Chemistry of marine resources-ⅩⅨ. The molecule design and synthesis of crow-link type alkyd resin and its enrichment behaviour for potassium ion in sea water

This paper first presents the molecule design and synthesis of crown-link type alkyd resin,and its enrichment behaviour for potassium ion in low concentration solution and sea water.On the basis of some theory concepts of Host-Guest chemistry developed in recent years,we have designed and synthesized a new polymer enrichment agent of crow-link resin for potassiumion,i.e.,polymacrocyclic ether bislactone of diethylene glycolpyromyllitic acid(briefly called crown-link type alkyd resin or PBL resin).The yield was about 97.4%,almost quantitatively.     

数字测井技术在油页岩勘探中的应用

通过研究数字测井曲线在含油页岩矿层的地层中的变化规律及油页岩、煤层、围岩等不同岩性的曲线形态,使数字测井技术更好地应用到油页岩钻探施工中。     

长江中下游湖泊沉积物铅污染记录——以洪湖、固城湖和太湖为例

2002～2005年在长江中下游的洪湖、固城湖和太湖分别采集了沉积物柱样钻孔,测定了总有机碳（TOC）和金属元素包括Pb,Al,Fe,Ti等,并采用²¹⁰Pb和¹³⁷Cs进行了近代沉积物定年。研究结果表明,洪湖钻孔平均沉积速率为0.15cm/a,固城湖平均沉积速率在0.067cm/a,太湖平均沉积速率为0.35～0.41cm/a。根据湖泊沉积物中铅元素与参考元素（Al,Fe和Ti）浓度和TOC的相关关系建立了回归方程,线性关系极显著（p<0.001）。根据回归方程获取了钻孔中铅的背景值变化,研究表明近代沉积物中金属铅不仅仅来源于自然的作用,而人类活动导致铅的累积发生时间都在20世纪70年代,从一个侧面也说明利用沉积物铅含量变化进行断代存在可能性。对太湖钻孔而言,其污染程度要高于洪湖和固城湖。研究结果表明近30年来洪湖和固城湖人为造成湖泊沉积物铅累积量在不断增加,其沉积物铅污染有进一步加重的趋势,应受到科学家和管理部门的关注。     

重金属污染胁迫下盐肤木的生化效应及波谱特征

利用遥感生物地球化学的原理和方法,分析了德兴铜矿的重金属污染状况和植物盐肤木的生物地球化学效应,对盐肤木生物地球化学效应的波谱特征进行了系统的提取和分析.研究发现酸、铜、镉等是德兴铜矿地区主要的环境污染因子,野外调查及样品的化验分析表明盐肤木对铜元素呈现一定的富集作用和很强的位移效应,是适合铜矿复垦的植被.利用导数光谱、包络线去除、红边效应、植被指数等光谱信息处理方法对盐肤木的野外波谱分析表明,随着叶片中Cu等金属元素含量的增大,其产生的毒化效应的波谱特征越明显,盐肤木叶片光谱反射率明显升高,波形蓝移,红边陡坡斜率增大,叶绿素吸收深度变浅,吸收中心稍有蓝移,水的吸收深度变浅,吸收中心位置红移,绿度指数变化明显.对波谱特征及其与重金属含量的相关关系综合分析后认为,红边特征、植被指数NDVI、叶绿素吸收深度与叶片铜含量关系显著,可以作为植被铜污染遥感图像特征提取的参考.     

从地球系统科学角度浅析中国地貌若干问题研究的新进展

以地球系统中各圈层的相互作用为主线,分析总结了我国沙漠地貌过程、流水地貌过程、冰川地貌过程及风沙地貌过程等领域研究的部分进展。由于我国沙漠地理位置的特殊性,其形成和演变与岩石圈构造变动即青藏高原隆升有着紧密的联系,所以,对我国沙漠形成、演变的研究能为探讨青藏高原隆升历史提供重要佐证。近30年来,有关我国沙漠形成时代的认识更新较快。新的沉积记录显示,我国西北地区的沙漠在中新世时就已经出现了,但沙漠沙丘大规模扩展可能是在中更新世才开始的。既使在晚更新世以来,我国沙漠地区的气候也有过明显波动、沙漠地貌的特征也发生过显著变化。沙漠通过为沙尘暴提供物源,对全球变化产生驱动作用。从地表过程来看,风沙地貌的形成演变不仅受风力作用,而且受流水、湖泊等多种地貌动力过程的影响,地貌类型是各种动力过程共同作用的缩影。古冰川地貌曾是最早发现的第四纪气候变化的证据。随着新的测年技术的出现,学术界对我国第四纪古冰川地貌演化过程有了较系统、全面的认识。流水地貌过程应该是地球上作用区域最广的一种地貌动力过程,对流水地貌过程的认识目前正在向微观和宏观深入。     

Application of Spectral Decomposition to Detection of Fracture-Cavity Carbonate Reservoir Beds in the Tahe Oiifieid, Tarim Basin, NW China

Ordovician fracture-cavity carbonate reservoir beds are the major type of producing formations in the Tahe oilfield, Tarim Basin. The seismic responses of these beds clearly changes depending on the different distance of the fracture-cavity reservoir bed from the top of the section. The seismic reflection becomes weak or is absent when the fracture-cavity reservoir beds are less than 20 ms below the top Ordovician. The effect on top Ordovician reflection became weaker with deeper burial of fracture-cavity reservoir beds but the developed deep fracture-cavity reservoir beds caused stronger reflection in the interior of the Ordovician. This interior reflection can be divided into strong long-axis, irregular and bead string reflections, and was present 80 ms below the top Ordovician. Aimed at understanding reflection characteristics, the spectral decomposition technique, which uses frequency to ＂tune-in＂ bed thickness, was used to predict Ordovician fracture-cavity carbonate formations in the Tahe oilfield. Through finely adjusting the processing parameters of spectral decomposition, it was found that the slice at 30 Hz of the tuned data cube can best represent reservoir bed development. Two large N-S-trending strong reflection belts in the mid-western part of the study area along wells TK440- TK427-TK417B and in the eastern part along wells TK404-TK409 were observed distinctly on the 30 Hz slice and 4-D time-frequency data cube carving. A small N-S trending reflection belt in the southern part along wells T403-TK446B was also clearly identified. The predicted reservoir bed development area coincides with the fracture-cavities connection area confirmed by drilling pressure testing results. Deep karst cavities occur basically in three reservoir bed-development belts identified by the Ordovician interior strong reflection. Spectral decomposition proved to be a useful technique in identifying fracture-cavity reservoir beds.     

Interaction of copper with fatty acids in Soxhlet extraction and its influence

Treatment with metallic copper for the removal of elemental sulfur from bitumen extracted from sedimentary rocks or petroleum is the most widely used method. Little attention has been paid, however, to its disadvantages. It was observed that copper can interact with some polar organic substances during conventional sulfur removal, which can strongly influence the quantitative and qualitative determination of bitumen, as has been confirmed by interaction of long-chain fatty acids with copper. The copper soap generated was analyzed by element analysis, inductively coupled plasma optical emission spectrometry （ICP-OES）, thermal analysis （TG-DSC） and Fourier Transform Infrared spectroscopy （FFIR）. Mechanism of the interaction was investigated and elucidated. Our experimental results would necessitate improvement of the present method for sulfur removal and/or a search for a new one.     

澜沧江某水电站右坝肩工程边坡倾倒变形问题的数值 模拟研究

澜沧江某水电站处于青藏高原东部边缘地带,属于高山峡谷地形地貌,高地应力环境,岩体卸荷裂隙很发育,使得倾倒变形和岩体质量、断裂活动及地震构造一样成为影响工程边坡岩体稳定的主要因素。针对工程边坡的大变形问题可采用离散元的数值模拟分析方法。通过建立理论开挖和工程边坡开挖离散元模型,可分别得出倾倒变形破坏机理发展过程为初期弱倾倒变形岩体的层内剪切错动、强倾倒变形岩体的层内拉张变形、强倾倒变形岩体的切层张-剪破裂及极强倾倒破裂岩体的折断张裂(坠覆)破裂和工程边坡的变形范围、确定开挖面及加固方式等。通过工程边坡模型的计算结果和现场地质调查成果的比较表明,计算结果和实际情况基本吻合。     

软弱夹层几何参数对试样力学行为影响颗粒元模拟研究

基于离散元理论的颗粒元程序,采用颗粒接触连接模型和滑动模型,建立了含软弱夹层试样的颗粒元模型。通过数值模型实验,对不同软弱夹层几何参数试样进行加载模拟,探讨了不同夹层厚度及不同倾角条件下试样的破坏过程和破坏形式,并分析其对试样强度的影响。模拟结果表明,裂隙首先产生于软弱夹层处,随着荷载的增加,再逐渐扩展,呈现渐进性破坏特征;夹层越厚,倾角越大,试样沿软弱夹层呈现较强的滑动特征,如果夹层薄且缓,软弱夹层成为试样破坏的非控制因素;软弱夹层厚度和夹角对试样的峰值强度都有影响,随软弱夹层厚度和夹角的增大,试样的峰值强度降低。     

底摩擦重力试验在倾倒变形岩体稳定性研究中的应用

底摩擦重力试验(底摩擦试验)是利用相似理论分析原理,将研究原形按几何比例和各种物理力学参数,制作相似模型及确定相应的边界条件。然后按照相似边界条件进行加载试验,再现曾经发生过或今后将会出现的物理力学现象,进而了解其发展演化规律及其对工程的影响。澜沧江某水电站坝肩主要为典型的倾倒变形岩体,为探讨倾倒变形岩体在天然重力场条件的变形破裂发展趋势。试验采用模拟重力场条件的岩体底摩擦模型试验技术模拟分析岩体倾倒变形进一步发展演变过程及特征。