38.262,respectively.The pyrite sample has the Pb isotopic ratios of 206 Pb/204 Pb,207 Pb/204 Pb and 208 Pb/204 Pb to be 17.980,15.604 and 38.145,respectively.In combination with the previous Pb isotope data for sulfides,it is found that there is only a slight variation in the Pb isotopic composition of galena,chalcopyrite,sphalerite and pyrite in the ore belt.However,there is some difference in Pb isotopic characteristics between galena and chalcopyrite,especially the Pb isotopic composition of galena shows an obvious linear correlation with some other relevant parameters(e.g.β and γ).The comprehensive analysis suggested that lead in galena(maybe including sphalerite and pyrite) was derived principally from wall rocks and underlying basement,and that in chalcopyrite only originated from the basement.The single-stage model ages of these sulfides couldn’t indicate the time limit of metallogenesis(Pb,Zn,Cu,etc.),and the positive linear correlations for the Pb isotopic composition of galena are of no single-stage and two-stage Pb-Pb isochron significance.Furthermore,there are significant differences in Pb isotopic composition characteristics between the genetic type of deposits in this polymetallic ore belt and the Mississippi Valley type(MVT).In addition,the authors also pointed out that there is a phenomenon of differentiation(not paragenesis) for lead and copper elements during the process of metallogenesis in this ore belt.     

辽东早元古代裂谷多金属硫铁矿地质及其成矿规律

辽东早元古代地层内赋存着一系列多金属硫铁矿床。矿床的形成与分布主要受裂谷盆地演化及含矿建造控制。在不同的演化阶段分别形成了含钴黄铁矿 含铜黄铁矿 含硬石膏黄铁矿矿床系列和含硼（镁电气石）磁黄铁矿 含铅锌黄铁矿 重晶石闪锌黄铁矿矿床系列。依据成矿特征可分为海底火山喷气沉积与海底喷气沉积两种成因类型。成矿作用受裂谷、次级盆地、一定含矿层位和特殊容矿岩石相互联系与配套的控矿因素制约。在对成矿规律研究的基础上将该区多金属硫铁矿划分为６个成矿远景区。     

Archaean high-K granitoids produced by remelting of earlier Tonalite–Trondhjemite–Granodiorite (TTG) in the Sangmelima region of the Ntem complex of the Congo craton,southern Cameroon

We present a geochemical and isotopic study that, consistent with observed field relations, suggest Sangmelima late Archaean high-K granite was derived by partial melting of older Archaean TTG. The TTG formations are sodic-trondhjemitic, showing calcic and calc-alkalic trends and are metaluminous to peraluminous. High-K granites in contrast show a potassic calc-alkaline affinity that spans the calcic, calc-alkalic, alkali-calcic and alkalic compositions. The two rock groups (TTG and high-K granites) on the other hand are both ferroan and magnesian. They have a similar degree of fractionation for LREE but a different one for HREE. Nd model ages and Sr/Y ratios define Mesoarchaean and slab-mantle derived magma compositions respectively, with Nb and Ti anomalies indicating a subduction setting for the TTG. Major and trace element in addition to Sr and Nd isotopic compositions support field observations that indicate the derivation of the high-K granitic group from the partial melting of the older TTG equivalent at depth. Geochemical characteristics of the high-K granitic group are therefore inherited features from the TTG protolith and cannot be used for determining their tectonic setting. The heat budget required for TTG partial melting is ascribed to the upwelling of the mantle marked by a doleritic event of identical age as the generated high-K granite melts. The cause of this upwelling is related to linear delamination along mega-shear zones in an intracontinental setting.     

祁连山区黑河流域季节冻土时空变化研究

季节冻土的时空变化对地—气水热交换、地表能量平衡、地表水文过程、生态系统及碳循环等有着非常重要的影响.利用黑河流域11个气象站40多年的气温数据和5 cm深度处的土壤温度数据,建立了月平均气温与土壤冻结天数之间的关系.同时应用月平均气温与冻结天数的相关关系和5 km网格化月平均气温及30 m分辨率的DEM数据,编制了黑河流域逐月季节冻土分布图,并按其空间分布特征,将逐月地表冻融状态划分为:完全冻结、不完全冻结和不冻结3种.系统研究了黑河流域2000-2009年逐月季节冻土分布及冻结概率的时空变化特征.在季节分配上,黑河流域完全冻结面积最大值出现在1月;不完全冻结面积最大值在11月;而不冻结面积最大值在6月和7月.在年际变化上,完全冻结状态的离差值在冷季变化大,暖季变化小;不完全冻结状态在一年的回暖期和降温初期,年际变化较大;不冻结状态分别在4月和10月变化较大.冻结概率在1月达到最大值,6月和7月降低到最小值.在空间分布上,黑河流域季节冻土的逐月分布与变化和冻结概率主要受海拔高度控制,纬度的影响次之.     

两株南极枝孢霉属真菌Cladosporium sp.NJF4和NJF6的次级代谢产物研究

南极因其独特的自然环境成为潜在、重要的微生物资源库,是产生新型生物活性物质和先导化合物菌株的潜在种源地,南极微生物正在成为创新药物研究新的重要资源。虽然近年来对南极微生物次级代谢产物的研究逐渐增加,但与温带和热带微生物研究相比仍处于初级阶段。对从南极普里兹湾海洋沉积物中获得的两株枝孢霉属真菌Cladosporium sp. NJF4和NJF6进行次级代谢产物分离及结构鉴定,获得20个化合物。化合物结构类型包括甾醇(1)、倍半萜类(7—8)、生物碱类(9—14)、二酮哌嗪(2—5、15—17)、芳香酸(6、18—19)等,其中倍半萜类(7—8)为首次从枝孢霉属真菌中分离得到,以上研究将为丰富南极微生物次级代谢产物库奠定一定的研究基础。     

啤麦穗粒结构的分阶段气候评价和预报方法研究

通过对十多年来啤麦穗粒结构与气象条件的关系的计算分析,得出了啤麦不同生育阶段影响穗粒结构的主要气象要素,并建立起其间的线性关系模式,为对啤麦产量构成要素进行分阶段的气候评价和预报提供了新的方法。     

风云三号降水测量雷达技术性能分析

风云三号降水测量卫星主要用于台风等灾害性天气系统强降水的监测,并提供全球中低纬度地区降水的结构信息。降水三维结构的准确测量是通过风云三号降水测量卫星的核心载荷——双频降水测量雷达实现的。首先介绍了风云三号降水测量雷达的主要任务与探测能力要求,然后通过仿真技术对降水测量雷达距离分辨率、水平分辨率、扫描角度、天线旁瓣电平、测量精度、波束匹配精度等主要技术性能指标进行了详细的分析。最后,利用于2010年开展的降水测量雷达样机航空校飞试验评估验证了降水测量雷达的各项功能和主要性能参数。结果表明,风云三号降水测量雷达整体降水探测性能与全球降水测量卫星的双频降水雷达相当。     

Adsorption of anionic dye on magnesium hydroxide-coated pyrolytic bio-char and reuse by microwave irradiation

Magnesium hydroxide-coated pyrolytic bio-char composite was prepared by chemical precipitation, and the adsorption behavior of anionic dye (directly frozen yellow) onto magnesium hydroxide-coated pyrolytic bio-char was investigated in the batch mode. The Fourier transform infrared spectroscopy, X-ray diffraction spectroscopy and X-ray fluorescence spectroscopy of adsorbents were characterized. Adsorption studies were performed at different pH, salt concentration, contacting time and dye concentration. The pH value of the solution influenced the adsorption capacity significantly, and adsorption is favored of pH 6–8. Salt coexisted in solution increased slightly directly frozen yellow adsorption capacity. The isotherm data were analyzed by Langmuir and Freundlich isotherm model, and Langmuir model was better to predict the equilibrium data. Thermodynamic calculations showed that the adsorption was a spontaneous and endothermic process. Exhausted magnesium hydroxide-coated pyrolytic bio-char was treated by microwave irradiation, and yield of regeneration was 98 % in the case of microwave irradiated time 5 min at 320 W. The magnesium hydroxide-coated pyrolytic bio-char can be reused.     

内蒙古孟恩陶勒盖银铅锌铟矿床成因研究

文章从地质特征及地球化学特征方面论证了孟恩陶勒盖矿床的成因。地质特征显示该矿床的形成与花岗岩之间不存在成因联系，矿床相对于岩浆岩围岩是后成的，花岗岩及断裂构造只是为矿床提供了储存空间。矿床地球化学特征显示该矿床的成因与可能位于深部的燕山期岩浆活动有关，成矿元素及硫主要来自岩浆，成矿流体以岩浆水为主。因此该矿床属于岩浆热液型多金属矿床。     

论卡以头组

卡以头组为介于宣威组和东川组之间的一个岩石地层单位 ,主要为黄绿色、灰绿色、褐黄色夹紫红色砂岩、砾岩和泥质岩组合 ,海相层底部夹少量灰岩 ,不含煤层和 Claraia。该组为晚二叠世—早三叠世沉积 ,海相多为早三叠世地层。建议以威宁哲觉剖面为卡以头组的标准剖面