Iron isotopic systematics of UHP eclogites respond to oxidizing fluid during exhumation

The iron stable isotope compositions (δ⁵⁶Fe) and iron valence states of ultrahigh‐pressure eclogites from Bixiling in the Dabie orogen belt, China, were measured to trace the changes of geochemical conditions during vertical transportation of earth materials, for example, oxygen fugacity. The bulk Fe³⁺/ΣFe ratios of retrograde eclogites, determined by Mössbauer spectroscopy, are consistently higher than those of fresh eclogites, suggesting oxidation during retrograde metamorphism and fluid infiltration. The studied eclogites (five samples) display limited mid‐ocean ridge basalts (MORB)‐like (~0.10‰) δ⁵⁶Fe values, which are indistinguishable from their protoliths, that is, gabbro cumulates formed through differentiation of mantle‐derived basaltic magma. This suggests that Fe isotope fractionation during continental subduction is limited. Garnet separates display limited δ⁵⁶Fe variation ranging from ?0.08 ± 0.07 ‰ to 0.02 ± 0.07‰, whereas coexisting omphacite displays a large variation of δ⁵⁶Fe values from 0.15 ± 0.07‰ to 0.47 ± 0.07‰. Omphacite also has highly variable Fe³⁺/ΣFe ratios from 0.367 ± 0.025 to 0.598 ± 0.024, indicating modification after peak metamorphism. Omphacite from retrograde eclogites has elevated Fe³⁺/ΣFe ratios (0.54–0.60) compared to that from fresh eclogites (~0.37), whereas garnet displays a narrow range of ferric iron content with Fe³⁺/ΣFe ratios from 0.039 ± 0.013 to 0.065 ± 0.022. The homogenous δ⁵⁶Fe values and Fe³⁺/ΣFe ratios of garnet suggest that it survived the retrograde metamorphism and preserved its Fe‐isotopic features and ferric contents of peak metamorphism. Because of similar diffusion rates of Fe and Mg in garnet and omphacite, and constant Δ²⁶Mg_{omphacite‐garnet} values (1.14 ± 0.04‰), equilibrium iron isotope fractionation between garnet and omphacite was probably achieved during peak metamorphism. Elevated Fe³⁺/ΣFe ratios of omphacite from retrograde eclogites and variant Δ⁵⁶Fe_{omphacite‐garnet} values of the studied eclogites (0.13 ± 0.10‰ to 0.48 ± 0.10‰) indicate that oxidized geofluid infiltration resulted in the elevation of δ⁵⁶Fe values of omphacite during retrograde metamorphism.     

便携式Li-K分析仪的研制及其在锂辉石中锂的分析应用

我国锂钾主要矿产资源大多分布在西部偏远地区,其勘查找矿或综合利用迫切需要现场快速分析技术的支持。本文介绍了自行开发的便携式Li-K分析仪的主要性能及其在锂辉石中锂的分析应用。Li-K分析仪是一种基于大气压的液体阴极辉光放电光谱仪,以待测液体为放电阴极,实现了样品中Li、K等元素的原子化和激发。该仪器以光纤传导CCD光谱仪作为检测器,其波长范围为345~1015 nm,分辨率3 nm;以Li 670.78 nm和K 769.90 nm分析谱线,在仪器最佳工作条件下测定Li、K的精密度(RSD,n=14)均低于2%,检出限为0.03μg/m L,检测范围0.1~10μg/m L。研究表明,不同酸度和酸的类型对谱线强度影响较大,且存在显著的样品基体效应,标准曲线法分析锂辉石中Li的结果偏差高达267%;而标准加入法可克服基体效应的影响,获得与ICP-OES一致性较好的分析结果,为现场开展固体样品中Li的测定奠定了基础。     

Phase transition of the Pacific decadal oscillation and decadal variation of the East Asian summer monsoon in the 20th century

This paper focuses on the relationship between the phase transition of the Pacific decadal oscillation (PDO) and decadal variation of the East Asian summer monsoon (EASM) in the twentieth century. The first transition occurred in the 1940s, with an enhanced SST in the North Pacific and reduced SST in the tropical eastern Pacific and South Indian Ocean. In agreement with these SST changes, a higher SLP was found in most parts of the Pacific, while a lower SLP was found in the North Pacific and most parts of the Indian Ocean. In this case, the EASM was largely enhanced with a southerly anomaly in the lower troposphere along the east coast of China. Correspondingly, there was less rainfall in the Yangtze River valley and more rainfall in northern and southern China. An opposite change was found when the PDO reversed its phase in the late 1970s. In the tropical Indian Ocean and western Pacific, however, the SST was enhanced in both the 1940s and 1970s. As a result, the western Pacific subtropical high (WPSH) tended to extend westward with a larger magnitude in the 1970s. The major features were reasonably reproduced by an atmospheric general circulation model (IAP AGCM4.0) prescribed with observed SST and sea ice. On the other hand, the westward extension of the WPSH was exaggerated in the 1970s, while it was underestimated in the 1940s. Besides, the spatial pattern of the simulated summer rainfall in eastern China tended to shift southward compared with the observation.     

高性能计算技术在气象领域的应用

高性能计算通过应用超级计算机与并行处理技术解决复杂的计算问题,是信息技术发展比较迅猛的领域之一。气象应用始终是高性能计算的重要领域,高性能计算技术有效地解决了高分辨率、高精度气象数值预报模式发展限制,在气象预报预测业务中发挥着核心支撑作用。数十年以来,由于数值天气模式研究和业务运行对计算资源的强烈需求,国内外气象领域高性能计算机及应用迅速发展起来。气象领域对高性能计算能力及系统的可靠性需求日益提升。高性能计算技术将与气象预报应用日益融合,相互影响促进,不断创新发展。为满足气象预报预测业务和科研工作需求,中国气象部门将进一步提升高性能计算能力,并致力于优化集约高性能计算系统布局,高效管理计算资源,发挥最大效益。     

辽宁地区不同降水云系雨滴谱参数及其特征量研究

利用位于辽宁省沈阳市和辽阳市的Parsivel（Particle Size and Velocity）激光雨滴谱仪观测到的雨滴谱资料按照积雨云降水系统、积层混合云降水系统和层状云降水系统分析雨滴谱特征量和谱参数的平均特征及随时间的演变特征。结果表明:Gamma分布拟合谱参数N₀和λ按照层状云、积层混合云和积雨云的顺序减小,谱参数μ按照层状云、积层混合云和积雨云的顺序增大;直径小于1 mm的降水粒子对数浓度的贡献最大,直径大于1 mm的降水粒子对雷达反射率的贡献最大;M-P分布的谱参数N₀与雨强I具有幂函数关系,并且随着雨强I的增大而增大,谱参数λ与雨强I具有指数函数关系,随着雨强I的增大而减小。     

语义感知的地理视频大数据自适应关联组织方法

正地理视频是智慧城市和城市安全领域的重要战略资源。复杂城市环境中公共安全事件大范围流动、多阶段演化及多因素并发等新特征,使现有基于摄像机位置分布存储与分区管理的地理视频组织产生涉案数据检索中迅速扩大的虚警输出规模与急剧降低的涉案信息价值密度。发展支持涉案数据快速整合和案件知识高效理解的数据组织新机制成为发挥地理视频安防价值的重要科学内容。     

采用弯曲进行道路化简冲突避免的方法

针对道路化简后可能导致要素间空间关系前后不一致的问题,提出了一种采用弯曲进行道路化简冲突避免的方法。首先,以弯曲为单元分析道路化简前后弯曲的形态变化规律,对化简过程产生的要素间空间冲突类型进行了归纳和总结;其次,基于道路弯曲与要素之间的空间关系,提出了相应的冲突判别规则;最后,利用弯曲化简的可控性和弯曲组的间接化简策略实现对化简冲突的避免。试验表明,该方法能有效地识别和避免道路化简产生的空间冲突,确保化简前后道路与其他要素空间关系的一致性。     

顾及邻域居民地群组相似性的道路网匹配方法

现有多源同比例尺道路网匹配方法中,大多只利用道路自身特征进行匹配,而较少顾及道路周边要素对匹配过程的影响和约束,从而影响了道路网匹配效果的进一步提高,特别是对系统误差改正后仍存在一定位置或旋转偏差的道路数据进行匹配时,这种影响尤为明显。本文借鉴人类对陌生环境的空间认知特点,提出了一种顾及邻域居民地群组相似性的道路网匹配方法。该方法通过构建城市骨架线网确定与道路相邻的居民地群组,进而计算居民地群组空间关系和几何特征相似度来获得对应道路的匹配结果。其特点在于:对存在位置或旋转偏差的道路数据匹配,以其邻域空间内居民地群组的整体相似性指标来带动道路自身匹配,实际上是增加了周边居民地群组对道路匹配过程的约束,更具鲁棒性。试验及对比分析表明,本方法能够较好地解决系统误差改正后仍存在较大位置和旋转偏差的道路数据间的匹配问题,提高匹配的正确率。