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151.
We investigate the electronic structures of one and two monolayer iron phthalocyanine (FePc) molecules on Au(111) surfaces. The first monolayer FePc is lying flat on the Au(111) substrate, and the second monolayer FePc is tilted at ~15° relative to the substrate plane along the nearest neighbour [101-] direction with a lobe downward to the central hole of the unit cell in the first layer. The structural information obtained by first-principles calculations is in agreement with the experiment results. Furthermore, it is demonstrated that the electronic structures of FePc molecules in one-monolayer FePc/Au(111) system are perturbed significantly, while the electronic structures of FePc molecules in the second monolayer in two-monolayer FePc/Au(111) system remain almost unchanged due to the screening of the buffer layer on Au(111). 相似文献
152.
Wave overtopping nearshore coastal structures, such as shore-parallel breakwaters, can significantly alter the current circulation and sediment transport patterns around the structures, which in turn affects the formation of tombolos and salients in the nearshore area. This paper describes the implementation of a wave overtopping module into an existing depth-averaged coastal morphological mode: COAST2D and model applications to investigate the effect of wave overtopping on the hydrodynamics and morphodynamics around a group of shore-parallel breakwaters. The hydrodynamic aspects of the model were validated against a series of laboratory conditions. The model was then applied to a study site at Sea Palling, Norfolk, UK, where 9 shore-parallel segmented breakwaters including 4 surface-piercing and 5 low-crested breakwaters are present, for the storm conditions in Nov 2006. The model results were compared with laboratory data and field measurements, showing a good agreement on both hydrodynamics and morphological changes. Further analysis of wave overtopping effect on the nearshore hydrodynamics and morphodynamics reveals that wave overtopping has significant impacts on the nearshore circulation, sediment transport and the resulting morphological changes within such a complex breakwater scheme under the storm and macro-tide conditions. The results indicate the importance of including the wave overtopping in modelling nearshore morphodynamics with the presence of coastal structures. 相似文献
153.
利用巴丹吉林沙漠北缘拐子湖流沙下垫面2013年7、10月和2014年1、4月的湍流通量资料,计算并分析了研究区近地层湍流强度,同时针对风速分量、温度、水汽和CO2归一化标准差随稳定度的变化关系和总体输送系数等陆面过程特征进行分析。结果表明:(1)风速各分量的湍流强度均随风速的增加逐渐减小,风速处于2 m·s-1以下时湍流发展最为旺盛。湍流强度主要由水平方向风速分量决定,垂直方向风速的作用较小,且近中性和不稳定层结利于湍流的发展。与其他地区相比,平坦且没有建筑物的沙漠地区,机械湍流较弱,湍流强度相应较小。(2)风速各分量的归一化标准差与稳定度(z/L)均满足1/3次方函数规律,其中垂直方向风速分量的拟合曲线方程较好。(3)动量输送系数Cd具有明显的夏季高、冬季低的变化状态且各月的日变化形态均呈夜间低、日间高的循环形态。热量输送系数Ch的不同月份日变化间并没有明显的排列次序,且日出日落前后具有明显的波动。不稳定层结时,Cd和Ch均随风速的增加逐渐减小;稳定层结时,Cd和Ch均随着风速的增加逐渐上升。 相似文献
154.
气候和人为因素对植被变化影响的评价方法综述 总被引:2,自引:1,他引:1
系统评价气候变化和人为因素引起的植被退化,对有效开展生态工程建设、实现生态环境的可持续发展具有重要意义。目前绝大多研究主要分析气候因素对植被变化的影响,分析气候因素和人类活动对植被变化的双重影响少有研究。本文主要介绍这一双重影响对植被变化的贡献程度的主要研究方法——定性-半定量法、回归分析法、残差趋势法、基于净第一生产力的评价方法。综述分析了气候和人为因素对植被变化驱动的主要结论,总结目前各研究方法存在的问题,提出了未来需要重点加强气候和人为因素对植被变化驱动因素的分解研究,加强模型评价和不确定性量化研究等。 相似文献
155.
Nannochloropsis oculata CS179, a unicellular marine microalga, is rich in long-chain polyunsaturated fatty acids (LCPUFAs). Elongase and desaturase
play a key role in the biosynthesis of PUFAs. A new elongase gene, which encodes 322 amino acids, was identified via RT-PCR and 5′ and 3′ RACE. The sequence of the elongase gene was blast-searched in the NCBI GenBank and showed a similarity
to those of the cryptosporidium. But the NJ-tree revealed that the N. oculata CS179 elongase clustered with those of the microalgae Phaeodactylum tricornutum, Ostreococcus tauri and Thalassiosira pseudonana. 相似文献
156.
The toxic effects of benzo[α]pyrene (B[α]P) at different concentrations (0.1, 0.5, 1, 2.5 and 7.5 μgL−1) on scallop (Chlamy farreri) immune system were studied. The results showed that B[α]P had significant toxic effects on the haemocyte counts, neutral red uptake, phagocytosis, bacteriolytic and antibacterial
activity (P<0.05), while the seawater control and acetone control had no significant differences. The haemocyte counts, neutral red uptake,
phagocytosis and bacteriolytic activity in all B[α]P treatment groups as well as antibacterial activity in groups of 0.5, 1, 2.5 and 7.5 μgL−1 B[α]P decreased significantly (P<0.05). Some of these indices tended to be stable on the sixth day and others on the ninth day, and the indices showed clear
time- and concentration-response to B[α]P. Bacteriolytic activity in 0.1μgL−1 B[α]P treatment group and antibacterial activity in 0.1 μgL−1 and 0.5 μgL- B[α]P treatment groups increased at the beginning of exposure and reached their peaks on day 1 and day 6, respectively. Following
that, both activities decreased gradually and became stable after day 9. When all the indices reached stability, they were
significantly lower than those in control group (P<0.05), except for antibacterial activity in 0.1 μgL−1 B[α]P treatment group (P>0.05). Thus, B[α] has evident toxic effects on scallop immune system, which supports the view that a relationship exists between pollution
and immunomodulation in aquatic organisms. 相似文献
157.
158.
平阴县土壤中重金属元素异常成因研究 总被引:1,自引:0,他引:1
通过对平阴县周边及其西部农田区采样调查,平阴县周边元素异常具有异常衬度较高,富集系数大等特征,西部农田区异常具有各元素套合关系好,多数异常衬度不高,富集系数小的特点。结果表明,西部农田区异常是以As,Cd为主要成分的异常,元素含量与SiO2,Al2O3,Fe2O3等常量组分间具有显著的相关性,随SiO2含量的增加而降低,随Al2O3,Fe2O3含量的增加而增加,说明土壤常量组分及其所决定的土壤质地是导致异常形成的主要因素;而平阴城区异常是以S,Hg,As,Zn,Mn等元素为主的异常,是典型的人为综合因素(化工烟尘、工厂污水、生活垃圾)产生的异常。 相似文献
159.
160.