Adsorption of anionic dye on magnesium hydroxide-coated pyrolytic bio-char and reuse by microwave irradiation

Magnesium hydroxide-coated pyrolytic bio-char composite was prepared by chemical precipitation, and the adsorption behavior of anionic dye (directly frozen yellow) onto magnesium hydroxide-coated pyrolytic bio-char was investigated in the batch mode. The Fourier transform infrared spectroscopy, X-ray diffraction spectroscopy and X-ray fluorescence spectroscopy of adsorbents were characterized. Adsorption studies were performed at different pH, salt concentration, contacting time and dye concentration. The pH value of the solution influenced the adsorption capacity significantly, and adsorption is favored of pH 6–8. Salt coexisted in solution increased slightly directly frozen yellow adsorption capacity. The isotherm data were analyzed by Langmuir and Freundlich isotherm model, and Langmuir model was better to predict the equilibrium data. Thermodynamic calculations showed that the adsorption was a spontaneous and endothermic process. Exhausted magnesium hydroxide-coated pyrolytic bio-char was treated by microwave irradiation, and yield of regeneration was 98 % in the case of microwave irradiated time 5 min at 320 W. The magnesium hydroxide-coated pyrolytic bio-char can be reused.     

内蒙古孟恩陶勒盖银铅锌铟矿床成因研究

文章从地质特征及地球化学特征方面论证了孟恩陶勒盖矿床的成因。地质特征显示该矿床的形成与花岗岩之间不存在成因联系，矿床相对于岩浆岩围岩是后成的，花岗岩及断裂构造只是为矿床提供了储存空间。矿床地球化学特征显示该矿床的成因与可能位于深部的燕山期岩浆活动有关，成矿元素及硫主要来自岩浆，成矿流体以岩浆水为主。因此该矿床属于岩浆热液型多金属矿床。     

硅灰石表面改性实验研究

实验以湖北大冶硅灰石为原料，初步探讨了硅灰石表达改性的工艺条件。经沉降体积法、表面接触角、红外光谱等方法检测和填充橡胶试验证实，硅灰石得到了改性且其填充性能有明显的提高。     

煤中惰质组在泥炭沼泽古环境研究中的应用

惰质组是煤中一种常见的显微组分。它不仅能用来鉴别成煤前植物的木炭化程度,而且还是泥炭沼泽古环境恢复的有效途径。近年来,欧洲学者利用惰质组成功推算了地史时期三叠纪—侏罗纪之交(T—J)的古火灾温度及类型,并重建了古植被类型及泥炭沼泽古生态环境变化。与其它方法相比,利用煤中惰质组含量及其反射率进行古环境恢复的工作对于植物种类繁多、沉积岩层中夹杂的煤层或煤炭、尤其对于古气候环境波动较大的地质转折时期最为理想。因此,利用惰质组的部分参数对我国含煤沉积盆地的古生态恢复以及成煤环境的研究有积极的借鉴意义。     

罕见的蓝色饵-纳透闪石研究

尽管角闪石在地壳中大量存在 ,但是蓝色钾 钠透闪石却是角闪石中的稀有品种。本文采用X射粉晶线衍射和晶胞参数计算 ,确定该矿物为蓝色的钾 钠透闪石 ,用电子探针 (EMPA)精确分析了它的化学成分 ,确定为钾 钠透闪石 ,而不是蓝色软玉 (即不是透闪石或阳起石 )。     

一种求解旅行商问题的改进蚁群算法

蚁群算法作为一种新型的优化算法,具有很强的适应性和鲁棒性,已广泛的应用于系统控制、人工智能、模式识别等工程领域。由于蚁群算法在搜索过程中易于陷入局部最优解,存在着加速收敛和早熟停滞现象的矛盾。文章针对这些问题,在基本蚁群算法的基础上,从参数的动态调整、信息量的更新规则、局部搜索策略进行相应的改进,引入信息素平滑机制,以求在加快收敛和防止早熟停滞之间取得较好的平衡。旅行商问题的仿真表明:改进后的蚁群算法具有较好的收敛性和稳定性,能够克服算法中早熟和停滞现象的过早出现。     

黑龙江七星河含煤盆地古近纪-新近纪沉积相及层序地层特征

黑龙江省东部七星河盆地是一新生代聚煤盆地,其含煤地层为古近系宝泉岭组、新近系富锦组。宝泉岭组由各级砂岩、泥岩、炭质泥岩以及褐煤组成,发育滨浅湖相、深-半深湖相、三角洲平原相,属于湖泊沉积体系、三角洲沉积体系。富锦组主要由泥岩、粉砂岩、中砂岩、含砾粗砂岩及煤层、炭质泥岩、硅藻岩组成,发育滨浅湖相、扇三角洲平原相,分别属于湖泊沉积体系和扇三角洲沉积体系。层序SI相当于宝泉岭组,发育低位体系域、湖侵体系域和高位体系域,煤层主要发育高位体系域中后期,成煤环境以滨浅湖淤积沼泽为主。层序SII相当于富锦组,主要发育湖侵体系域、高位体系域,局部地区发育低位体系域,煤层亦主要发育高位体系域中后期,成煤环境以扇三角洲淤积沼泽和滨浅湖淤积沼泽为主。层序SI、SII的高位体系域中后期,盆地基底沉降速率和物源供给处于相对平衡状态,主要发育了扇三角洲淤积沼泽、滨浅湖和滨浅湖淤积沼泽环境,发育可采煤层。     

Progress in the Research on the Impact of Wind Farms on Climate and Environment

Wind power has become one of the fastest growing renewable energy. With the large-scale deployment of wind farms in the world, people have started to pay attention to the impact of wind farms on the ecological environment and climate. This paper summarized the impact of wind farms on climate and ecological environment by investigating relevant literature: In the areas of wind farms, on the one hand, the set-up of wind turbines changes original aerodynamic roughness height and strengthens the dragging of the land surface against turbulence, directly affecting the turbulent motion of the boundary layer, resulting in the changes of intensity and pattern of material energy and water vapor exchange between land surface and near-surface atmosphere, further affecting the atmospheric circulation and climate. On the other hand, wind turbines convert the majority of the wind kinetic energy into electric energy, which produces the wake effect of the wind turbine. The budget patterns and spatial and temporal distribution of large-scale kinetic energy in the boundary layer are changed correspondingly, generating changes in various fluxes (heat flux, water vapor flux, etc.) in the atmosphere, which affect temperature, precipitation, and wind speed. Generally, the warming or cooling effect of wind farms on the near-surface is related to the stability of atmosphere. However, simulations in the global climate model showed that the average impact of wind farms on global climate is small, much smaller than the expected changes in greenhouse gas emissions and the interannual changes in natural climate.Wind power emits almost no carbon dioxide and pollutants. Compared with other traditional energy sources, it reduces water consumption but may generate some negative ecological impacts such as animal habitats, bird collisions, and noise, vision impact. However, some measures can be taken to mitigate these adverse effects.     

基于BP神经网络的溶洞规模预测及应用

复杂岩溶地区的溶洞发育规模受地质构造、地区岩性、地下水动力系统等多种因素的影响,具有高度复杂性和非线性的特征。通过对岩溶区溶洞的赋存规律研究,确定影响溶洞发育规模的控制因素进行定量处理,收集已探明溶洞的样本数据。为克服已有研究对溶洞发育规模定性描述的模糊性,文章利用BP（Back Propagation）神经网络对自组织、自适应特性对数据样本的非线性关系揭示的能力,实现对溶洞发育规模的预测,并基于MATLAB实现BP神经网络结构的设计、训练、预测,其结果表明:BP神经网络模型对溶洞规模预测的精度高、收敛性能好。      

台湾峡谷HD133和HD77柱状样的沉积构成和发育背景

分别对南海东北部台湾峡谷内水深3 280 m的HD133和峡谷外水深3 378 m的HD77重力活塞柱状样进行了沉积物粒度、古生物和碳酸钙含量分析,利用AMS14C同位素测年和沉积速率初步认定是属于MIS3a以来的沉积。按沉积物粒度和碳酸钙含量可将两支柱状样划分为3套沉积层段:上部层段1和下部层段3均以粉砂质黏土为主,夹薄层粉砂,深水底栖有孔虫含量高,碳酸钙低于10%,代表受重力流作用较弱的正常深海沉积;中部层段2发育一套以中-细粒为主的厚砂层,含大量浅水底栖有孔虫,碳酸钙含量可高达60%,AMS14C测年出现倒置现象,表明主要为浅水重力流沉积。柱状样的沉积构成响应同期海平面变化,特别表现在深水砂层沉积的两大控制因素:在时间上,低海平面时期大量浅水和陆源碎屑物质直接输送到陆坡之下的深水区,形成富砂的层段2;在空间上,峡谷水道是重力流的物质输送通道,地形优势使得重力流携带物优先在水道中发生沉积,造成HD133柱的含砂量明显高于HD77柱状样。