Electro‐Catalytic Degradation of Phenol Organics with SnO2‐Sb2O3/Ti Electrodes

The effect of extraordinary degradation of phenol organics on the SnO₂‐Sb₂O₃/Ti electrode is investigated through experimental research and theoretical analysis. The phenol organics contained 4‐chloro‐phenol, 4‐bromo‐phenol, and 2‐iodo‐phenol. At a current density of 4 mA cm^–2 and an electrolysis time of 12 h, the degradation efficiency of the phenols was over 98% with a relatively short degradation time, whereas the degradation time of the PbO₂/Ti electrode surpassed 40 h while delivering 100% disposal efficiency. Therefore, the effectiveness of electrochemical (EC) oxidation by the SnO₂‐Sb₂O₃/Ti was superior to that of the PbO₂/Ti electrode. At the same time, the SnO₂‐Sb₂O₃/Ti had higher oxygen generation potential and lower electron consumption than the other electrodes. This was mainly due to the effect of the middle Sb₂O₃ layer, which due to its high porosity and good catalytic effect, contributed to a better catalysis than the SnO₂ part.     

1631年常德地震与太阳山断裂带活动性分析

地震成因类型的研究可以为未来地震趋势的估计、烈度区划和重大工程场地地震安全性评价等提供重要科学依据.作为华南内陆的较大地震之一的常德63/4级地震成因探讨更具现实的意义.近年来,湖南和湖北及附近地区在进行重大工程(核电站,水火电站,大型水库,桥梁,速公路及高层建筑等)的场地地震安全性评价工作,及编制地震动区划图时都对常德63/4级地震予以了高度的重视.     

竖向地震动强度包络函数的空间变化规律

利用SMART 1台阵三次地震记录拟合了各个测点在地震中的竖向地震动强度包络曲线及Amin 和Ang的强度包络函数中各模型参数值,分析了各模型参数的空间变化规律,建立了各模型参数随二维空间坐标及土层厚度变化的随机模型,为多点地震动合成中竖向强度包络函数的计算提供了理论依据。     

Stratification and mixing of a post-glacial Neoproterozoic ocean: Evidence from carbon and sulfur isotopes in a cap dolostone from northwest China

To improve our knowledge about the geochemical and environmental aftermath of Neoproterozoic global glaciations, we analyzed stable isotopes (δ¹³C, δ¹⁸O, δ³⁴S) and elemental concentrations (Ca, Mg, S, Sr, Fe, and Mn) of the ～ 10-m-thick Zhamoketi cap dolostone atop the Tereeken diamictite in the Quruqtagh area, eastern Chinese Tianshan. Available chemostratigraphic data suggest that the Tereeken diamictite is probably equivalent to the Marinoan glaciation. Our new data indicate that organic and carbonate carbon isotopes of the Zhamoketi cap dolostone show little stratigraphic variations, averaging ? 28.2‰ and ? 4.6‰, respectively. In contrast, sulfur isotopes show significant stratigraphic variations. Carbonate associated sulfate (CAS) abundance decreases rapidly in the basal cap dolostone and δ³⁴S_CAS composition varies between + 9‰ and + 15‰ in the lower 2.5 m. In the overlying interval, CAS abundance remains low while δ³⁴S_CAS rises ～ 5‰ and varies more widely between + 10‰ and + 21‰. The range of δ³⁴S_py of the cap dolostone overlaps with that of δ³⁴S_CAS, but direct comparison shows that δ³⁴S_py is typically greater than δ³⁴S_CAS measured from the same samples. Hypotheses to explain the observations must account for both the remarkable sulfur isotope enrichment of pyrites and the inverse fractionation. We propose that CAS and pyrite were derived from two isotopically distinct reservoirs in a chemically stratified basin or a basin with a sulfate minimum zone. In this model, CAS was derived from shallow, oxic surface waters with moderate sulfate concentration and depleted in ³⁴S due to the post-glacial influx of sulfur from continental weathering. In contrast, pyrite was derived from anoxic bottom waters (or a sulfate minimum zone) with low sulfate concentration and ³⁴S enrichment due to long-term syn-glacial sulfate reduction. The rapid shift in CAS abundance and sulfur isotope composition within the cap dolostone is interpreted to reflect the mixing of the two reservoirs after initial deglaciation. Comparison with other post-Marinoan cap carbonates shows significant spatial heterogeneity in δ³⁴S_CAS, which together with strong temporal variation in δ³⁴S_CAS, points to generally low sulfate concentrations in post-Marinoan oceans.     

南京基准地震台与中国地震台网测定体波震级对比分析

以中国地震台网测定的综合体波震级为标准震级,采用正交回归方法,得到南京测震台（NJ2）体波震级与标准体波震级之间的关系式,并对震级偏差与震级大小、震中方位和震中距关系进行偏差分析,为台站分析人员提供指导.     

四川地区震后应急会商资料快速产出系统的设计与实现

地震预报意见以大量资料为基础,依靠专家经验和多学科知识并通过会商讨论形成。显著地震发生后,快速、准确、有效地研判震情可为后期应急指挥和地震现场工作奠定基础。本文以Datist软件为平台,基于四川及邻区的基础资料,设计研发符合四川震情的震后会商资料快速产出系统,当四川及邻区发生中强地震时,通过该系统可在收到地震短信5分钟内以请求触发的方式快速产出应急会商资料,并以微信、PowerPoint和Word的形式将基础资料发送给分析预报人员,为后期趋势分析奠定基础。     

基于企业微信的宁波市地震应急工作助手的设计与实现

通过分析市县地震部门的地震应急组织机构、主要职能、关键流程,设计了地震应急工作助手的需求方案。并应用ASP.NET MVC、HTML5等开发技术,基于企业微信,开发了包括震情服务、灾情服务、应急服务、工作报告、资料查询、通知公告、通信录等7大功能的地震应急工作助手软件。该软件具有相对机动灵活、成本低、易于推广使用的优势。多次地震应急演练使用表明,软件能在较大程度上提高地震应急工作的规范化程度和处置效率。     

Dissolved organic matter in surface runoff in the Loess Plateau of China: The role of rainfall events and land-use

Exploring the chemical characterization of dissolved organic matter (DOM) is important for understanding the fate of laterally transported organic matter in watersheds. We hypothesized that differences in water-extractable organic matter (WEOM) in soils of varying land uses and rainfall events may significantly affect the quality and the quantity of stream DOM. To test our hypotheses, characteristics of rainfall-runoff DOM and WEOM of source materials (topsoil from different land uses and gullies, as well as typical vegetation) were investigated at two adjacent catchments in the Loess Plateau of China, using ultraviolet–visible absorbance and excitation emission matrix fluorescence with parallel factor analysis (PARAFAC). Results indicated that land-use types may significantly affect the chemical composition of soil WEOM, including its aromaticity, molecular weight, and degree of humification. The PARAFAC analysis demonstrated that the soils and stream water were dominated by terrestrial/allochthonous humic-like substances and microbial transformable humic-like fluorophores. Shifts in the fluorescence properties of stream DOM suggested a pronounced change in the relative proportion of allochthonous versus autochthonous material under different rainfall patterns and land uses. For example, high proportions of forestland could provide more allochthonous DOM input. This study highlights the relevance of soils and hydrological dynamics on the composition and fluxes of DOM issuing from watersheds. The composition of DOM in soils was influenced by land-use type. Precipitation patterns influenced the proportion of terrestrial versus microbial origins of DOM in surface runoff. Contributions of allochthonous, terrestrially derived DOM inputs were highest from forested landscapes.     

三峡澎溪河水-气界面温室气体模型估算及其敏感性分析

模型估算法是水-气界面温室气体通量监测的主要方法,所得成果也不胜枚举.然而监测过程中诸多环境因素会对最终结果产生不确定的影响.结合三峡库区澎溪河背景条件,利用模型估算法进行水-气界面温室气体通量(以CO_2为例)估算,并且采用修正Morris筛选法尝试分析模型估算法中各个参数对温室气体扩散通量(以CO_2为例)的局部敏感性.研究结果表明:利用模型估算法计算三峡澎溪河流域水-气界面温室气体通量具有较高的可行性和可靠性;风速、水温以及pH值会对监测结果产生影响,且风速越强、水温越高、pH值越小,CO_2扩散通量就越大;pH值是高灵敏参数,风速和水温是灵敏参数.在三峡库区澎溪河监测过程中更应注意pH值的精确性,每次采样前需校正仪器.     

2014年8月云南鲁甸MS 6.5地震典型地表破裂特征

北京时间2014年8月3日16时30分,云南省鲁甸县发生了M_S 6.5地震,本次地震的发震构造为包谷垴-小河断裂。野外调查发现,王家坡不稳定斜坡上的地表破裂在整个破裂带中比较具有代表性,其地表破裂带整体走向N45°W-N50°W,并且由剪切破裂、张剪切破裂、压剪切破裂、张性破裂以及鼓包等典型地表破裂组成。其中左、右地表破裂边界与发震断层的出露位置一致,由断层错动造成;而部分地表破裂与断层的位置不重合,其成因分为2种,一种是发震断层导致的一些次级地表破裂,另一种是地震引发的滑坡后缘破裂。地表破裂类型和基本组合特征显示出王家坡潜在不稳定斜坡上的地表破裂带具有左旋走滑的性质。