皖南花山锑金矿床硫化物电子探针分析及其指示意义

花山锑金矿床位于皖南东至县境内, 是皖南地区代表性金-多金属矿床之一。 本次工作对花山锑金矿床开展了野外地质、岩相学特征观察以及金属硫化物电子探针分析, 得到以下结论：1） 花山锑金矿床主要成矿阶段可分为毒砂-黄铁矿（PyⅠ）阶段、黄铜矿-黄铁矿 （PyⅡ）阶段和方解石-辉锑矿阶段。 2） 金在不同阶段硫化物中均有赋存, 其矿化伴随整个热液成矿过程, 且以毒砂-PyⅠ阶段和黄铜矿-PyⅡ阶段为主。 毒砂-PyⅠ阶段和黄铜矿-PyⅡ阶段发育金矿化, 无锑矿化, 方解石-辉锑矿阶段发育锑、金共生矿化。 3） 早阶段即毒砂 -PyⅠ阶段和黄铜矿-PyⅡ阶段载金矿物为黄铁矿、毒砂及黄铜矿, 成矿物质来源以地层为 主;晚阶段即方解石-辉锑矿阶段载金矿物为辉锑矿, 成矿物质来源以燕山期岩浆岩为主。 本次工作对东至及皖南地区金矿床的寻找勘探具有重要的指示意义。     

Re–Os and U–Pb Geochronology of Porphyry and Skarn Types Copper Deposits in Jilin Province,NE China

Jilin Province in NE China lies on the eastern edge of the Xing–Meng Orogenic Belt. Mineral exploration in this area has resulted in the discovery of numerous large, medium, and small sized Cu, Mo, Au, and Co deposits. To better understand the formation and distribution of both the porphyry and skarn types Cu deposits of the region, we examined the geological characteristics of the deposits and applied zircon U–Pb and molybdenite Re–Os isotope dating to constrain the age of the mineralization. The Binghugou Cu deposit yields a zircon U–Pb age for quartz diorite of 128.1 ± 1.6 Ma; the Chang'anpu Cu deposit yields a zircon U–Pb age for granite porphyry of 117.0 ± 1.4 Ma; the Ermi Cu deposit yields a zircon U–Pb age for granite porphyry of 96.8 ± 1.1 Ma; the Tongshan Cu deposit yields molybdenite Re–Os model ages of 128.7 to 130.2 Ma, an isochron age of 129.0 ± 1.6 Ma, and a weighted mean model age of 129.2 ± 0.7 Ma; and the Tianhexing Cu deposit yields molybdenite Re–Os model ages of 113.9 to 115.2 Ma, an isochron age of 114.7 ± 1.2 Ma, and a weighted mean model age of 114.7 ± 0.7 Ma. The new ages, combined with existing geochronology data, show that intense porphyry and skarn types Cu mineralization was coeval with Cretaceous magmatism. The geotectonic processes responsible for the genesis of the Cu mineralization were probably related to lithospheric thinning. By analyzing the accumulated molybdenite Re–Os, zircon U–Pb, and Ar–Ar ages for NE China, it is concluded that the Cu deposits formed during multiple events coinciding with periods of magmatic activity. We have identified five phases of mineralization: early Paleozoic (~476 Ma), late Paleozoic (286.5–273.6 Ma), early Mesozoic (~228.7 Ma), Jurassic (194.8–137.1 Ma), and Cretaceous (131.2–96.8 Ma). Although Cu deposits formed during each phase, most of the Cu mineralization occurred during the Cretaceous.     

流-固耦合模型试验用的新型相似材料研制及应用

为研究隧道突水、突泥过程中断层及围岩各物理场变化规律,根据地质力学模型试验相似原理,通过大量多组别配比试验,研制出适用于流-固耦合模型试验的新型断层及围岩相似材料。其中,断层相似材料以砂为粗骨料,滑石粉为细骨料,石膏、膨润土作为胶结剂,液态石蜡作为调节剂;围岩相似材料以砂为粗骨料,重晶石粉、滑石粉为细骨料,白水泥及乳胶作为胶结剂。通过大量室内试验,对比分析原岩及相似材料变形特征及强度破坏特性,重点对单轴抗压强度、渗透系数、重度、泊松比、弹性模量等重要变形及水理特性参量进行调控,系统研究不同配比对材料参数的影响规律。试验结果表明：该材料力学参数变化范围广、性能稳定、操作工艺简单,可用来模拟不同渗透系数的低、中等强度岩体材料。将该相似材料应用于吉莲高速公路永莲隧道断层突水、突泥三维地质力学模型试验中,力学性能及水理特性均达到试验要求,能够有效地模拟突水、突泥的发展演变过程,真实反映断层灾变过程中各物理场响应规律。     

武都万象洞方解石现代沉积体系δ~(18)O值月变化特征

万象洞所在地大气降水同位素值年内波动较大,变化起止时间存在显著的年际差异。观测期内,武都降水同位素δD-δ18O组合特征与周边城市降水同位素多年平均值重建的区域降水雨水线基本重合,洞穴所在地区降水同位素具有很好的区域代表性。洞穴滴水同位素值年内变化幅度较小,基本反映了当地大气降水同位素值的月加权平均水平。洞穴次生碳酸盐与洞穴滴水之间符合同位素平衡分馏基本规律。季节尺度上,不同监测点滴水及次生碳酸盐δ18O值因受地下水混合作用强弱差异及洞穴温度的小幅变化等影响而略有差异;年际变化上,夏季风爆发前后降雨量的权重及爆发时间的早晚对洞穴滴水-碳酸盐体系同位素水平存在一定的影响。万象洞洞穴滴水、石笋氧同位素信号在年代际尺度上可以很好地指示区域内大气降水的同位素变化特征。     

基于Google Earth影像分析区域性大型“X”共轭节理系统对宏观岩溶作用的控制

从黔南、桂北的航天遥感图像上可以清楚地看出,地表的宏观岩溶地貌明显地受控于区域性大型“X”共轭节理系统,此类节理构成一幅巨型的渗滤网,成为大气降水下渗的主要通道,从而导致被其穿透的岩石遭受溶蚀,形成以线性岩溶谷地为主体的岩溶景观。即水平地层分布区,呈片状“X”形网络结构;直立地层分布区,呈羽状条带结构。水体下渗至潜水面后,将主要沿“X”节理走向向当地最低侵蚀基准面排泄,从而形成复杂的地下管道网络系统。首次利用网上Google Earth影像研究喀斯特环境,解决了只能依赖航片和卫星照片才能研究地球地貌的瓶颈,这对地貌研究和喀斯特石漠化的研究和治理提供了廉价便利的影像材料。     

十万山盆地演化过程中的油气资源效应

十万山盆地位于广西西南部，大地构造位置属于华南板块的西北缘，是在华南板块与杨子板块拼接的加里东运动之后，早古生代华南洋再一次打开形成被动大陆边缘。晚二叠世末，该地区变成孤后盆地，进一步转化成前陆盆地。在盆山转换过程中，经历了三次沉积－构造盆山转换过程：泥盆纪－二早叠世分地新生与被动大陆边缘拉张裂谷；晚二叠世与中三叠世间盆地构造性质转换与前陆盆地；晚三叠世至侏罗纪的晚期前陆磨拉石沉积。在碎屑岩陆架沉积阶段，生成碎屑岩烃源岩层。在碳酸盐台地沉阶段，发育硝屑灰岩、藻灰岩、礁灰岩和暴露作用生成的白云岩储集岩。因而其早期被动大陆边缘阶段构了古生新储组合。前陆盆地早期在前渊盆地内沉积了一套碎屑岩烃源岩。它与早期的储集层构成了新生古储组合。同时也对下伏地层起到了封闭作用。沉积地层逐层向克拉通斜坡上超覆，发育地层圈闭。前渊阶段中期快速沉积的巨厚的复理石沉积和晚期快速沉积形成的磨拉石沉积有利于早期沉积的迅速埋藏、成熟和保存。     

南祁连山前区中生代晚期古构造特征的研究

南祁连山前区可以分为露头和盆地区两个不同的大地构造单元,本区晚中生代构造活动强烈,控制了新生代的沉积过程和现今中生界残余层序的分布。本文提出了均匀平板状沉积体后期的构造变形可以利用古地质图以及高精度残余地层厚度的变化规律判断古构造带的分析方法,并且对于研究区中生代晚期的古构造特征进行了分析。露头区主要利用古地质图分析方法,研究区集中在赛什腾山-埃姆尼克山北缘的鱼卡和红山地区。盆地区主要利用中生界残余厚度图的分析方法,研究区集中在赛什腾山-埃姆尼克山南侧的赛什腾南部凹陷和马海凸起地区。通过这4个地区古构造特征的研究,提出南祁连山前区中生代晚期在区域性隆升的背景下,形成了一系列古构造带,古构造活动的特点是形成北西-北北西走向的背斜和向斜构造,这些褶皱的波长为15～20 km,为中尺度规模。同时指出,中国西部多数地区均缺失上白垩统,暗示着当时的中亚地区存在一个广阔的晚白垩世古高原。     

过去2000年气候变化对中国经济与社会发展影响研究综述

It is one of the important focuses of the Past Global Changes (PAGES) to investigate the long-term impacts of climate change on regional social and economic development over the past two millenniums. The past decades in China have witnessed great progresses in the study of past climatic influence on human society. In this paper, reviews have been made on the latest proceedings related with researches about the past 2000-year climatic impacts on Chinese history in terms of the following three aspects: economic fluctuations, social stability, and the rise and fall of dynasties in China. It is concluded that climate change and socio-economic fluctuation in historical China really temporarily demonstrated a good coincidence, which indicates a potential driving-response mechanism was likely embedded in the complicated relationship between climate change and human society. A warm climate provided relatively stable conditions of agricultural production and thus generally played a positive role in the healthy development of the economy and society. On the contrary, socio-economic adverseness triggered by a colder climate was preconditioned with social problems such as the intensification of the contradiction between people and land, as well as the gradual accumulation of social rigidity. These social problems accompanying with social development contributed higher vulnerability of society in the face of changing climate, which to some extent might amplify the effects of climatic deterioration. The authors emphasize that the future studies of the relationship between past climate change and human history in China should attach more attention to the following key problems: making deeper exploitation of the potential of Chinese historical documents, exploring the mechanism of climate-society interaction, and studying the differences of climatic effects on socio-economic development at the regional scale. This study from a historical perspective might enhance the understanding of human-environment relationship under a situation of global warming, and also provide the scientific basis for the sustainable social development in China.     

硼及硼同位素地球化学在地质研究中的应用

总结了硼及硼同位素的地球化学特征：（１）硼是易溶元素,主要赋存在地球表层,尤其是海水、海相沉积物及海水交代岩石中。其同位素组成δ１１Ｂ值按顺序变化,封闭盐湖卤水（＞４０‰）＞海水（３９５‰）＞海相硼矿物（１８２‰～３１７３‰）＞海相沉积物（１３９‰～２５２‰）＞海水交代岩石（４５１‰～１０８５‰）。大陆水及陆相沉积物硼含量及硼同位素组成变化极大,并多以负值为主。海陆过渡构造带则具有过渡的硼丰度值和硼同位素组成。（２）１１Ｂ较１０Ｂ具有更活跃的地球化学性质,因此在水岩作用中具有明显的同位素交换。硅化交代作用中,岩石被硅化交代,释放硼,并优先释放重硼,同位素组成变轻;在脱硅反应中,岩石释放硅吸收硼,并优先吸收重硼,同位素组成变重。在封闭体系中,水溶液淋滤岩石中部分的硼,即可大量富集,并富集１１Ｂ;在开放体系中,岩石硼被大量淋滤流失,δ１１Ｂ值明显降低。由于水岩作用的结果,从新鲜海底玄武岩到正常海水,硼同位素值从－２９５‰到３９５‰逐渐升高。（３）变质脱水反应中硼被大量排出,并优先排出重硼同位素,进入流体相,因此随着变质程度由低到高,岩石中硼含量及同位素组成δ１１Ｂ值由高变低。（４）在成矿研究中?