Study on biogenic amines in various dry salted fish consumed in China

This study was carried out to investigate the biogenic amines（BAs）, physicochemical property and microorganisms in dry salted fish, a traditional aquatic food consumed in China. Forty three samples of dry salted fish were gathered from retail and wholesale markets and manufacturers, which had been produced in various regions in China. Cadaverine（CAD） and putrescine（PUT） were quantitatively the most common biogenic amines. About 14% of the samples exceeded the histamine content standards established by the FDA and/or EU. The highest histamine content was found in Silver pomfret（Pampus argenteus）(347.79 mg kg^-1). Five of forty three samples exceeded the acceptable content of TYR(100 mg kg^-1), and 23.26% of dried-salted fish contained high contents of biogenic amines(above 600 mg kg^-1). In addition, species, regions, pickling processes and drying methods made the physicochemical property, microorganisms and biogenic amines in dry salted fish to be different to some extents. The total plate count（TPC） was much higher than that of total halophilic bacteria in all samples. The biogenic amines, physicochemical property and microbiological counts exhibited large variations among samples. Furthermore, no significant correlation between biogenic amines and physicochemical property and TPC was observed. This study indicated that dry salted fish may still present healthy risk for BAs, depending on the processing methods, storage conditions among others.     

新疆乌恰萨热克铜矿北矿带库孜贡苏组沉积相、古流向、物源区及其找矿意义——来自砾石统计分析的证据

萨热克盆地库孜贡苏组是萨热克铜矿的赋矿层位,开展沉积相、物源区及古流向研究对隐伏铜矿的勘探具有重要意义。选取萨热克铜矿北矿带库孜贡苏组地表矿化最好的砾岩展开砾石统计分析,结果表明,偏斜度显示砾岩为冲积扇相沉积,砾石叠瓦状和砂岩斜层理产状统计显示古流向为北北东向;砾石成分主要为石英、石英砂岩、砂岩,石英岩等;粒度分布呈宽峰态或尖峰态;物源区为元古宇长城系阿克苏群变质岩剥蚀区;物源补给分为主河流补给和支河流补给2种方式。冲积扇相、古流向、物源区分析确定了矿体的范围、最优的勘探线布置方位和潜在的找矿靶区,具有很好的勘探意义。     

内蒙古中部红格尔图地区花岗岩的成因及构造背景——LA-ICP-MS锆石U-Pb年龄、地球化学的制约

内蒙古察右后旗红格尔图花岗岩岩体位于索伦缝合带以南,主要为正长花岗岩和二长花岗岩,富硅(70.44%~78.80%),富碱(7.46%~10.74%),贫镁、铁、钛等,A/CNK值在0.95~1.41之间,碱铝指数AKI值在0.68~0.97之间,碱度率AR值在3.30~6.68之间,为弱过铝质-过铝质类碱性系列花岗岩;稀土元素总量变化范围大,轻稀土元素富集,重稀土元素亏损,Eu呈负异常(δEu=0.03~0.89);富集高场强元素Th、U、Hf、Ta、Y等,亏损大离子亲石元素Sr、Ba、Eu等;高场强元素和值((Zr+Nb+Ce+Y)350×10~(-6))明显偏低,该岩体属于高分异I型花岗岩,形成于后造山(后碰撞)伸展构造环境。LA-ICP-MS锆石同位素测年,获得锆石~(206)Pb/~(238)U年龄加权平均值分别为267.2±1.4Ma、269.2±1.6Ma和272.1±1.2Ma,表明该岩体形成于中二叠世,因此研究区内两大板块碰撞缝合的时间应该至少早于该岩体的形成时代,即应该至少早于267.2~272.1Ma。     

Effects of Mudstone Particle Content on Shear Strength of a Crushed Sandstone–Mudstone Particle Mixture

The present study focuses on the shear strength, deformation, and particle crushing of sand which is mixed by crushed sandstone and mudstone particles. Two triaxial tests—one for unsaturated specimens and the other for saturated specimens—were performed, along with sieve analysis tests. Results obtained from the triaxial tests indicate that, with the increment of the mudstone particle content by weight, the angle of internal friction decreases, the cohesion increases and then decreases, and both the initial angle of shearing resistance at the atmospheric pressure and decremental angle increase and then decrease. Compared to the unsaturated specimens, the deviator stress or normalized deviator stress of the saturated specimens at the same axial stress may decrease due to the wetting action. Thus, the shear strength of the tested materials may be reduced by the wetting action. Results of sieve analysis tests indicate that the mixing of some mudstone particles into the sandstone particle mixture may reduce the amount of particle crushing, but the wetting action may increase the amount. The amount of the crushed particle may arrive at a minimum of 40% of mudstone particle content by weight.     

Analysis of urbanization based on center-of-gravity movement and characteristics in Songhua River basin of China and its southern source sub-basin between 1990 and 2010

Urbanization in modern times led to a series of development strategies that brought new opportunities in China. Rapid urbanization caused severe stress to the ecosystems and the environment. Using the center-of-gravity(COG) method and parameters such as population, economy, and land, we studied the urbanization pattern in Songhua River Basin and its southern source sub-basin from 1990 to 2010. Urbanization was analyzed based on the COG position, eccentric distance, movement direction of COG, and distance of COG movement. Various characteristics of urbanization in the southern source sub-basin of the Songhua River were explained in relation to the whole Songhua River Basin. Urbanization in the southern source sub-basin of the Songhua River is balanced, relatively advanced, and stable compared to the whole Songhua River Basin. The average eccentric distance between the urbanization COGs in the Songhua River′s south source basin indicated rapid expansion of land urbanization during the span of this study. A basic pattern of urbanization COG in the whole Songhua Basin was observed, but there existed differences among the three aspects of urbanization process. Land urbanization is still in its active stage, so future studies should focus on analysis of such urbanization trends.     

Distribution and geochemical significance of trace elements in shale rocks and their residual kerogens

There is a dearth of information about the distribution of trace elements in kerogen from shale rocks despite several reports on trace element composition in many shale samples. In this study, trace elements in shale rocks and their residual kerogens were determined by inductively coupled plasma–mass spectrometry. The results from this study show redox-sensitive elements relatively concentrated in the kerogens as compared to the shales. This may be primarily due to the adsorption and complexation ability of kerogen, which enables enrichment in Ni, Co, Cu, and Zn. For the rare earth elements (REEs), distinct distribution characteristics were observed for shales dominated by terrigenous minerals and their kerogen counterparts. However, shales with less input of terrigenous minerals showed similar REE distribution patterns to their residual kerogen. It is speculated that the distribution patterns of the REEs in shales and kerogens may be source-related.     

The morphological characteristics of gully systems and watersheds in Dry-Hot Valley,SW China

Gully systems and watersheds are geomorphic units with clear boundaries that are relatively independent of basin landscapes and play an important role in natural geography. In order to explore the morphological characteristics of gully systems and watersheds in the Dry-Hot Valley [South West (SW) China], gullies are interpreted from online Google images with high resolution and watersheds are extracted from digital elevation model at a scale of 1:50,000. The results show that: (1) There are 17,382 gullies (with a total area of 1141.66 km²) and 42 watersheds in the study area. (2) The average gully density of the study area (D) is 4.29 km/km², gully frequency (F) is 14.39 gullies/km², the branching ratio (B) is 5.13, the length ratio (L) is 3.12, and the coefficient of the main and tributary gullies (M) is 0.06. The degree of gully erosion is strong to extremely strong, the main development intensity of gully erosion ranges from intense to moderate, and the type of gully system is tributary. (3) The watershed areas (A) are between 0.39 and 96.43 km², the relief ratio (R) is from 0.10 to 0.19, the circularity ratio (C) is from 0.30 to 0.83, the texture ratio (T) is from 0.82 to 39.35, and the dominant geomorphological texture type is fine. (4) There is a quantitative relationship between F and D:F?=?0.624D² (R?=0.84) and T is closely related to D, F, M (R²?>?0.7). A, R and C are related to M (R²?>?0.5). The development of gully systems is the result of coupling effects between multiple factors. In this area, the degree of erosion and the condition of the main and tributary gullies can be controlled by the degree of topographic breakage in the watershed, which provides some theoretical basis for the evaluation of gully erosion by the latter. In addition, the scale, relief, and shape have a significant impact on the locations of the main and tributary gullies. For tributary gullies, attention should be paid to the interception and control of runoff and sediment in the small confluence branches in order to prevent gully expansion and head advance. These features can inform the development of targeted measures for the control of soil erosion.     

贵州遵义深溪大型锰矿床主要地质特征

贵州遵义地区是我国二叠纪锰矿的重要分布区之一,深溪锰矿是遵义地区继铜锣井锰矿发现的第二个大型隐伏锰矿床。本文结合深溪锰矿找矿实践,详细总结了深溪锰矿床地层、构造、矿石等特征,并对锰矿的矿床成因进行了探讨。研究表明,深溪锰矿严格受地层层位控制,呈层状、似层状产于二叠纪茅口组第三段浅灰至灰黑色含锰岩系中,矿石矿物主要为菱锰矿,含少量黄铜矿、重晶石、毒砂等矿物,矿石为块状、斑杂状、角砾状构造,自然类型为碳酸锰矿石,工业类型为贫锰矿、富锰矿。分析认为深溪锰矿为深部的气液成矿物质喷溢至地堑盆地中沉积成矿,为"内生外成"的"古天然气渗漏沉积型锰矿床"。