Observations on low-temperature oxidation of minerals in bituminous coals

Mineral matter in three naturally weathered coals from Pennsylvania strip mines and in two laboratory-oxidized coals has been characterized by ⁵⁷Fe Mössbauer spectroscopy, scanning electron microscopy and other techniques to determine mineralogical trasnformations that occur in coals during weathering. Pyrite was found to be the most readily oxidized mineral, forming a variety of iron sulfates initially and geethite eventually. The iron sulfates formed were different in the two laboratory-oxidized coals, despite identical oxidation treatments. Calcite disappeared from one calcite-rich coal with increasing oxidation, but was not replaced by an equivalent amount of gypsum. A severely weathered strip-mine coal was enriched in calcium, which was dispersed through the oxidized macerals. Extended X-ray absorption fine-structure spectroscopy indicated that this dispersed calcium was most likely present as salts of carboxylic acids. Siderite was suprisingly resistant to oxidation at room temperature. Less direct evidence indicates that clay minerals also take part in the alteration to some extent.The coals oxidized in the laboratory showed alteration behavior that differed in a number of respects from that of the strip-mine coals. For example, iron sulfates were much less common in the latter coals; also, the formation of geothite appeared to be controlled to a large extent by the pyrite particle size in the strip-mine coals, but not in the laboratory-oxidized coals.The oxidation of an individual pyrite grain is not only a function of general conditions (temperature, humidity, oxygen partial pressure), but also the immediate local (< 1 mm) chemistry, as a variety of iron sulfates were observed in the coals, often in close proximity. Also, assemblages of gypsum and goethite were observed in otherwise slightly oxidized coal, which indicates that the alteration of pyrite and calcite, when in close contact, proceeds most rapidly.     

珠江口盆地东部中新统珠江组碳酸盐岩沉积微相研究

基于对珠江口盆地东部新近系下中新统珠江组碳酸盐岩1483块常规及铸体薄片显微特征的观察、描述以及古生物特征和岩石学特征的研究,依据碳酸盐岩颗粒组分和结构构造等特点,将珠江组碳酸盐岩划分为8个主要微相类型,并根据灰岩颗粒类型及相对含量的多少,将其进一步细分为22个次一级的微相类型。根据这些微相类型在纵向上的组合特征与环境意义,可在珠江组碳酸盐岩中识别出碳酸盐岩缓坡、局限台地、开阔台地、台地边缘滩、台地边缘礁、台地前斜坡等6个沉积相带。这些沉积相的纵向演化规律揭示了东沙隆起在早中新世海平面上升过程中经历了由碳酸盐岩缓坡到台地的沉积演化历程。      

大同火山群地质及岩石学特征

大同火山群以盆地为对称轴分布,中更新世晚期火山位于盆地的轴部,中更新世早期火山位于盆地两侧。计算的延伸和断裂速率分别为0.43cm/a和0.22cm/a。大同火山群主要属于碱性橄榄玄武岩系列,中更新世早期火山的一部分属于拉斑系列,夏威夷岩是大同火山岩的一个主要类型.中更新世早期火山岩的氧化物变异趋势可能是受高压下Ol+Opx的分离作用控制.中更新世晚期火山岩氧化物变异趋势暗示了是受岩浆混合作用的控制。     

Raman spectroscopic study of K-lingunite at various pressures and temperatures

K-lingunite is a high-pressure modification of K-feldspar that possesses the tetragonal hollandite structure. Variations of the Raman spectra of K-lingunite were studied up to ~31.5 GPa at room temperature, and in the range 79–823 K at atmospheric pressure. The Raman frequencies of all bands were observed to increase with increasing pressure, and decrease with increasing temperature for K-lingunite. This behavior is in line with those observed for most of other materials. New sharp Raman bands appear at pressures greater than 13–15 GPa, suggesting a phase transition in K-lingunite with increasing pressure. The transition is reversible when pressure was released. The appearance of these new Raman bands may correspond to the phase transition revealed earlier at around 20 GPa by X-ray diffraction studies. Instead of transforming back to its stable minerals, such as orthoclase, microcline or sanidine, K-lingunite became amorphous in the temperature range 803–823 K at atmospheric pressure.     

胶东金矿集区硫和碳的循环与控矿作用

胶东金矿集区矿石中普遍含金属硫化物和碳酸盐矿物,某些矿床中还见有富含炭质的断裂破碎带.成矿溶液中含有大量的SO4^2-、HCO3^-、CO2和有机质等的含硫和含碳组分.矿石硫同位素组成明显富集重硫,结合胶东金矿主要成矿时期（早白垩世）特殊的地质背景、同期海水硫酸盐δ^34S平均值（约＋16‰）及现代海水沿NE-NNE向断裂倒灌情况,笔者认为,硫的主要来源与海水硫的大量补给有关.而根据碳、氧同位素组成特征分析,形成金矿床中方解石的物源有很大一部分来自前寒武系碳酸盐岩.浅表环境下成矿金属元素及硫、碳等物质在热液对流系统中的大规模循环是成矿的关键,SO4^2-与S2^-之间的临界转化是制约成矿金属元素活化-迁移-聚集的重要因素,而含碳组分（CO3^2-、HCO3^-、CO2和有机质）则有利于Au、Cu、Pb、Zn等元素的活化和迁移,含硫和含碳组分的循环及有关的物理化学反应之间有明显的关联性.     

盆地的形成和充填过程模拟──以拉伸盆地为例

沉积盆地定量动力学模拟和分析是目前地学领域的一个研究热点。文中建立的拉伸盆地模拟系统可模拟拉伸盆地的沉降过程、估算盆地的拉伸量、分析盆地深部结构和热流背景;动态模拟盆地的充填过程及预测层序格架和沉积体系域的分布样式。沉降和热史模拟结合了二维的回剥法和简单或纯剪切的盆地形成模型。盆地充填模型综合考虑了盆地的构造沉降、均衡作用。沉积物供给。海（湖）平面变化等对盆地充填过程的控制作用。对莺、琼盆地模拟分析揭示了盆地的幕式拉伸过程和深部热演化;层序模拟提示了盆地沉降。海平面变化等对盆地充填演化的控制作用。     

华南飑线升尺度增长过程中的多尺度能量相互作用分析

采用WRF模式对华南飑线的升尺度增长过程进行模拟,利用Barnes滤波将模式数据分解为三个尺度,分别代入相应的能量方程中进行计算,从能量角度研究飑线升尺度增长过程中动能和位能的变化,以及三个尺度系统能量的相互转化.研究表明:动能的变化与飑线过程中各尺度系统的演变有较好的对应,β中小尺度对流的发展对应β中小尺度系统动能的...     

花鲈和鲈鱼群体的遗传分化研究

利用随机扩增多态DNA(RAPD)技术对3个中国花鲈(Lateolabrax maculatus)群体(威海,舟山和北海)和4个日本鲈鱼(L.japonicus)群体(东京湾、山口、有明海和八代海)进行了遗传分化研究。18条随机引物在7个群体中共扩增出159条谱带,其中多态性谱带133条(83.65%)。花鲈和鲈鱼群体间的平均等位基因数和平均有效等位基因数分别为1.836 5和1.524 2,Nei’s多样性指数和Shannon多样性信息指数分别为0.3075和0.4586。花鲈和鲈鱼群体内的遗传多样性分别为0.3156~0.3669和0.2982~0.5150。UPGMA聚类分析显示,舟山、威海和北海3个花鲈群体亲缘关系较近并形成一分支,而日本有明海与八代海的鲈鱼群体同花鲈关系较远,它们与另2个鲈鱼群体(东京湾和山口)形成另一分支。本文结果进一步从分子水平上支持将中国产花鲈和日本的鲈鱼划分为2个种的观点,并且RAPD数据表明花鲈和鲈鱼群体内都出现了明显的遗传分化。     

TS50全站仪配合多测回测角软件在地铁基坑监测中的应用

TS50全站仪配合徕卡多测回测角软件能够自动瞄准、自动观测,具有高智能、高精度的特点,从而在地铁基坑监测领域得到广泛的应用.文章结合济南市轨道交通R1线前大彦站基坑监测项目实践,对测量方法、数据处理、监测效果等方面进行论述.实际应用表明:基于TS50全站仪的多测回测角软件能提供及时可靠的监测数据,科学指导基坑施工,保证...     

Optimal design of inerter systems for the force-transmission suppression of oscillating structures

When dealing with the oscillations of fixed-base structures or machine s induced by external forces,suppre ssing the vibrational impact on the adjacent structures and the environment helps to maintain the structural durability and ensure the users ’ comfort level.This study proposed an inerter-based optimal solution to suppress the vibrational forces and energy transmitted to the suppo rting ground by utilizing the great potential of the inerter.For the exte rnal fo rce,which contains various fr...